Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials

Autores
Peralta, Marcos Emanuel; Koffman Frischknecht, Alejandro; Moreno, Mario Sergio Jesus; Martire, Daniel Osvaldo; Carlos, Luciano
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We propose here a novel green synthesis route of core-shell magnetic nanomaterials based on the polyol method, which uses bio-based substances (BBS) derived from biowaste, as stabilizer and directing agent. First, we studied the effect of BBS concentration on the size, morphology, and composition of magnetic iron oxides nanoparticles obtained in the presence of BBS via the polyol synthesis method (MBBS). Then, as a proof of concept, we further coated MBBS with mesoporous silica (MBBS@mSiO2) or titanium dioxide (MBBS@TiO2) to obtain magnetic nanostructured core-shell materials. All the materials were deeply characterized with diverse physicochemical techniques. Results showed that both the size of the nanocrystals and their aggregation strongly depend on the BBS concentration used in the synthesis: the higher the concentration of BBS, the smaller the sizes of the iron oxide nanoparticles. On the other hand, the as-prepared magnetic core-shell nanomaterials were applied with good performance in different systems. In particular, MBBS@SiO2 showed to be an excellent nanocarrier of ibuprofen and successful adsorbent of methylene blue (MB) from aqueous solution. MBBS@TiO2 was capable of degrading MB with the same efficiency of pristine TiO2. These excellent results encourage the use of bio-based substances in different types of synthesis methods since they could reduce the fabrication costs and the environmental impact.
Fil: Peralta, Marcos Emanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Koffman Frischknecht, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Moreno, Mario Sergio Jesus. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Materia
GREEN CHEMISTRY
MAGNETIC NANOPARTICLES
MAGNETITE
SOLVOTHERMAL SYNTHESIS
WASTE VALORIZATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/227619
Acceder
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spelling Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell MaterialsPeralta, Marcos EmanuelKoffman Frischknecht, AlejandroMoreno, Mario Sergio JesusMartire, Daniel OsvaldoCarlos, LucianoGREEN CHEMISTRYMAGNETIC NANOPARTICLESMAGNETITESOLVOTHERMAL SYNTHESISWASTE VALORIZATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We propose here a novel green synthesis route of core-shell magnetic nanomaterials based on the polyol method, which uses bio-based substances (BBS) derived from biowaste, as stabilizer and directing agent. First, we studied the effect of BBS concentration on the size, morphology, and composition of magnetic iron oxides nanoparticles obtained in the presence of BBS via the polyol synthesis method (MBBS). Then, as a proof of concept, we further coated MBBS with mesoporous silica (MBBS@mSiO2) or titanium dioxide (MBBS@TiO2) to obtain magnetic nanostructured core-shell materials. All the materials were deeply characterized with diverse physicochemical techniques. Results showed that both the size of the nanocrystals and their aggregation strongly depend on the BBS concentration used in the synthesis: the higher the concentration of BBS, the smaller the sizes of the iron oxide nanoparticles. On the other hand, the as-prepared magnetic core-shell nanomaterials were applied with good performance in different systems. In particular, MBBS@SiO2 showed to be an excellent nanocarrier of ibuprofen and successful adsorbent of methylene blue (MB) from aqueous solution. MBBS@TiO2 was capable of degrading MB with the same efficiency of pristine TiO2. These excellent results encourage the use of bio-based substances in different types of synthesis methods since they could reduce the fabrication costs and the environmental impact.Fil: Peralta, Marcos Emanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Koffman Frischknecht, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Moreno, Mario Sergio Jesus. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; ArgentinaFil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaMDPI2023-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/227619Peralta, Marcos Emanuel; Koffman Frischknecht, Alejandro; Moreno, Mario Sergio Jesus; Martire, Daniel Osvaldo; Carlos, Luciano; Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials; MDPI; Inorganics; 11; 1; 1-2023; 1-132304-6740CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2304-6740/11/1/46info:eu-repo/semantics/altIdentifier/doi/10.3390/inorganics11010046info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:00:33Zoai:ri.conicet.gov.ar:11336/227619instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:00:33.297CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials
title Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials
spellingShingle Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials
Peralta, Marcos Emanuel
GREEN CHEMISTRY
MAGNETIC NANOPARTICLES
MAGNETITE
SOLVOTHERMAL SYNTHESIS
WASTE VALORIZATION
title_short Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials
title_full Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials
title_fullStr Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials
title_full_unstemmed Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials
title_sort Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials
dc.creator.none.fl_str_mv Peralta, Marcos Emanuel
Koffman Frischknecht, Alejandro
Moreno, Mario Sergio Jesus
Martire, Daniel Osvaldo
Carlos, Luciano
author Peralta, Marcos Emanuel
author_facet Peralta, Marcos Emanuel
Koffman Frischknecht, Alejandro
Moreno, Mario Sergio Jesus
Martire, Daniel Osvaldo
Carlos, Luciano
author_role author
author2 Koffman Frischknecht, Alejandro
Moreno, Mario Sergio Jesus
Martire, Daniel Osvaldo
Carlos, Luciano
author2_role author
author
author
author
dc.subject.none.fl_str_mv GREEN CHEMISTRY
MAGNETIC NANOPARTICLES
MAGNETITE
SOLVOTHERMAL SYNTHESIS
WASTE VALORIZATION
topic GREEN CHEMISTRY
MAGNETIC NANOPARTICLES
MAGNETITE
SOLVOTHERMAL SYNTHESIS
WASTE VALORIZATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We propose here a novel green synthesis route of core-shell magnetic nanomaterials based on the polyol method, which uses bio-based substances (BBS) derived from biowaste, as stabilizer and directing agent. First, we studied the effect of BBS concentration on the size, morphology, and composition of magnetic iron oxides nanoparticles obtained in the presence of BBS via the polyol synthesis method (MBBS). Then, as a proof of concept, we further coated MBBS with mesoporous silica (MBBS@mSiO2) or titanium dioxide (MBBS@TiO2) to obtain magnetic nanostructured core-shell materials. All the materials were deeply characterized with diverse physicochemical techniques. Results showed that both the size of the nanocrystals and their aggregation strongly depend on the BBS concentration used in the synthesis: the higher the concentration of BBS, the smaller the sizes of the iron oxide nanoparticles. On the other hand, the as-prepared magnetic core-shell nanomaterials were applied with good performance in different systems. In particular, MBBS@SiO2 showed to be an excellent nanocarrier of ibuprofen and successful adsorbent of methylene blue (MB) from aqueous solution. MBBS@TiO2 was capable of degrading MB with the same efficiency of pristine TiO2. These excellent results encourage the use of bio-based substances in different types of synthesis methods since they could reduce the fabrication costs and the environmental impact.
Fil: Peralta, Marcos Emanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Koffman Frischknecht, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Moreno, Mario Sergio Jesus. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
description We propose here a novel green synthesis route of core-shell magnetic nanomaterials based on the polyol method, which uses bio-based substances (BBS) derived from biowaste, as stabilizer and directing agent. First, we studied the effect of BBS concentration on the size, morphology, and composition of magnetic iron oxides nanoparticles obtained in the presence of BBS via the polyol synthesis method (MBBS). Then, as a proof of concept, we further coated MBBS with mesoporous silica (MBBS@mSiO2) or titanium dioxide (MBBS@TiO2) to obtain magnetic nanostructured core-shell materials. All the materials were deeply characterized with diverse physicochemical techniques. Results showed that both the size of the nanocrystals and their aggregation strongly depend on the BBS concentration used in the synthesis: the higher the concentration of BBS, the smaller the sizes of the iron oxide nanoparticles. On the other hand, the as-prepared magnetic core-shell nanomaterials were applied with good performance in different systems. In particular, MBBS@SiO2 showed to be an excellent nanocarrier of ibuprofen and successful adsorbent of methylene blue (MB) from aqueous solution. MBBS@TiO2 was capable of degrading MB with the same efficiency of pristine TiO2. These excellent results encourage the use of bio-based substances in different types of synthesis methods since they could reduce the fabrication costs and the environmental impact.
publishDate 2023
dc.date.none.fl_str_mv 2023-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/227619
Peralta, Marcos Emanuel; Koffman Frischknecht, Alejandro; Moreno, Mario Sergio Jesus; Martire, Daniel Osvaldo; Carlos, Luciano; Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials; MDPI; Inorganics; 11; 1; 1-2023; 1-13
2304-6740
CONICET Digital
CONICET
url http://hdl.handle.net/11336/227619
identifier_str_mv Peralta, Marcos Emanuel; Koffman Frischknecht, Alejandro; Moreno, Mario Sergio Jesus; Martire, Daniel Osvaldo; Carlos, Luciano; Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials; MDPI; Inorganics; 11; 1; 1-2023; 1-13
2304-6740
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2304-6740/11/1/46
info:eu-repo/semantics/altIdentifier/doi/10.3390/inorganics11010046
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
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dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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