Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films

Autores
Isola, Lucio Manuel; Malvasio, Bruno Federico; Giordana, María Florencia; Malarria, Jorge Alberto
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The wide-spread multiple transformation in Ti-rich Ni-Ti shape memory alloys produced by Ti2Ni nano-precipitates was investigated. For this purpose, a series of amorphous Ti-Ni-Co thin films with the same composition were subjected to different annealing treatments. The characteristic temperatures and heat of the transformations were measured by four-point probe resistivity and differential scanning calorimetry. A critical review of the thermodynamics of thermally-induced thermoelastic martensitic transformations is presented. The values of the frictional work and the stored elastic energy associated with the thermoelastic transformations were assessed from the transformation temperatures, and related with the transformation heats measured in the samples annealed at different temperatures. It was observed that the stored elastic energy decreases as the annealing temperature rises due to a change in the distribution of the Ti2Ni precipitates, in concordance with an increase of the transformation heat measured by the calorimeter. Nevertheless, the values of the frictional work were independent of the annealing temperature. The influence of the dissipation of the stored elastic energy on the transformation temperatures and thermal hysteresis is discussed. Finally, a better understanding of the wide-spread multiple transformation, as an effect of the local stresses introduced by Ti2Ni nano-precipitates in the matrix, is proposed.
Fil: Isola, Lucio Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Fil: Malvasio, Bruno Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Fil: Giordana, María Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Fil: Malarria, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Materia
MARTENSITIC PHASE TRANSFORMATION
NI-TI SHAPE MEMORY ALLOYS
SPUTTERING
THERMAL HYSTERESIS
THERMODYNAMICS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/148715
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/148715
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin filmsIsola, Lucio ManuelMalvasio, Bruno FedericoGiordana, María FlorenciaMalarria, Jorge AlbertoMARTENSITIC PHASE TRANSFORMATIONNI-TI SHAPE MEMORY ALLOYSSPUTTERINGTHERMAL HYSTERESISTHERMODYNAMICShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The wide-spread multiple transformation in Ti-rich Ni-Ti shape memory alloys produced by Ti2Ni nano-precipitates was investigated. For this purpose, a series of amorphous Ti-Ni-Co thin films with the same composition were subjected to different annealing treatments. The characteristic temperatures and heat of the transformations were measured by four-point probe resistivity and differential scanning calorimetry. A critical review of the thermodynamics of thermally-induced thermoelastic martensitic transformations is presented. The values of the frictional work and the stored elastic energy associated with the thermoelastic transformations were assessed from the transformation temperatures, and related with the transformation heats measured in the samples annealed at different temperatures. It was observed that the stored elastic energy decreases as the annealing temperature rises due to a change in the distribution of the Ti2Ni precipitates, in concordance with an increase of the transformation heat measured by the calorimeter. Nevertheless, the values of the frictional work were independent of the annealing temperature. The influence of the dissipation of the stored elastic energy on the transformation temperatures and thermal hysteresis is discussed. Finally, a better understanding of the wide-spread multiple transformation, as an effect of the local stresses introduced by Ti2Ni nano-precipitates in the matrix, is proposed.Fil: Isola, Lucio Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; ArgentinaFil: Malvasio, Bruno Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; ArgentinaFil: Giordana, María Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; ArgentinaFil: Malarria, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; ArgentinaElsevier Science2020-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/148715Isola, Lucio Manuel; Malvasio, Bruno Federico; Giordana, María Florencia; Malarria, Jorge Alberto; Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films; Elsevier Science; Journal of Alloys and Compounds; 818; 3-2020; 1-310925-8388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0925838819341507info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2019.152904info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:02:52Zoai:ri.conicet.gov.ar:11336/148715instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:02:52.518CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films
title Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films
spellingShingle Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films
Isola, Lucio Manuel
MARTENSITIC PHASE TRANSFORMATION
NI-TI SHAPE MEMORY ALLOYS
SPUTTERING
THERMAL HYSTERESIS
THERMODYNAMICS
title_short Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films
title_full Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films
title_fullStr Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films
title_full_unstemmed Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films
title_sort Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films
dc.creator.none.fl_str_mv Isola, Lucio Manuel
Malvasio, Bruno Federico
Giordana, María Florencia
Malarria, Jorge Alberto
author Isola, Lucio Manuel
author_facet Isola, Lucio Manuel
Malvasio, Bruno Federico
Giordana, María Florencia
Malarria, Jorge Alberto
author_role author
author2 Malvasio, Bruno Federico
Giordana, María Florencia
Malarria, Jorge Alberto
author2_role author
author
author
dc.subject.none.fl_str_mv MARTENSITIC PHASE TRANSFORMATION
NI-TI SHAPE MEMORY ALLOYS
SPUTTERING
THERMAL HYSTERESIS
THERMODYNAMICS
topic MARTENSITIC PHASE TRANSFORMATION
NI-TI SHAPE MEMORY ALLOYS
SPUTTERING
THERMAL HYSTERESIS
THERMODYNAMICS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The wide-spread multiple transformation in Ti-rich Ni-Ti shape memory alloys produced by Ti2Ni nano-precipitates was investigated. For this purpose, a series of amorphous Ti-Ni-Co thin films with the same composition were subjected to different annealing treatments. The characteristic temperatures and heat of the transformations were measured by four-point probe resistivity and differential scanning calorimetry. A critical review of the thermodynamics of thermally-induced thermoelastic martensitic transformations is presented. The values of the frictional work and the stored elastic energy associated with the thermoelastic transformations were assessed from the transformation temperatures, and related with the transformation heats measured in the samples annealed at different temperatures. It was observed that the stored elastic energy decreases as the annealing temperature rises due to a change in the distribution of the Ti2Ni precipitates, in concordance with an increase of the transformation heat measured by the calorimeter. Nevertheless, the values of the frictional work were independent of the annealing temperature. The influence of the dissipation of the stored elastic energy on the transformation temperatures and thermal hysteresis is discussed. Finally, a better understanding of the wide-spread multiple transformation, as an effect of the local stresses introduced by Ti2Ni nano-precipitates in the matrix, is proposed.
Fil: Isola, Lucio Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Fil: Malvasio, Bruno Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Fil: Giordana, María Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Fil: Malarria, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
description The wide-spread multiple transformation in Ti-rich Ni-Ti shape memory alloys produced by Ti2Ni nano-precipitates was investigated. For this purpose, a series of amorphous Ti-Ni-Co thin films with the same composition were subjected to different annealing treatments. The characteristic temperatures and heat of the transformations were measured by four-point probe resistivity and differential scanning calorimetry. A critical review of the thermodynamics of thermally-induced thermoelastic martensitic transformations is presented. The values of the frictional work and the stored elastic energy associated with the thermoelastic transformations were assessed from the transformation temperatures, and related with the transformation heats measured in the samples annealed at different temperatures. It was observed that the stored elastic energy decreases as the annealing temperature rises due to a change in the distribution of the Ti2Ni precipitates, in concordance with an increase of the transformation heat measured by the calorimeter. Nevertheless, the values of the frictional work were independent of the annealing temperature. The influence of the dissipation of the stored elastic energy on the transformation temperatures and thermal hysteresis is discussed. Finally, a better understanding of the wide-spread multiple transformation, as an effect of the local stresses introduced by Ti2Ni nano-precipitates in the matrix, is proposed.
publishDate 2020
dc.date.none.fl_str_mv 2020-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/148715
Isola, Lucio Manuel; Malvasio, Bruno Federico; Giordana, María Florencia; Malarria, Jorge Alberto; Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films; Elsevier Science; Journal of Alloys and Compounds; 818; 3-2020; 1-31
0925-8388
CONICET Digital
CONICET
url http://hdl.handle.net/11336/148715
identifier_str_mv Isola, Lucio Manuel; Malvasio, Bruno Federico; Giordana, María Florencia; Malarria, Jorge Alberto; Effect of the precipitates on the thermodynamics of the martensitic transformations in Ti-rich Ni-Ti-Co thin films; Elsevier Science; Journal of Alloys and Compounds; 818; 3-2020; 1-31
0925-8388
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0925838819341507
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2019.152904
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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