High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate

Autores
Romagnoli, Roberto; del Amo, Delia Beatriz; Vetere, Vicente Francisco; Vèleva, L.
Año de publicación
2000
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Zinc molybdenum phosphate belongs to the so called second generation phosphate pigments and is claimed to have equal or greater anticorrosive properties than chromates and better than zinc phosphate alone. Little Information is available in the literature about its anticorrosive performance. The aim o f this research was to stucfy the anticorrosive performance o f zinc molybdenum phosphate in solvent borne epoxy paints employing two anticorrosive pigment loadings. The effect o f incorporating zinc oxide as complemetary pigm ent was also studied SAE 1010 Steel ponéis were prim ed and coated with three different paint systems containing the anticorrosive paint and this paint plus a sealer cmd/or a topcoat. The anticorrosive efftciency o f the different paint systems was assessed by accelerated tests (salí spray, humidity and accelerated weathering). Electrochemical measurements were done employing the anticorrosive paints alone. Results showed that the highest anticorrosive effect was obtained employing 30% o f zinc molybdenum phosphate. Polarization measurements showed that the anoche film form ed on Steel blocked the active sites fo r oxygen reduction. The incorporation o f zinc oxide to pigment form ula was detrim ental due to its high water absorption and to the fa ct that it reduced zinc molybdenum phosphate solubility by the common ion effect. Polarization curves o f pigm ents mixtures could be used as a guideline to precüct the anticorrosive coating perform ance in accelerated and electrochemical tests. However, the fin a l decisión on pigm ent selection musí be taken on the basis o f accelerated triáis.
Fil: Romagnoli, Roberto. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: del Amo, Delia Beatriz. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Vetere, Vicente Francisco. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Vèleva, L.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Materia
ZINC MOLYBDENUM PHOSPHATE
EPOXY ANTICORROSIVE PAINTS
ZINC OXIDE
ACCELERATED TESTS
ELECTROCHEMICAL TESTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/151897
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/151897
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphatePinturas epoxidicas anticorrosivas de alta eficiencia pigmentadas con fosfato de cinc modificado con moubdato de cincRomagnoli, Robertodel Amo, Delia BeatrizVetere, Vicente FranciscoVèleva, L.ZINC MOLYBDENUM PHOSPHATEEPOXY ANTICORROSIVE PAINTSZINC OXIDEACCELERATED TESTSELECTROCHEMICAL TESTShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Zinc molybdenum phosphate belongs to the so called second generation phosphate pigments and is claimed to have equal or greater anticorrosive properties than chromates and better than zinc phosphate alone. Little Information is available in the literature about its anticorrosive performance. The aim o f this research was to stucfy the anticorrosive performance o f zinc molybdenum phosphate in solvent borne epoxy paints employing two anticorrosive pigment loadings. The effect o f incorporating zinc oxide as complemetary pigm ent was also studied SAE 1010 Steel ponéis were prim ed and coated with three different paint systems containing the anticorrosive paint and this paint plus a sealer cmd/or a topcoat. The anticorrosive efftciency o f the different paint systems was assessed by accelerated tests (salí spray, humidity and accelerated weathering). Electrochemical measurements were done employing the anticorrosive paints alone. Results showed that the highest anticorrosive effect was obtained employing 30% o f zinc molybdenum phosphate. Polarization measurements showed that the anoche film form ed on Steel blocked the active sites fo r oxygen reduction. The incorporation o f zinc oxide to pigment form ula was detrim ental due to its high water absorption and to the fa ct that it reduced zinc molybdenum phosphate solubility by the common ion effect. Polarization curves o f pigm ents mixtures could be used as a guideline to precüct the anticorrosive coating perform ance in accelerated and electrochemical tests. However, the fin a l decisión on pigm ent selection musí be taken on the basis o f accelerated triáis.Fil: Romagnoli, Roberto. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: del Amo, Delia Beatriz. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Vetere, Vicente Francisco. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Vèleva, L.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; ArgentinaOil & Colour Chemists Assoc2000-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/mswordapplication/pdfhttp://hdl.handle.net/11336/151897Romagnoli, Roberto; del Amo, Delia Beatriz; Vetere, Vicente Francisco; Vèleva, L.; High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate; Oil & Colour Chemists Assoc; Surface Coatings International; 83; 1; 1-2000; 27-311356-0751CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/BF02692684info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/BF02692684info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:01:23Zoai:ri.conicet.gov.ar:11336/151897instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:01:24.572CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate
Pinturas epoxidicas anticorrosivas de alta eficiencia pigmentadas con fosfato de cinc modificado con moubdato de cinc
title High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate
spellingShingle High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate
Romagnoli, Roberto
ZINC MOLYBDENUM PHOSPHATE
EPOXY ANTICORROSIVE PAINTS
ZINC OXIDE
ACCELERATED TESTS
ELECTROCHEMICAL TESTS
title_short High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate
title_full High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate
title_fullStr High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate
title_full_unstemmed High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate
title_sort High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate
dc.creator.none.fl_str_mv Romagnoli, Roberto
del Amo, Delia Beatriz
Vetere, Vicente Francisco
Vèleva, L.
author Romagnoli, Roberto
author_facet Romagnoli, Roberto
del Amo, Delia Beatriz
Vetere, Vicente Francisco
Vèleva, L.
author_role author
author2 del Amo, Delia Beatriz
Vetere, Vicente Francisco
Vèleva, L.
author2_role author
author
author
dc.subject.none.fl_str_mv ZINC MOLYBDENUM PHOSPHATE
EPOXY ANTICORROSIVE PAINTS
ZINC OXIDE
ACCELERATED TESTS
ELECTROCHEMICAL TESTS
topic ZINC MOLYBDENUM PHOSPHATE
EPOXY ANTICORROSIVE PAINTS
ZINC OXIDE
ACCELERATED TESTS
ELECTROCHEMICAL TESTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Zinc molybdenum phosphate belongs to the so called second generation phosphate pigments and is claimed to have equal or greater anticorrosive properties than chromates and better than zinc phosphate alone. Little Information is available in the literature about its anticorrosive performance. The aim o f this research was to stucfy the anticorrosive performance o f zinc molybdenum phosphate in solvent borne epoxy paints employing two anticorrosive pigment loadings. The effect o f incorporating zinc oxide as complemetary pigm ent was also studied SAE 1010 Steel ponéis were prim ed and coated with three different paint systems containing the anticorrosive paint and this paint plus a sealer cmd/or a topcoat. The anticorrosive efftciency o f the different paint systems was assessed by accelerated tests (salí spray, humidity and accelerated weathering). Electrochemical measurements were done employing the anticorrosive paints alone. Results showed that the highest anticorrosive effect was obtained employing 30% o f zinc molybdenum phosphate. Polarization measurements showed that the anoche film form ed on Steel blocked the active sites fo r oxygen reduction. The incorporation o f zinc oxide to pigment form ula was detrim ental due to its high water absorption and to the fa ct that it reduced zinc molybdenum phosphate solubility by the common ion effect. Polarization curves o f pigm ents mixtures could be used as a guideline to precüct the anticorrosive coating perform ance in accelerated and electrochemical tests. However, the fin a l decisión on pigm ent selection musí be taken on the basis o f accelerated triáis.
Fil: Romagnoli, Roberto. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: del Amo, Delia Beatriz. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Vetere, Vicente Francisco. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Vèleva, L.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
description Zinc molybdenum phosphate belongs to the so called second generation phosphate pigments and is claimed to have equal or greater anticorrosive properties than chromates and better than zinc phosphate alone. Little Information is available in the literature about its anticorrosive performance. The aim o f this research was to stucfy the anticorrosive performance o f zinc molybdenum phosphate in solvent borne epoxy paints employing two anticorrosive pigment loadings. The effect o f incorporating zinc oxide as complemetary pigm ent was also studied SAE 1010 Steel ponéis were prim ed and coated with three different paint systems containing the anticorrosive paint and this paint plus a sealer cmd/or a topcoat. The anticorrosive efftciency o f the different paint systems was assessed by accelerated tests (salí spray, humidity and accelerated weathering). Electrochemical measurements were done employing the anticorrosive paints alone. Results showed that the highest anticorrosive effect was obtained employing 30% o f zinc molybdenum phosphate. Polarization measurements showed that the anoche film form ed on Steel blocked the active sites fo r oxygen reduction. The incorporation o f zinc oxide to pigment form ula was detrim ental due to its high water absorption and to the fa ct that it reduced zinc molybdenum phosphate solubility by the common ion effect. Polarization curves o f pigm ents mixtures could be used as a guideline to precüct the anticorrosive coating perform ance in accelerated and electrochemical tests. However, the fin a l decisión on pigm ent selection musí be taken on the basis o f accelerated triáis.
publishDate 2000
dc.date.none.fl_str_mv 2000-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/151897
Romagnoli, Roberto; del Amo, Delia Beatriz; Vetere, Vicente Francisco; Vèleva, L.; High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate; Oil & Colour Chemists Assoc; Surface Coatings International; 83; 1; 1-2000; 27-31
1356-0751
CONICET Digital
CONICET
url http://hdl.handle.net/11336/151897
identifier_str_mv Romagnoli, Roberto; del Amo, Delia Beatriz; Vetere, Vicente Francisco; Vèleva, L.; High performance anticorrosive epoxy paints pigmented with zinc molybdenum phosphate; Oil & Colour Chemists Assoc; Surface Coatings International; 83; 1; 1-2000; 27-31
1356-0751
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/BF02692684
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/BF02692684
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/msword
application/pdf
dc.publisher.none.fl_str_mv Oil & Colour Chemists Assoc
publisher.none.fl_str_mv Oil & Colour Chemists Assoc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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