A mesoionic carbene complex of manganese in five oxidation states

Autores
Wittwer, Benjamin; Dickmann, Nicole; Berg, Stephan; Leitner, Daniel; Tesi, Lorenzo; Hunger, David; Gratzl, Raphael; van Slageren, Joris; Neuman, Nicolás Ignacio; Munz, Dominik; Hohloch, Stephan
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Reaction between a carbazole-based mesoionic carbene ligand and manganese(ii) iodide results in the formation of a rare air-stable manganese(iv) complex after aerobic workup. Cyclic voltammetry reveals the complex to be stable in five oxidation states. The electronic structure of all five oxidation states is elucidated chemically, spectroscopically (NMR, high-frequency EPR, UV-Vis, MCD), magnetically, and computationally (DFT, CASSCF).
Fil: Wittwer, Benjamin. Universidad de Innsbruck; Austria
Fil: Dickmann, Nicole. University of Paderborn; Alemania
Fil: Berg, Stephan. University of Paderborn; Alemania
Fil: Leitner, Daniel. Universidad de Innsbruck; Austria
Fil: Tesi, Lorenzo. Universitat Stuttgart; Alemania
Fil: Hunger, David. Universitat Stuttgart; Alemania
Fil: Gratzl, Raphael. Universidad de Innsbruck; Austria
Fil: van Slageren, Joris. Universitat Stuttgart; Alemania
Fil: Neuman, Nicolás Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Universitat Stuttgart; Alemania
Fil: Munz, Dominik. Universitat Saarland; Alemania. Universitat Erlangen Nuremberg; Alemania
Fil: Hohloch, Stephan. Universidad de Innsbruck; Austria
Materia
MESOIONIC
CARBENE
MANGANESE
CARBAZOLE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/216206
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/216206
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A mesoionic carbene complex of manganese in five oxidation statesWittwer, BenjaminDickmann, NicoleBerg, StephanLeitner, DanielTesi, LorenzoHunger, DavidGratzl, Raphaelvan Slageren, JorisNeuman, Nicolás IgnacioMunz, DominikHohloch, StephanMESOIONICCARBENEMANGANESECARBAZOLEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Reaction between a carbazole-based mesoionic carbene ligand and manganese(ii) iodide results in the formation of a rare air-stable manganese(iv) complex after aerobic workup. Cyclic voltammetry reveals the complex to be stable in five oxidation states. The electronic structure of all five oxidation states is elucidated chemically, spectroscopically (NMR, high-frequency EPR, UV-Vis, MCD), magnetically, and computationally (DFT, CASSCF).Fil: Wittwer, Benjamin. Universidad de Innsbruck; AustriaFil: Dickmann, Nicole. University of Paderborn; AlemaniaFil: Berg, Stephan. University of Paderborn; AlemaniaFil: Leitner, Daniel. Universidad de Innsbruck; AustriaFil: Tesi, Lorenzo. Universitat Stuttgart; AlemaniaFil: Hunger, David. Universitat Stuttgart; AlemaniaFil: Gratzl, Raphael. Universidad de Innsbruck; AustriaFil: van Slageren, Joris. Universitat Stuttgart; AlemaniaFil: Neuman, Nicolás Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Universitat Stuttgart; AlemaniaFil: Munz, Dominik. Universitat Saarland; Alemania. Universitat Erlangen Nuremberg; AlemaniaFil: Hohloch, Stephan. Universidad de Innsbruck; AustriaRoyal Society of Chemistry2022-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/216206Wittwer, Benjamin; Dickmann, Nicole; Berg, Stephan; Leitner, Daniel; Tesi, Lorenzo; et al.; A mesoionic carbene complex of manganese in five oxidation states; Royal Society of Chemistry; Chemical Communications; 58; 41; 4-2022; 6096-60991359-7345CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/D2CC00097Kinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2022/CC/D2CC00097Kinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:53:02Zoai:ri.conicet.gov.ar:11336/216206instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:53:02.77CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A mesoionic carbene complex of manganese in five oxidation states
title A mesoionic carbene complex of manganese in five oxidation states
spellingShingle A mesoionic carbene complex of manganese in five oxidation states
Wittwer, Benjamin
MESOIONIC
CARBENE
MANGANESE
CARBAZOLE
title_short A mesoionic carbene complex of manganese in five oxidation states
title_full A mesoionic carbene complex of manganese in five oxidation states
title_fullStr A mesoionic carbene complex of manganese in five oxidation states
title_full_unstemmed A mesoionic carbene complex of manganese in five oxidation states
title_sort A mesoionic carbene complex of manganese in five oxidation states
dc.creator.none.fl_str_mv Wittwer, Benjamin
Dickmann, Nicole
Berg, Stephan
Leitner, Daniel
Tesi, Lorenzo
Hunger, David
Gratzl, Raphael
van Slageren, Joris
Neuman, Nicolás Ignacio
Munz, Dominik
Hohloch, Stephan
author Wittwer, Benjamin
author_facet Wittwer, Benjamin
Dickmann, Nicole
Berg, Stephan
Leitner, Daniel
Tesi, Lorenzo
Hunger, David
Gratzl, Raphael
van Slageren, Joris
Neuman, Nicolás Ignacio
Munz, Dominik
Hohloch, Stephan
author_role author
author2 Dickmann, Nicole
Berg, Stephan
Leitner, Daniel
Tesi, Lorenzo
Hunger, David
Gratzl, Raphael
van Slageren, Joris
Neuman, Nicolás Ignacio
Munz, Dominik
Hohloch, Stephan
author2_role author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv MESOIONIC
CARBENE
MANGANESE
CARBAZOLE
topic MESOIONIC
CARBENE
MANGANESE
CARBAZOLE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Reaction between a carbazole-based mesoionic carbene ligand and manganese(ii) iodide results in the formation of a rare air-stable manganese(iv) complex after aerobic workup. Cyclic voltammetry reveals the complex to be stable in five oxidation states. The electronic structure of all five oxidation states is elucidated chemically, spectroscopically (NMR, high-frequency EPR, UV-Vis, MCD), magnetically, and computationally (DFT, CASSCF).
Fil: Wittwer, Benjamin. Universidad de Innsbruck; Austria
Fil: Dickmann, Nicole. University of Paderborn; Alemania
Fil: Berg, Stephan. University of Paderborn; Alemania
Fil: Leitner, Daniel. Universidad de Innsbruck; Austria
Fil: Tesi, Lorenzo. Universitat Stuttgart; Alemania
Fil: Hunger, David. Universitat Stuttgart; Alemania
Fil: Gratzl, Raphael. Universidad de Innsbruck; Austria
Fil: van Slageren, Joris. Universitat Stuttgart; Alemania
Fil: Neuman, Nicolás Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Universitat Stuttgart; Alemania
Fil: Munz, Dominik. Universitat Saarland; Alemania. Universitat Erlangen Nuremberg; Alemania
Fil: Hohloch, Stephan. Universidad de Innsbruck; Austria
description Reaction between a carbazole-based mesoionic carbene ligand and manganese(ii) iodide results in the formation of a rare air-stable manganese(iv) complex after aerobic workup. Cyclic voltammetry reveals the complex to be stable in five oxidation states. The electronic structure of all five oxidation states is elucidated chemically, spectroscopically (NMR, high-frequency EPR, UV-Vis, MCD), magnetically, and computationally (DFT, CASSCF).
publishDate 2022
dc.date.none.fl_str_mv 2022-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/216206
Wittwer, Benjamin; Dickmann, Nicole; Berg, Stephan; Leitner, Daniel; Tesi, Lorenzo; et al.; A mesoionic carbene complex of manganese in five oxidation states; Royal Society of Chemistry; Chemical Communications; 58; 41; 4-2022; 6096-6099
1359-7345
CONICET Digital
CONICET
url http://hdl.handle.net/11336/216206
identifier_str_mv Wittwer, Benjamin; Dickmann, Nicole; Berg, Stephan; Leitner, Daniel; Tesi, Lorenzo; et al.; A mesoionic carbene complex of manganese in five oxidation states; Royal Society of Chemistry; Chemical Communications; 58; 41; 4-2022; 6096-6099
1359-7345
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/D2CC00097K
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2022/CC/D2CC00097K
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613624391270400
score 13.070432

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