Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials

Autores
Vaschetto, Eliana Gabriela; Pecchi Sanchez, Gina Angela; Casuscelli, Sandra Graciela; Eimer, Griselda Alejandra
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
B-MCM-41 type nano-structured materials were prepared by direct hydrothermal synthesis. The time of hydrothermal treatment, the Si/B initial molar ratio and the nature of the hydroxide source in the synthesis process were analyzed. All the materials were characterized by XRD, N2 adsorption, TEM, SEM, ICP-OES, FT-IR and adsorption of pyridine coupled to FT-IR spectroscopy. The role of hydroxide source is essential to achieve the incorporation of boron in the mesoporous structure. The relationship between the Boron content in the synthesis gel, the degree of introduction of tetra-coordinated B into the framework, the formation of nest silanols and the relative density of the acidic sites have been discussed. We could corroborate that hydroxyl groups present in silanol nests are the direct responsible of the moderate Brønsted acidity of our materials. The enhancement in the density of acidic nest silanols was reached by increasing the B content in the mesoporous structure. Finally, the use of NH4OH, as hydroxide source, Si/B initial molar ratio of 10 and 20 and a hydrothermal treatment of 6 days resulted the optimum synthesis conditions to obtain the highest framework B incorporation and more abundant moderate Brønsted sites (silanol nests), thus improving the potential catalytic properties of these materials.
Fil: Vaschetto, Eliana Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Pecchi Sanchez, Gina Angela. Universidad de Concepción; Chile
Fil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Materia
B-MCM-41
MESOPOROUS MATERIALS
MODERATE ACIDITY
SILANOL NESTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31977
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31977
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materialsVaschetto, Eliana GabrielaPecchi Sanchez, Gina AngelaCasuscelli, Sandra GracielaEimer, Griselda AlejandraB-MCM-41MESOPOROUS MATERIALSMODERATE ACIDITYSILANOL NESTShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2B-MCM-41 type nano-structured materials were prepared by direct hydrothermal synthesis. The time of hydrothermal treatment, the Si/B initial molar ratio and the nature of the hydroxide source in the synthesis process were analyzed. All the materials were characterized by XRD, N2 adsorption, TEM, SEM, ICP-OES, FT-IR and adsorption of pyridine coupled to FT-IR spectroscopy. The role of hydroxide source is essential to achieve the incorporation of boron in the mesoporous structure. The relationship between the Boron content in the synthesis gel, the degree of introduction of tetra-coordinated B into the framework, the formation of nest silanols and the relative density of the acidic sites have been discussed. We could corroborate that hydroxyl groups present in silanol nests are the direct responsible of the moderate Brønsted acidity of our materials. The enhancement in the density of acidic nest silanols was reached by increasing the B content in the mesoporous structure. Finally, the use of NH4OH, as hydroxide source, Si/B initial molar ratio of 10 and 20 and a hydrothermal treatment of 6 days resulted the optimum synthesis conditions to obtain the highest framework B incorporation and more abundant moderate Brønsted sites (silanol nests), thus improving the potential catalytic properties of these materials.Fil: Vaschetto, Eliana Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Pecchi Sanchez, Gina Angela. Universidad de Concepción; ChileFil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaElsevier Science2016-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31977Vaschetto, Eliana Gabriela; Pecchi Sanchez, Gina Angela; Casuscelli, Sandra Graciela; Eimer, Griselda Alejandra; Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials; Elsevier Science; Microporous and Mesoporous Materials; 258; 6-2016; 269-2761387-1811CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2016.06.039info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1387181116302414info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:57:14Zoai:ri.conicet.gov.ar:11336/31977instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:57:14.458CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials
title Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials
spellingShingle Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials
Vaschetto, Eliana Gabriela
B-MCM-41
MESOPOROUS MATERIALS
MODERATE ACIDITY
SILANOL NESTS
title_short Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials
title_full Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials
title_fullStr Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials
title_full_unstemmed Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials
title_sort Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials
dc.creator.none.fl_str_mv Vaschetto, Eliana Gabriela
Pecchi Sanchez, Gina Angela
Casuscelli, Sandra Graciela
Eimer, Griselda Alejandra
author Vaschetto, Eliana Gabriela
author_facet Vaschetto, Eliana Gabriela
Pecchi Sanchez, Gina Angela
Casuscelli, Sandra Graciela
Eimer, Griselda Alejandra
author_role author
author2 Pecchi Sanchez, Gina Angela
Casuscelli, Sandra Graciela
Eimer, Griselda Alejandra
author2_role author
author
author
dc.subject.none.fl_str_mv B-MCM-41
MESOPOROUS MATERIALS
MODERATE ACIDITY
SILANOL NESTS
topic B-MCM-41
MESOPOROUS MATERIALS
MODERATE ACIDITY
SILANOL NESTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv B-MCM-41 type nano-structured materials were prepared by direct hydrothermal synthesis. The time of hydrothermal treatment, the Si/B initial molar ratio and the nature of the hydroxide source in the synthesis process were analyzed. All the materials were characterized by XRD, N2 adsorption, TEM, SEM, ICP-OES, FT-IR and adsorption of pyridine coupled to FT-IR spectroscopy. The role of hydroxide source is essential to achieve the incorporation of boron in the mesoporous structure. The relationship between the Boron content in the synthesis gel, the degree of introduction of tetra-coordinated B into the framework, the formation of nest silanols and the relative density of the acidic sites have been discussed. We could corroborate that hydroxyl groups present in silanol nests are the direct responsible of the moderate Brønsted acidity of our materials. The enhancement in the density of acidic nest silanols was reached by increasing the B content in the mesoporous structure. Finally, the use of NH4OH, as hydroxide source, Si/B initial molar ratio of 10 and 20 and a hydrothermal treatment of 6 days resulted the optimum synthesis conditions to obtain the highest framework B incorporation and more abundant moderate Brønsted sites (silanol nests), thus improving the potential catalytic properties of these materials.
Fil: Vaschetto, Eliana Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Pecchi Sanchez, Gina Angela. Universidad de Concepción; Chile
Fil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
description B-MCM-41 type nano-structured materials were prepared by direct hydrothermal synthesis. The time of hydrothermal treatment, the Si/B initial molar ratio and the nature of the hydroxide source in the synthesis process were analyzed. All the materials were characterized by XRD, N2 adsorption, TEM, SEM, ICP-OES, FT-IR and adsorption of pyridine coupled to FT-IR spectroscopy. The role of hydroxide source is essential to achieve the incorporation of boron in the mesoporous structure. The relationship between the Boron content in the synthesis gel, the degree of introduction of tetra-coordinated B into the framework, the formation of nest silanols and the relative density of the acidic sites have been discussed. We could corroborate that hydroxyl groups present in silanol nests are the direct responsible of the moderate Brønsted acidity of our materials. The enhancement in the density of acidic nest silanols was reached by increasing the B content in the mesoporous structure. Finally, the use of NH4OH, as hydroxide source, Si/B initial molar ratio of 10 and 20 and a hydrothermal treatment of 6 days resulted the optimum synthesis conditions to obtain the highest framework B incorporation and more abundant moderate Brønsted sites (silanol nests), thus improving the potential catalytic properties of these materials.
publishDate 2016
dc.date.none.fl_str_mv 2016-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31977
Vaschetto, Eliana Gabriela; Pecchi Sanchez, Gina Angela; Casuscelli, Sandra Graciela; Eimer, Griselda Alejandra; Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials; Elsevier Science; Microporous and Mesoporous Materials; 258; 6-2016; 269-276
1387-1811
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31977
identifier_str_mv Vaschetto, Eliana Gabriela; Pecchi Sanchez, Gina Angela; Casuscelli, Sandra Graciela; Eimer, Griselda Alejandra; Influence of the synthesis conditions on the incorporation of B and the acidity in B-MCM-41 materials; Elsevier Science; Microporous and Mesoporous Materials; 258; 6-2016; 269-276
1387-1811
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2016.06.039
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1387181116302414
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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