Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils

Autores
Bertero, Melisa Paola; García, Juan Rafael; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Matrices of FCC catalysts with different content of alumina and the compound catalysts prepared with them including Y zeolite were used to upgrade bio-oils from pine wood sawdust and soybean shell. The biomasses were selected according to their different lignin content which results in very different proportions of phenolic compounds (coke precursors) in the respective bio-oils. The bio-oils were produced by fast pyrolysis and the vapours were immediately upgraded over a fixed bed of catalyst at 550 °C using a mass catalyst/bio-oil relationship of 3.5. In terms of hydrocarbon yield, the matrices were more effective in deoxygenating pine wood sawdust bio-oil and the compound catalysts in deoxygenating soybean shell bio-oil. These differences can be the consequence of the different compositions of the bio-oils which, in the case of pine wood sawdust, includes a significant concentration of phenolic ethers which form coke on the matrix and the external surface of the zeolite, thus preventing lighter compounds from accessing the micropore system of the compound catalysts. Pine sawdust bio-oil produced more coke than soybean shell bio-oil; in the case of compound catalysts, coke deposited preferentially on the catalyst matrix, thus decreasing its mesopore specific surface area up to 65 %.
Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Bio-Oil
Biomass
Fcc
Fuels
Silica&Ndash;Alumina
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/63474
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/63474
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oilsBertero, Melisa PaolaGarcía, Juan RafaelFalco, Marisa GuadalupeSedran, Ulises AnselmoBio-OilBiomassFccFuelsSilica&Ndash;Aluminahttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Matrices of FCC catalysts with different content of alumina and the compound catalysts prepared with them including Y zeolite were used to upgrade bio-oils from pine wood sawdust and soybean shell. The biomasses were selected according to their different lignin content which results in very different proportions of phenolic compounds (coke precursors) in the respective bio-oils. The bio-oils were produced by fast pyrolysis and the vapours were immediately upgraded over a fixed bed of catalyst at 550 °C using a mass catalyst/bio-oil relationship of 3.5. In terms of hydrocarbon yield, the matrices were more effective in deoxygenating pine wood sawdust bio-oil and the compound catalysts in deoxygenating soybean shell bio-oil. These differences can be the consequence of the different compositions of the bio-oils which, in the case of pine wood sawdust, includes a significant concentration of phenolic ethers which form coke on the matrix and the external surface of the zeolite, thus preventing lighter compounds from accessing the micropore system of the compound catalysts. Pine sawdust bio-oil produced more coke than soybean shell bio-oil; in the case of compound catalysts, coke deposited preferentially on the catalyst matrix, thus decreasing its mesopore specific surface area up to 65 %.Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaSpringer2017-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63474Bertero, Melisa Paola; García, Juan Rafael; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo; Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils; Springer; Waste and Biomass Valorization; 8; 3; 4-2017; 933-9481877-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s12649-016-9624-zinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:04:11Zoai:ri.conicet.gov.ar:11336/63474instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:04:12.267CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils
title Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils
spellingShingle Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils
Bertero, Melisa Paola
Bio-Oil
Biomass
Fcc
Fuels
Silica&Ndash;Alumina
title_short Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils
title_full Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils
title_fullStr Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils
title_full_unstemmed Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils
title_sort Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils
dc.creator.none.fl_str_mv Bertero, Melisa Paola
García, Juan Rafael
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author Bertero, Melisa Paola
author_facet Bertero, Melisa Paola
García, Juan Rafael
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author_role author
author2 García, Juan Rafael
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author2_role author
author
author
dc.subject.none.fl_str_mv Bio-Oil
Biomass
Fcc
Fuels
Silica&Ndash;Alumina
topic Bio-Oil
Biomass
Fcc
Fuels
Silica&Ndash;Alumina
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Matrices of FCC catalysts with different content of alumina and the compound catalysts prepared with them including Y zeolite were used to upgrade bio-oils from pine wood sawdust and soybean shell. The biomasses were selected according to their different lignin content which results in very different proportions of phenolic compounds (coke precursors) in the respective bio-oils. The bio-oils were produced by fast pyrolysis and the vapours were immediately upgraded over a fixed bed of catalyst at 550 °C using a mass catalyst/bio-oil relationship of 3.5. In terms of hydrocarbon yield, the matrices were more effective in deoxygenating pine wood sawdust bio-oil and the compound catalysts in deoxygenating soybean shell bio-oil. These differences can be the consequence of the different compositions of the bio-oils which, in the case of pine wood sawdust, includes a significant concentration of phenolic ethers which form coke on the matrix and the external surface of the zeolite, thus preventing lighter compounds from accessing the micropore system of the compound catalysts. Pine sawdust bio-oil produced more coke than soybean shell bio-oil; in the case of compound catalysts, coke deposited preferentially on the catalyst matrix, thus decreasing its mesopore specific surface area up to 65 %.
Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: García, Juan Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description Matrices of FCC catalysts with different content of alumina and the compound catalysts prepared with them including Y zeolite were used to upgrade bio-oils from pine wood sawdust and soybean shell. The biomasses were selected according to their different lignin content which results in very different proportions of phenolic compounds (coke precursors) in the respective bio-oils. The bio-oils were produced by fast pyrolysis and the vapours were immediately upgraded over a fixed bed of catalyst at 550 °C using a mass catalyst/bio-oil relationship of 3.5. In terms of hydrocarbon yield, the matrices were more effective in deoxygenating pine wood sawdust bio-oil and the compound catalysts in deoxygenating soybean shell bio-oil. These differences can be the consequence of the different compositions of the bio-oils which, in the case of pine wood sawdust, includes a significant concentration of phenolic ethers which form coke on the matrix and the external surface of the zeolite, thus preventing lighter compounds from accessing the micropore system of the compound catalysts. Pine sawdust bio-oil produced more coke than soybean shell bio-oil; in the case of compound catalysts, coke deposited preferentially on the catalyst matrix, thus decreasing its mesopore specific surface area up to 65 %.
publishDate 2017
dc.date.none.fl_str_mv 2017-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/63474
Bertero, Melisa Paola; García, Juan Rafael; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo; Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils; Springer; Waste and Biomass Valorization; 8; 3; 4-2017; 933-948
1877-265X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/63474
identifier_str_mv Bertero, Melisa Paola; García, Juan Rafael; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo; Hydrocarbons from Bio-oils: Performance of the Matrix in FCC Catalysts in the Immediate Catalytic Upgrading of Different Raw Bio-oils; Springer; Waste and Biomass Valorization; 8; 3; 4-2017; 933-948
1877-265X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s12649-016-9624-z
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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