Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains
- Autores
- Puig, Julieta; Hoppe, Cristina Elena; Pérez, Claudio Javier; Galante, Maria Jose; Williams, Roberto Juan Jose; Rodríguez Abreu, C.
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In a recent paper (Zucchi, I. A.; et al. Macromolecules 2008, 41, 4895), we showed that linear amphiphilic epoxy polymers synthesized by the polyaddition of diglycidyl ether of bisphenol A (DGEBA) with dodecylamine (DA) could undergo a physical gelation process through tail-to-tail association of dodecyl chains. The aim of the present study was to analyze in more detail conditions leading to the formation of epoxy networks with physical cross-links by the reaction of DGEBA with alkylamines of different chain lengths: octylamine (OA), dodecylamine (DA), and hexadecylamine (HA). SAXS spectra showed that tail-to-tail associations of alkyl chains were present since the beginning of polymerization and remained in the final materials. Initially, these associations correspond to micelles of the alkylamines dispersed in the solvent (DGEBA). In the course of polymerization, micelles are disaggregated as the individual alkylamine chains become part of the linear amphiphilic polymer. However, tail-to-tail associations among alkyl chains attached to the polymer backbone persisted in the final materials. Reactions were followed by rheometry at 100 °C. For every system, a significant discontinuity in the increase in the storage modulus observed at advanced conversions was assigned to a phase inversion process produced by solvent depletion. By annealing prolonged times at the reaction temperature, a crossover of storage and loss modulus was observed because of the increase in the extent of associations among alkyl chains leading to a physical gel. Times for physical gelation varied in the order OA < DA < HA. Both DGEBA−DA and DGEBA−HA polymers could be reversibly transformed from gel to liquid states by appropriate heating−cooling cycles; however, the DGEBA−OA polymer showed no thermoreversibility. Physical gels exhibited a high swelling capacity in THF (HA > DA > OA). These amphiphilic gels could be used as dispersion media for a variety of nanoparticles stabilized with alkyl chains. They can also be the basis of single-component thermally remendable epoxy networks.
Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Pérez, Claudio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rodríguez Abreu, C.. Instituto de Química Avanzada de Cataluña. Barcelona; España. CIBER de Bioingeniería, Biomateriales y Nanomedicina; España - Materia
-
Epoxy Networks
Physical Crosslinks
Reversible Networks - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/35019
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Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl ChainsPuig, JulietaHoppe, Cristina ElenaPérez, Claudio JavierGalante, Maria JoseWilliams, Roberto Juan JoseRodríguez Abreu, C.Epoxy NetworksPhysical CrosslinksReversible Networkshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In a recent paper (Zucchi, I. A.; et al. Macromolecules 2008, 41, 4895), we showed that linear amphiphilic epoxy polymers synthesized by the polyaddition of diglycidyl ether of bisphenol A (DGEBA) with dodecylamine (DA) could undergo a physical gelation process through tail-to-tail association of dodecyl chains. The aim of the present study was to analyze in more detail conditions leading to the formation of epoxy networks with physical cross-links by the reaction of DGEBA with alkylamines of different chain lengths: octylamine (OA), dodecylamine (DA), and hexadecylamine (HA). SAXS spectra showed that tail-to-tail associations of alkyl chains were present since the beginning of polymerization and remained in the final materials. Initially, these associations correspond to micelles of the alkylamines dispersed in the solvent (DGEBA). In the course of polymerization, micelles are disaggregated as the individual alkylamine chains become part of the linear amphiphilic polymer. However, tail-to-tail associations among alkyl chains attached to the polymer backbone persisted in the final materials. Reactions were followed by rheometry at 100 °C. For every system, a significant discontinuity in the increase in the storage modulus observed at advanced conversions was assigned to a phase inversion process produced by solvent depletion. By annealing prolonged times at the reaction temperature, a crossover of storage and loss modulus was observed because of the increase in the extent of associations among alkyl chains leading to a physical gel. Times for physical gelation varied in the order OA < DA < HA. Both DGEBA−DA and DGEBA−HA polymers could be reversibly transformed from gel to liquid states by appropriate heating−cooling cycles; however, the DGEBA−OA polymer showed no thermoreversibility. Physical gels exhibited a high swelling capacity in THF (HA > DA > OA). These amphiphilic gels could be used as dispersion media for a variety of nanoparticles stabilized with alkyl chains. They can also be the basis of single-component thermally remendable epoxy networks.Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Pérez, Claudio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Rodríguez Abreu, C.. Instituto de Química Avanzada de Cataluña. Barcelona; España. CIBER de Bioingeniería, Biomateriales y Nanomedicina; EspañaAmerican Chemical Society2009-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/35019Puig, Julieta; Hoppe, Cristina Elena; Pérez, Claudio Javier; Galante, Maria Jose; Williams, Roberto Juan Jose; et al.; Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains; American Chemical Society; Macromolecules; 42; 23; 10-2009; 9344-93500024-9297CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ma9018203info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ma9018203info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:55:48Zoai:ri.conicet.gov.ar:11336/35019instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:55:49.023CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains |
title |
Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains |
spellingShingle |
Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains Puig, Julieta Epoxy Networks Physical Crosslinks Reversible Networks |
title_short |
Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains |
title_full |
Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains |
title_fullStr |
Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains |
title_full_unstemmed |
Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains |
title_sort |
Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains |
dc.creator.none.fl_str_mv |
Puig, Julieta Hoppe, Cristina Elena Pérez, Claudio Javier Galante, Maria Jose Williams, Roberto Juan Jose Rodríguez Abreu, C. |
author |
Puig, Julieta |
author_facet |
Puig, Julieta Hoppe, Cristina Elena Pérez, Claudio Javier Galante, Maria Jose Williams, Roberto Juan Jose Rodríguez Abreu, C. |
author_role |
author |
author2 |
Hoppe, Cristina Elena Pérez, Claudio Javier Galante, Maria Jose Williams, Roberto Juan Jose Rodríguez Abreu, C. |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Epoxy Networks Physical Crosslinks Reversible Networks |
topic |
Epoxy Networks Physical Crosslinks Reversible Networks |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In a recent paper (Zucchi, I. A.; et al. Macromolecules 2008, 41, 4895), we showed that linear amphiphilic epoxy polymers synthesized by the polyaddition of diglycidyl ether of bisphenol A (DGEBA) with dodecylamine (DA) could undergo a physical gelation process through tail-to-tail association of dodecyl chains. The aim of the present study was to analyze in more detail conditions leading to the formation of epoxy networks with physical cross-links by the reaction of DGEBA with alkylamines of different chain lengths: octylamine (OA), dodecylamine (DA), and hexadecylamine (HA). SAXS spectra showed that tail-to-tail associations of alkyl chains were present since the beginning of polymerization and remained in the final materials. Initially, these associations correspond to micelles of the alkylamines dispersed in the solvent (DGEBA). In the course of polymerization, micelles are disaggregated as the individual alkylamine chains become part of the linear amphiphilic polymer. However, tail-to-tail associations among alkyl chains attached to the polymer backbone persisted in the final materials. Reactions were followed by rheometry at 100 °C. For every system, a significant discontinuity in the increase in the storage modulus observed at advanced conversions was assigned to a phase inversion process produced by solvent depletion. By annealing prolonged times at the reaction temperature, a crossover of storage and loss modulus was observed because of the increase in the extent of associations among alkyl chains leading to a physical gel. Times for physical gelation varied in the order OA < DA < HA. Both DGEBA−DA and DGEBA−HA polymers could be reversibly transformed from gel to liquid states by appropriate heating−cooling cycles; however, the DGEBA−OA polymer showed no thermoreversibility. Physical gels exhibited a high swelling capacity in THF (HA > DA > OA). These amphiphilic gels could be used as dispersion media for a variety of nanoparticles stabilized with alkyl chains. They can also be the basis of single-component thermally remendable epoxy networks. Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Pérez, Claudio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Rodríguez Abreu, C.. Instituto de Química Avanzada de Cataluña. Barcelona; España. CIBER de Bioingeniería, Biomateriales y Nanomedicina; España |
description |
In a recent paper (Zucchi, I. A.; et al. Macromolecules 2008, 41, 4895), we showed that linear amphiphilic epoxy polymers synthesized by the polyaddition of diglycidyl ether of bisphenol A (DGEBA) with dodecylamine (DA) could undergo a physical gelation process through tail-to-tail association of dodecyl chains. The aim of the present study was to analyze in more detail conditions leading to the formation of epoxy networks with physical cross-links by the reaction of DGEBA with alkylamines of different chain lengths: octylamine (OA), dodecylamine (DA), and hexadecylamine (HA). SAXS spectra showed that tail-to-tail associations of alkyl chains were present since the beginning of polymerization and remained in the final materials. Initially, these associations correspond to micelles of the alkylamines dispersed in the solvent (DGEBA). In the course of polymerization, micelles are disaggregated as the individual alkylamine chains become part of the linear amphiphilic polymer. However, tail-to-tail associations among alkyl chains attached to the polymer backbone persisted in the final materials. Reactions were followed by rheometry at 100 °C. For every system, a significant discontinuity in the increase in the storage modulus observed at advanced conversions was assigned to a phase inversion process produced by solvent depletion. By annealing prolonged times at the reaction temperature, a crossover of storage and loss modulus was observed because of the increase in the extent of associations among alkyl chains leading to a physical gel. Times for physical gelation varied in the order OA < DA < HA. Both DGEBA−DA and DGEBA−HA polymers could be reversibly transformed from gel to liquid states by appropriate heating−cooling cycles; however, the DGEBA−OA polymer showed no thermoreversibility. Physical gels exhibited a high swelling capacity in THF (HA > DA > OA). These amphiphilic gels could be used as dispersion media for a variety of nanoparticles stabilized with alkyl chains. They can also be the basis of single-component thermally remendable epoxy networks. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-10 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/35019 Puig, Julieta; Hoppe, Cristina Elena; Pérez, Claudio Javier; Galante, Maria Jose; Williams, Roberto Juan Jose; et al.; Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains; American Chemical Society; Macromolecules; 42; 23; 10-2009; 9344-9350 0024-9297 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/35019 |
identifier_str_mv |
Puig, Julieta; Hoppe, Cristina Elena; Pérez, Claudio Javier; Galante, Maria Jose; Williams, Roberto Juan Jose; et al.; Epoxy Networks with Physical Cross-Links Produced by Tail-to-Tail Associations of Alkyl Chains; American Chemical Society; Macromolecules; 42; 23; 10-2009; 9344-9350 0024-9297 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/ma9018203 info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ma9018203 |
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info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |