Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2

Autores
Henao Arboleda, Diana Patricia; Argüello, Gustavo Alejandro; Malanca, Fabio Ernesto
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Photooxidation of (CH3)3CCHO in the presence of NO2 leads to the formation of CO, CO2, (CH3)3CC(O)OONO2 (DMPPN), and (CH3)3CONO2. The synthesis of DMPPN and thermal decomposition studies were carried out. Pressure dependence was studied at 293 K from 6.0 to 1000 mbar. Kinetic parameters for DMPPN were determined between 293 and 308 K, at total pressures of 9.0 and 1000 mbar. The values found for the activation energy and pre-exponential factor were (109 ± 3) kJ/mol, 1.7 × 1015 s-1, and (117 ± 3) kJ/mol, 5.2 × 1016 s-1 at these pressures, respectively. Thermal stability for DMPPN is similar to peroxyacyl nitrates already identified in the atmosphere, such as peroxyacetyl and peroxypropionyl nitrates. The quantum yield for photolysis at 254 nm of (CH3)3CCHO was determined to be 0.60 ± 0.05.
Fil: Henao Arboleda, Diana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Argüello, Gustavo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Malanca, Fabio Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Atmospheric Degradation
Peroxyacyl Nitrates
Photochemistry
Photooxidation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37631
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2Henao Arboleda, Diana PatriciaArgüello, Gustavo AlejandroMalanca, Fabio ErnestoAtmospheric DegradationPeroxyacyl NitratesPhotochemistryPhotooxidationhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Photooxidation of (CH3)3CCHO in the presence of NO2 leads to the formation of CO, CO2, (CH3)3CC(O)OONO2 (DMPPN), and (CH3)3CONO2. The synthesis of DMPPN and thermal decomposition studies were carried out. Pressure dependence was studied at 293 K from 6.0 to 1000 mbar. Kinetic parameters for DMPPN were determined between 293 and 308 K, at total pressures of 9.0 and 1000 mbar. The values found for the activation energy and pre-exponential factor were (109 ± 3) kJ/mol, 1.7 × 1015 s-1, and (117 ± 3) kJ/mol, 5.2 × 1016 s-1 at these pressures, respectively. Thermal stability for DMPPN is similar to peroxyacyl nitrates already identified in the atmosphere, such as peroxyacetyl and peroxypropionyl nitrates. The quantum yield for photolysis at 254 nm of (CH3)3CCHO was determined to be 0.60 ± 0.05.Fil: Henao Arboleda, Diana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Argüello, Gustavo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Malanca, Fabio Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier Science Sa2015-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37631Henao Arboleda, Diana Patricia; Argüello, Gustavo Alejandro; Malanca, Fabio Ernesto; Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2; Elsevier Science Sa; Journal of Photochemistry and Photobiology A: Chemistry; 299; 2-2015; 62-661010-6030CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jphotochem.2014.11.008info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1010603014004729info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:33:11Zoai:ri.conicet.gov.ar:11336/37631instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:33:12.09CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2
title Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2
spellingShingle Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2
Henao Arboleda, Diana Patricia
Atmospheric Degradation
Peroxyacyl Nitrates
Photochemistry
Photooxidation
title_short Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2
title_full Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2
title_fullStr Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2
title_full_unstemmed Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2
title_sort Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2
dc.creator.none.fl_str_mv Henao Arboleda, Diana Patricia
Argüello, Gustavo Alejandro
Malanca, Fabio Ernesto
author Henao Arboleda, Diana Patricia
author_facet Henao Arboleda, Diana Patricia
Argüello, Gustavo Alejandro
Malanca, Fabio Ernesto
author_role author
author2 Argüello, Gustavo Alejandro
Malanca, Fabio Ernesto
author2_role author
author
dc.subject.none.fl_str_mv Atmospheric Degradation
Peroxyacyl Nitrates
Photochemistry
Photooxidation
topic Atmospheric Degradation
Peroxyacyl Nitrates
Photochemistry
Photooxidation
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Photooxidation of (CH3)3CCHO in the presence of NO2 leads to the formation of CO, CO2, (CH3)3CC(O)OONO2 (DMPPN), and (CH3)3CONO2. The synthesis of DMPPN and thermal decomposition studies were carried out. Pressure dependence was studied at 293 K from 6.0 to 1000 mbar. Kinetic parameters for DMPPN were determined between 293 and 308 K, at total pressures of 9.0 and 1000 mbar. The values found for the activation energy and pre-exponential factor were (109 ± 3) kJ/mol, 1.7 × 1015 s-1, and (117 ± 3) kJ/mol, 5.2 × 1016 s-1 at these pressures, respectively. Thermal stability for DMPPN is similar to peroxyacyl nitrates already identified in the atmosphere, such as peroxyacetyl and peroxypropionyl nitrates. The quantum yield for photolysis at 254 nm of (CH3)3CCHO was determined to be 0.60 ± 0.05.
Fil: Henao Arboleda, Diana Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Argüello, Gustavo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Malanca, Fabio Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description Photooxidation of (CH3)3CCHO in the presence of NO2 leads to the formation of CO, CO2, (CH3)3CC(O)OONO2 (DMPPN), and (CH3)3CONO2. The synthesis of DMPPN and thermal decomposition studies were carried out. Pressure dependence was studied at 293 K from 6.0 to 1000 mbar. Kinetic parameters for DMPPN were determined between 293 and 308 K, at total pressures of 9.0 and 1000 mbar. The values found for the activation energy and pre-exponential factor were (109 ± 3) kJ/mol, 1.7 × 1015 s-1, and (117 ± 3) kJ/mol, 5.2 × 1016 s-1 at these pressures, respectively. Thermal stability for DMPPN is similar to peroxyacyl nitrates already identified in the atmosphere, such as peroxyacetyl and peroxypropionyl nitrates. The quantum yield for photolysis at 254 nm of (CH3)3CCHO was determined to be 0.60 ± 0.05.
publishDate 2015
dc.date.none.fl_str_mv 2015-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37631
Henao Arboleda, Diana Patricia; Argüello, Gustavo Alejandro; Malanca, Fabio Ernesto; Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2; Elsevier Science Sa; Journal of Photochemistry and Photobiology A: Chemistry; 299; 2-2015; 62-66
1010-6030
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37631
identifier_str_mv Henao Arboleda, Diana Patricia; Argüello, Gustavo Alejandro; Malanca, Fabio Ernesto; Chlorine initiated photooxidation of (CH3)3CC(O)H in the presence of NO2 and photolysis at 254 nm. Synthesis and thermal stability of (CH3)3CC(O)OONO2; Elsevier Science Sa; Journal of Photochemistry and Photobiology A: Chemistry; 299; 2-2015; 62-66
1010-6030
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jphotochem.2014.11.008
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1010603014004729
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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