Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions

Autores
Pereda, Selva; Bottini, Susana Beatriz; Brignole, Esteban Alberto
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Gas-liquid catalyzed reactions carried out in a supercritical medium take advantage of the high reaction rates and improved selectivities that can be achieved by having reactants and products in a homogeneous phase. In this work, the phase behavior of several supercritical reactions are analyzed and the selection of adequate solvents is discussed. The reactions studied include the hydrogenation of terpenic compounds and unsaturated aldehydes, and the hydroformylation of hydrocarbons to produce aldehydes. Recent experimental results from the literature on the kinetics and selectivities of these reactions are discussed on the basis of the phase equilibrium scenario under the reaction conditions.
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
1-Hexene
Hydroformylation
Hydrogenation
Phase Equilibria
Supercritical Reaction Media
Terpenes
Unsaturated Aldehydes
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/79072
Acceder
id CONICETDig_aa7558b6760c8ff058b9090b40793c3b
oai_identifier_str oai:ri.conicet.gov.ar:11336/79072
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactionsPereda, SelvaBottini, Susana BeatrizBrignole, Esteban Alberto1-HexeneHydroformylationHydrogenationPhase EquilibriaSupercritical Reaction MediaTerpenesUnsaturated Aldehydeshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Gas-liquid catalyzed reactions carried out in a supercritical medium take advantage of the high reaction rates and improved selectivities that can be achieved by having reactants and products in a homogeneous phase. In this work, the phase behavior of several supercritical reactions are analyzed and the selection of adequate solvents is discussed. The reactions studied include the hydrogenation of terpenic compounds and unsaturated aldehydes, and the hydroformylation of hydrocarbons to produce aldehydes. Recent experimental results from the literature on the kinetics and selectivities of these reactions are discussed on the basis of the phase equilibrium scenario under the reaction conditions.Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2005-03-18info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/79072Pereda, Selva; Bottini, Susana Beatriz; Brignole, Esteban Alberto; Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions; Elsevier Science; Applied Catalysis A: General; 281; 1-2; 18-3-2005; 129-1370926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X04009251info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2004.11.019info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-17T10:57:32Zoai:ri.conicet.gov.ar:11336/79072instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-17 10:57:32.922CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions
title Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions
spellingShingle Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions
Pereda, Selva
1-Hexene
Hydroformylation
Hydrogenation
Phase Equilibria
Supercritical Reaction Media
Terpenes
Unsaturated Aldehydes
title_short Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions
title_full Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions
title_fullStr Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions
title_full_unstemmed Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions
title_sort Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions
dc.creator.none.fl_str_mv Pereda, Selva
Bottini, Susana Beatriz
Brignole, Esteban Alberto
author Pereda, Selva
author_facet Pereda, Selva
Bottini, Susana Beatriz
Brignole, Esteban Alberto
author_role author
author2 Bottini, Susana Beatriz
Brignole, Esteban Alberto
author2_role author
author
dc.subject.none.fl_str_mv 1-Hexene
Hydroformylation
Hydrogenation
Phase Equilibria
Supercritical Reaction Media
Terpenes
Unsaturated Aldehydes
topic 1-Hexene
Hydroformylation
Hydrogenation
Phase Equilibria
Supercritical Reaction Media
Terpenes
Unsaturated Aldehydes
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Gas-liquid catalyzed reactions carried out in a supercritical medium take advantage of the high reaction rates and improved selectivities that can be achieved by having reactants and products in a homogeneous phase. In this work, the phase behavior of several supercritical reactions are analyzed and the selection of adequate solvents is discussed. The reactions studied include the hydrogenation of terpenic compounds and unsaturated aldehydes, and the hydroformylation of hydrocarbons to produce aldehydes. Recent experimental results from the literature on the kinetics and selectivities of these reactions are discussed on the basis of the phase equilibrium scenario under the reaction conditions.
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Gas-liquid catalyzed reactions carried out in a supercritical medium take advantage of the high reaction rates and improved selectivities that can be achieved by having reactants and products in a homogeneous phase. In this work, the phase behavior of several supercritical reactions are analyzed and the selection of adequate solvents is discussed. The reactions studied include the hydrogenation of terpenic compounds and unsaturated aldehydes, and the hydroformylation of hydrocarbons to produce aldehydes. Recent experimental results from the literature on the kinetics and selectivities of these reactions are discussed on the basis of the phase equilibrium scenario under the reaction conditions.
publishDate 2005
dc.date.none.fl_str_mv 2005-03-18
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/79072
Pereda, Selva; Bottini, Susana Beatriz; Brignole, Esteban Alberto; Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions; Elsevier Science; Applied Catalysis A: General; 281; 1-2; 18-3-2005; 129-137
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/79072
identifier_str_mv Pereda, Selva; Bottini, Susana Beatriz; Brignole, Esteban Alberto; Supercritical fluids and phase behavior in heterogeneous gas-liquid catalytic reactions; Elsevier Science; Applied Catalysis A: General; 281; 1-2; 18-3-2005; 129-137
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X04009251
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2004.11.019
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1843606246820675584
score 13.001348

Publicaciones similares