Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads

Autores
Colombo Migliorero, María Belén; Palermo, Valeria; Romanelli, Gustavo Pablo; Vazquez, Patricia Graciela
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Heteropolyacids are used as catalysts in numerous reactions because they are inexpensive, nontoxic, have high acid strength and excellent redox proper-ties. They have been used as acid catalyst in different ways, and numerous studies indicate that the incorpo-ration of Nb into the structure of a solid generates an increase in the acidity of the sample, both at Lewis and Brönsted acid sites. Heteropolyacids have low surface area, which makes it necessary to include them in a support to increase the surface area and allow their use as heterogeneous catalysts in liquid phase reactions because they are very soluble in po-lar solvents. In this work, the synthesis of catalysts containing a niobium-doped heteropolyacid (PMoNb) included in silica at different concentrations is re-ported. The catalysts were characterized by ICP-MS, FT-IR, XRD, potentiometric titration, and their cata-lytic activity was tested in the selective oxidation of diphenyl sulfide to diphenyl sulfoxide, showing excel-lent results.
Fil: Colombo Migliorero, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Palermo, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
KEGGIN HETEROPOLYACID
HETEROGENEOUS CATALYSIS
DIPHENYL SULFIDE
GREEN CONDITIONS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/247984
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loadsColombo Migliorero, María BelénPalermo, ValeriaRomanelli, Gustavo PabloVazquez, Patricia GracielaKEGGIN HETEROPOLYACIDHETEROGENEOUS CATALYSISDIPHENYL SULFIDEGREEN CONDITIONShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Heteropolyacids are used as catalysts in numerous reactions because they are inexpensive, nontoxic, have high acid strength and excellent redox proper-ties. They have been used as acid catalyst in different ways, and numerous studies indicate that the incorpo-ration of Nb into the structure of a solid generates an increase in the acidity of the sample, both at Lewis and Brönsted acid sites. Heteropolyacids have low surface area, which makes it necessary to include them in a support to increase the surface area and allow their use as heterogeneous catalysts in liquid phase reactions because they are very soluble in po-lar solvents. In this work, the synthesis of catalysts containing a niobium-doped heteropolyacid (PMoNb) included in silica at different concentrations is re-ported. The catalysts were characterized by ICP-MS, FT-IR, XRD, potentiometric titration, and their cata-lytic activity was tested in the selective oxidation of diphenyl sulfide to diphenyl sulfoxide, showing excel-lent results.Fil: Colombo Migliorero, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Palermo, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaPlanta Piloto de Ingeniería Química2023-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/247984Colombo Migliorero, María Belén; Palermo, Valeria; Romanelli, Gustavo Pablo; Vazquez, Patricia Graciela; Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads; Planta Piloto de Ingeniería Química; Latin American Applied Research; 53; 1; 1-2023; 49-540327-07931851-8796CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://laar.plapiqui.edu.ar/OJS/index.php/laar/article/view/1129info:eu-repo/semantics/altIdentifier/doi/10.52292/j.laar.2023.1129info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:42:24Zoai:ri.conicet.gov.ar:11336/247984instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:42:24.709CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads
title Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads
spellingShingle Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads
Colombo Migliorero, María Belén
KEGGIN HETEROPOLYACID
HETEROGENEOUS CATALYSIS
DIPHENYL SULFIDE
GREEN CONDITIONS
title_short Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads
title_full Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads
title_fullStr Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads
title_full_unstemmed Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads
title_sort Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads
dc.creator.none.fl_str_mv Colombo Migliorero, María Belén
Palermo, Valeria
Romanelli, Gustavo Pablo
Vazquez, Patricia Graciela
author Colombo Migliorero, María Belén
author_facet Colombo Migliorero, María Belén
Palermo, Valeria
Romanelli, Gustavo Pablo
Vazquez, Patricia Graciela
author_role author
author2 Palermo, Valeria
Romanelli, Gustavo Pablo
Vazquez, Patricia Graciela
author2_role author
author
author
dc.subject.none.fl_str_mv KEGGIN HETEROPOLYACID
HETEROGENEOUS CATALYSIS
DIPHENYL SULFIDE
GREEN CONDITIONS
topic KEGGIN HETEROPOLYACID
HETEROGENEOUS CATALYSIS
DIPHENYL SULFIDE
GREEN CONDITIONS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Heteropolyacids are used as catalysts in numerous reactions because they are inexpensive, nontoxic, have high acid strength and excellent redox proper-ties. They have been used as acid catalyst in different ways, and numerous studies indicate that the incorpo-ration of Nb into the structure of a solid generates an increase in the acidity of the sample, both at Lewis and Brönsted acid sites. Heteropolyacids have low surface area, which makes it necessary to include them in a support to increase the surface area and allow their use as heterogeneous catalysts in liquid phase reactions because they are very soluble in po-lar solvents. In this work, the synthesis of catalysts containing a niobium-doped heteropolyacid (PMoNb) included in silica at different concentrations is re-ported. The catalysts were characterized by ICP-MS, FT-IR, XRD, potentiometric titration, and their cata-lytic activity was tested in the selective oxidation of diphenyl sulfide to diphenyl sulfoxide, showing excel-lent results.
Fil: Colombo Migliorero, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Palermo, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description Heteropolyacids are used as catalysts in numerous reactions because they are inexpensive, nontoxic, have high acid strength and excellent redox proper-ties. They have been used as acid catalyst in different ways, and numerous studies indicate that the incorpo-ration of Nb into the structure of a solid generates an increase in the acidity of the sample, both at Lewis and Brönsted acid sites. Heteropolyacids have low surface area, which makes it necessary to include them in a support to increase the surface area and allow their use as heterogeneous catalysts in liquid phase reactions because they are very soluble in po-lar solvents. In this work, the synthesis of catalysts containing a niobium-doped heteropolyacid (PMoNb) included in silica at different concentrations is re-ported. The catalysts were characterized by ICP-MS, FT-IR, XRD, potentiometric titration, and their cata-lytic activity was tested in the selective oxidation of diphenyl sulfide to diphenyl sulfoxide, showing excel-lent results.
publishDate 2023
dc.date.none.fl_str_mv 2023-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/247984
Colombo Migliorero, María Belén; Palermo, Valeria; Romanelli, Gustavo Pablo; Vazquez, Patricia Graciela; Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads; Planta Piloto de Ingeniería Química; Latin American Applied Research; 53; 1; 1-2023; 49-54
0327-0793
1851-8796
CONICET Digital
CONICET
url http://hdl.handle.net/11336/247984
identifier_str_mv Colombo Migliorero, María Belén; Palermo, Valeria; Romanelli, Gustavo Pablo; Vazquez, Patricia Graciela; Niobium-doped phosphomolybdic acid catalyst includedin silica matrix: study of stability and reactivity using different loads; Planta Piloto de Ingeniería Química; Latin American Applied Research; 53; 1; 1-2023; 49-54
0327-0793
1851-8796
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://laar.plapiqui.edu.ar/OJS/index.php/laar/article/view/1129
info:eu-repo/semantics/altIdentifier/doi/10.52292/j.laar.2023.1129
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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