Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction

Autores
Castro Grijalba, Alexander; Reyes Gallardo, Emilia M.; Wuilloud, Rodolfo German; Lucena Rodríguez, Rafael; Cárdenas Aranzana, María Soledad
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the present article a new approach for the synthesis of magnetic polymeric ionic liquid nanocomposites based on the Radziszewski reaction is presented. The Radziszewski reaction is a simple and successful procedure to obtain imidazolium-containing polymers under mild conditions and consists of the reaction between diamine compounds, glyoxal and formaldehyde in an acidic media. If magnetic nanoparticles coated with amino groups are introduced, they can participate as polyamines in the synthesis thus providing a final nanocomposite where polymeric ionic liquids and nanoparticles are combined. The resulting nanocomposite has been characterized using several instrumental techniques aimed at elucidating its chemical composition (infrared spectroscopy and elemental analysis), properties (zeta potential) and morphology (microscopy, X-ray diffraction and dynamic light scattering). Finally, its sorptive ability towards three non-steroidal anti-inflammatory drugs (NSAIDs) such as salicylic acid, ketoprofen and naproxen was evaluated considering the main variables involved in the process. According to the results, the polymeric ionic liquid nanocomposite is a promising sorptive material for analytical purposes.
Fil: Castro Grijalba, Alexander. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina
Fil: Reyes Gallardo, Emilia M.. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; España
Fil: Wuilloud, Rodolfo German. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina
Fil: Lucena Rodríguez, Rafael. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; España
Fil: Cárdenas Aranzana, María Soledad. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; España
Materia
Polymeric ionic liquids
Magnetic
Nanoparticles
Synthesis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37321
Acceder
id CONICETDig_a7a8a7209ae00c30bd2bc089dd5fa26d
oai_identifier_str oai:ri.conicet.gov.ar:11336/37321
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reactionCastro Grijalba, AlexanderReyes Gallardo, Emilia M.Wuilloud, Rodolfo GermanLucena Rodríguez, RafaelCárdenas Aranzana, María SoledadPolymeric ionic liquidsMagneticNanoparticlesSynthesishttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2In the present article a new approach for the synthesis of magnetic polymeric ionic liquid nanocomposites based on the Radziszewski reaction is presented. The Radziszewski reaction is a simple and successful procedure to obtain imidazolium-containing polymers under mild conditions and consists of the reaction between diamine compounds, glyoxal and formaldehyde in an acidic media. If magnetic nanoparticles coated with amino groups are introduced, they can participate as polyamines in the synthesis thus providing a final nanocomposite where polymeric ionic liquids and nanoparticles are combined. The resulting nanocomposite has been characterized using several instrumental techniques aimed at elucidating its chemical composition (infrared spectroscopy and elemental analysis), properties (zeta potential) and morphology (microscopy, X-ray diffraction and dynamic light scattering). Finally, its sorptive ability towards three non-steroidal anti-inflammatory drugs (NSAIDs) such as salicylic acid, ketoprofen and naproxen was evaluated considering the main variables involved in the process. According to the results, the polymeric ionic liquid nanocomposite is a promising sorptive material for analytical purposes.Fil: Castro Grijalba, Alexander. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; ArgentinaFil: Reyes Gallardo, Emilia M.. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; EspañaFil: Wuilloud, Rodolfo German. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; ArgentinaFil: Lucena Rodríguez, Rafael. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; EspañaFil: Cárdenas Aranzana, María Soledad. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; EspañaRoyal Society of Chemistry2017-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37321Castro Grijalba, Alexander; Reyes Gallardo, Emilia M.; Wuilloud, Rodolfo German; Lucena Rodríguez, Rafael; Cárdenas Aranzana, María Soledad; Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction; Royal Society of Chemistry; RSC Advances; 7; 68; 9-2017; 42979-429852046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C7RA07947H#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/c7ra07947hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:56:07Zoai:ri.conicet.gov.ar:11336/37321instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:56:07.336CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction
title Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction
spellingShingle Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction
Castro Grijalba, Alexander
Polymeric ionic liquids
Magnetic
Nanoparticles
Synthesis
title_short Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction
title_full Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction
title_fullStr Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction
title_full_unstemmed Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction
title_sort Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction
dc.creator.none.fl_str_mv Castro Grijalba, Alexander
Reyes Gallardo, Emilia M.
Wuilloud, Rodolfo German
Lucena Rodríguez, Rafael
Cárdenas Aranzana, María Soledad
author Castro Grijalba, Alexander
author_facet Castro Grijalba, Alexander
Reyes Gallardo, Emilia M.
Wuilloud, Rodolfo German
Lucena Rodríguez, Rafael
Cárdenas Aranzana, María Soledad
author_role author
author2 Reyes Gallardo, Emilia M.
Wuilloud, Rodolfo German
Lucena Rodríguez, Rafael
Cárdenas Aranzana, María Soledad
author2_role author
author
author
author
dc.subject.none.fl_str_mv Polymeric ionic liquids
Magnetic
Nanoparticles
Synthesis
topic Polymeric ionic liquids
Magnetic
Nanoparticles
Synthesis
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In the present article a new approach for the synthesis of magnetic polymeric ionic liquid nanocomposites based on the Radziszewski reaction is presented. The Radziszewski reaction is a simple and successful procedure to obtain imidazolium-containing polymers under mild conditions and consists of the reaction between diamine compounds, glyoxal and formaldehyde in an acidic media. If magnetic nanoparticles coated with amino groups are introduced, they can participate as polyamines in the synthesis thus providing a final nanocomposite where polymeric ionic liquids and nanoparticles are combined. The resulting nanocomposite has been characterized using several instrumental techniques aimed at elucidating its chemical composition (infrared spectroscopy and elemental analysis), properties (zeta potential) and morphology (microscopy, X-ray diffraction and dynamic light scattering). Finally, its sorptive ability towards three non-steroidal anti-inflammatory drugs (NSAIDs) such as salicylic acid, ketoprofen and naproxen was evaluated considering the main variables involved in the process. According to the results, the polymeric ionic liquid nanocomposite is a promising sorptive material for analytical purposes.
Fil: Castro Grijalba, Alexander. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina
Fil: Reyes Gallardo, Emilia M.. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; España
Fil: Wuilloud, Rodolfo German. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales. Laboratorio de Química Analítica para Investigación y Desarrollo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina
Fil: Lucena Rodríguez, Rafael. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; España
Fil: Cárdenas Aranzana, María Soledad. Universidad de Cordoba. Fac. de Matemática Astronomía y Física; España
description In the present article a new approach for the synthesis of magnetic polymeric ionic liquid nanocomposites based on the Radziszewski reaction is presented. The Radziszewski reaction is a simple and successful procedure to obtain imidazolium-containing polymers under mild conditions and consists of the reaction between diamine compounds, glyoxal and formaldehyde in an acidic media. If magnetic nanoparticles coated with amino groups are introduced, they can participate as polyamines in the synthesis thus providing a final nanocomposite where polymeric ionic liquids and nanoparticles are combined. The resulting nanocomposite has been characterized using several instrumental techniques aimed at elucidating its chemical composition (infrared spectroscopy and elemental analysis), properties (zeta potential) and morphology (microscopy, X-ray diffraction and dynamic light scattering). Finally, its sorptive ability towards three non-steroidal anti-inflammatory drugs (NSAIDs) such as salicylic acid, ketoprofen and naproxen was evaluated considering the main variables involved in the process. According to the results, the polymeric ionic liquid nanocomposite is a promising sorptive material for analytical purposes.
publishDate 2017
dc.date.none.fl_str_mv 2017-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37321
Castro Grijalba, Alexander; Reyes Gallardo, Emilia M.; Wuilloud, Rodolfo German; Lucena Rodríguez, Rafael; Cárdenas Aranzana, María Soledad; Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction; Royal Society of Chemistry; RSC Advances; 7; 68; 9-2017; 42979-42985
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37321
identifier_str_mv Castro Grijalba, Alexander; Reyes Gallardo, Emilia M.; Wuilloud, Rodolfo German; Lucena Rodríguez, Rafael; Cárdenas Aranzana, María Soledad; Synthesis of magnetic polymeric ionic liquid nanocomposites by the Radziszewski reaction; Royal Society of Chemistry; RSC Advances; 7; 68; 9-2017; 42979-42985
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C7RA07947H#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/c7ra07947h
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613687435853824
score 13.070432

Publicaciones similares