Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching

Autores
Rubio Marcos, Fernando; Del Campo, Adolfo; Rojas Hernandez, Rocío E.; Ramírez, Mariola O.; Parra, Rodrigo; Ichikawa, Rodrigo U.; Ramajo, Leandro Alfredo; Bausá, Luisa E.; Fernández, Jose F.
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The control of ferroelectric domain walls at the nanometric level leads to novel interfacial properties and functionalities. In particular, the comprehension of charged domain walls, CDWs, lies at the frontier of future nanoelectronic research. Whereas many of the effects have been demonstrated for ideal archetypes, such as single crystals, and/or thin films, a similar control of CDWs on polycrystalline ferroelectrics has not been achieved. Here, we unambiguously show the presence of charged domain walls on a lead-free (K,Na)NbO3 polycrystalline system. The appearance of CDWs is observed in situ by confocal Raman microscopy and second harmonic generation microscopy. CDWs produce an internal strain gradient within each domain. Specifically, the anisotropic strain develops a crucial piece in the ferroelectric domain switching due to the coupling between the polarization of light and the ferroelectric polarization of the nanodomain in the (K,Na)NbO3 ceramic. This effect leads to the tuning of the ferroelectric domain switching by means of the light polarization angle. Our results will help to understand the relevance of charged domain walls on the ferroelectric domain switching process and may facilitate the development of domain wall nanoelectronics by remote light control utilizing polycrystalline ferroelectrics.
Fil: Rubio Marcos, Fernando. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Del Campo, Adolfo. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Rojas Hernandez, Rocío E.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Ramírez, Mariola O.. Instituto Superior Tecnico; Portugal
Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ichikawa, Rodrigo U.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Bausá, Luisa E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Fernández, Jose F.. Universidad Autónoma de Madrid; España
Materia
Ferroelectrics
Charged domain walls
KNaNbO3
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/93487
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/93487
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switchingRubio Marcos, FernandoDel Campo, AdolfoRojas Hernandez, Rocío E.Ramírez, Mariola O.Parra, RodrigoIchikawa, Rodrigo U.Ramajo, Leandro AlfredoBausá, Luisa E.Fernández, Jose F.FerroelectricsCharged domain wallsKNaNbO3https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The control of ferroelectric domain walls at the nanometric level leads to novel interfacial properties and functionalities. In particular, the comprehension of charged domain walls, CDWs, lies at the frontier of future nanoelectronic research. Whereas many of the effects have been demonstrated for ideal archetypes, such as single crystals, and/or thin films, a similar control of CDWs on polycrystalline ferroelectrics has not been achieved. Here, we unambiguously show the presence of charged domain walls on a lead-free (K,Na)NbO3 polycrystalline system. The appearance of CDWs is observed in situ by confocal Raman microscopy and second harmonic generation microscopy. CDWs produce an internal strain gradient within each domain. Specifically, the anisotropic strain develops a crucial piece in the ferroelectric domain switching due to the coupling between the polarization of light and the ferroelectric polarization of the nanodomain in the (K,Na)NbO3 ceramic. This effect leads to the tuning of the ferroelectric domain switching by means of the light polarization angle. Our results will help to understand the relevance of charged domain walls on the ferroelectric domain switching process and may facilitate the development of domain wall nanoelectronics by remote light control utilizing polycrystalline ferroelectrics.Fil: Rubio Marcos, Fernando. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Del Campo, Adolfo. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Rojas Hernandez, Rocío E.. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Ramírez, Mariola O.. Instituto Superior Tecnico; PortugalFil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ichikawa, Rodrigo U.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Bausá, Luisa E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Fernández, Jose F.. Universidad Autónoma de Madrid; EspañaRoyal Society of Chemistry2018-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/93487Rubio Marcos, Fernando; Del Campo, Adolfo; Rojas Hernandez, Rocío E.; Ramírez, Mariola O.; Parra, Rodrigo; et al.; Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching; Royal Society of Chemistry; Nanoscale; 10; 2; 1-2018; 705-7152040-3372CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/nr/c7nr04304jinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C7NR04304Jinfo:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)https://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:36:54Zoai:ri.conicet.gov.ar:11336/93487instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:36:54.68CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching
title Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching
spellingShingle Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching
Rubio Marcos, Fernando
Ferroelectrics
Charged domain walls
KNaNbO3
title_short Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching
title_full Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching
title_fullStr Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching
title_full_unstemmed Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching
title_sort Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching
dc.creator.none.fl_str_mv Rubio Marcos, Fernando
Del Campo, Adolfo
Rojas Hernandez, Rocío E.
Ramírez, Mariola O.
Parra, Rodrigo
Ichikawa, Rodrigo U.
Ramajo, Leandro Alfredo
Bausá, Luisa E.
Fernández, Jose F.
author Rubio Marcos, Fernando
author_facet Rubio Marcos, Fernando
Del Campo, Adolfo
Rojas Hernandez, Rocío E.
Ramírez, Mariola O.
Parra, Rodrigo
Ichikawa, Rodrigo U.
Ramajo, Leandro Alfredo
Bausá, Luisa E.
Fernández, Jose F.
author_role author
author2 Del Campo, Adolfo
Rojas Hernandez, Rocío E.
Ramírez, Mariola O.
Parra, Rodrigo
Ichikawa, Rodrigo U.
Ramajo, Leandro Alfredo
Bausá, Luisa E.
Fernández, Jose F.
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Ferroelectrics
Charged domain walls
KNaNbO3
topic Ferroelectrics
Charged domain walls
KNaNbO3
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The control of ferroelectric domain walls at the nanometric level leads to novel interfacial properties and functionalities. In particular, the comprehension of charged domain walls, CDWs, lies at the frontier of future nanoelectronic research. Whereas many of the effects have been demonstrated for ideal archetypes, such as single crystals, and/or thin films, a similar control of CDWs on polycrystalline ferroelectrics has not been achieved. Here, we unambiguously show the presence of charged domain walls on a lead-free (K,Na)NbO3 polycrystalline system. The appearance of CDWs is observed in situ by confocal Raman microscopy and second harmonic generation microscopy. CDWs produce an internal strain gradient within each domain. Specifically, the anisotropic strain develops a crucial piece in the ferroelectric domain switching due to the coupling between the polarization of light and the ferroelectric polarization of the nanodomain in the (K,Na)NbO3 ceramic. This effect leads to the tuning of the ferroelectric domain switching by means of the light polarization angle. Our results will help to understand the relevance of charged domain walls on the ferroelectric domain switching process and may facilitate the development of domain wall nanoelectronics by remote light control utilizing polycrystalline ferroelectrics.
Fil: Rubio Marcos, Fernando. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Del Campo, Adolfo. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Rojas Hernandez, Rocío E.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Ramírez, Mariola O.. Instituto Superior Tecnico; Portugal
Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ichikawa, Rodrigo U.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Bausá, Luisa E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Fernández, Jose F.. Universidad Autónoma de Madrid; España
description The control of ferroelectric domain walls at the nanometric level leads to novel interfacial properties and functionalities. In particular, the comprehension of charged domain walls, CDWs, lies at the frontier of future nanoelectronic research. Whereas many of the effects have been demonstrated for ideal archetypes, such as single crystals, and/or thin films, a similar control of CDWs on polycrystalline ferroelectrics has not been achieved. Here, we unambiguously show the presence of charged domain walls on a lead-free (K,Na)NbO3 polycrystalline system. The appearance of CDWs is observed in situ by confocal Raman microscopy and second harmonic generation microscopy. CDWs produce an internal strain gradient within each domain. Specifically, the anisotropic strain develops a crucial piece in the ferroelectric domain switching due to the coupling between the polarization of light and the ferroelectric polarization of the nanodomain in the (K,Na)NbO3 ceramic. This effect leads to the tuning of the ferroelectric domain switching by means of the light polarization angle. Our results will help to understand the relevance of charged domain walls on the ferroelectric domain switching process and may facilitate the development of domain wall nanoelectronics by remote light control utilizing polycrystalline ferroelectrics.
publishDate 2018
dc.date.none.fl_str_mv 2018-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/93487
Rubio Marcos, Fernando; Del Campo, Adolfo; Rojas Hernandez, Rocío E.; Ramírez, Mariola O.; Parra, Rodrigo; et al.; Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching; Royal Society of Chemistry; Nanoscale; 10; 2; 1-2018; 705-715
2040-3372
CONICET Digital
CONICET
url http://hdl.handle.net/11336/93487
identifier_str_mv Rubio Marcos, Fernando; Del Campo, Adolfo; Rojas Hernandez, Rocío E.; Ramírez, Mariola O.; Parra, Rodrigo; et al.; Experimental evidence of charged domain walls in lead-free ferroelectric ceramics: Light-driven nanodomain switching; Royal Society of Chemistry; Nanoscale; 10; 2; 1-2018; 705-715
2040-3372
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/nr/c7nr04304j
info:eu-repo/semantics/altIdentifier/doi/10.1039/C7NR04304J
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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