Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments

Autores
Gutierrez, Laura Beatriz; Miro, Eduardo Ernesto; Irusta, S.
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Co-mordenites were prepared by ion exchange and wet impregnation over Na-mordenite and H-mordenite. The prepared solids were calcined and aliquots of these samples were subject to redox treatments first with CO for 2 h at 773 K and then kept 2 h at the same temperature in flowing O2. A thorough characterization of the solids was carried out by TPR, XPS, CO volumetric adsorption, and FTIR with CO, NO and pyridine adsorption as probe molecules. After the redox treatment, Na based samples showed an important increase in the CO adsorption. TPR and XPS results indicated reduction of the oxides present in the calcined samples and the migration of exchanged cobalt from hidden to more exposed sites was demonstrated by FTIR. The acid catalysts did not change their CO capacity of adsorption; exchanged cobalt ions were mainly in β-type sites and remained in this position after treatment. After the redox treatments, the activity for the selective reduction of NOx with methane suffered a decrease on both types of mordenites, probably caused by the strong adsorption of NO and the reduction of β-type Co2+ to metallic cobalt that would diminish the active sites concentration and also block the channels, thus preventing the access of the reactants.
Fil: Gutierrez, Laura Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Irusta, S.. Universidad de Zaragoza; España
Materia
Co-Mordenites
Co-Ftir
No-Ftir
Py-Ftir
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/65154
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatmentsGutierrez, Laura BeatrizMiro, Eduardo ErnestoIrusta, S.Co-MordenitesCo-FtirNo-FtirPy-Ftirhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Co-mordenites were prepared by ion exchange and wet impregnation over Na-mordenite and H-mordenite. The prepared solids were calcined and aliquots of these samples were subject to redox treatments first with CO for 2 h at 773 K and then kept 2 h at the same temperature in flowing O2. A thorough characterization of the solids was carried out by TPR, XPS, CO volumetric adsorption, and FTIR with CO, NO and pyridine adsorption as probe molecules. After the redox treatment, Na based samples showed an important increase in the CO adsorption. TPR and XPS results indicated reduction of the oxides present in the calcined samples and the migration of exchanged cobalt from hidden to more exposed sites was demonstrated by FTIR. The acid catalysts did not change their CO capacity of adsorption; exchanged cobalt ions were mainly in β-type sites and remained in this position after treatment. After the redox treatments, the activity for the selective reduction of NOx with methane suffered a decrease on both types of mordenites, probably caused by the strong adsorption of NO and the reduction of β-type Co2+ to metallic cobalt that would diminish the active sites concentration and also block the channels, thus preventing the access of the reactants.Fil: Gutierrez, Laura Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Irusta, S.. Universidad de Zaragoza; EspañaElsevier Science2008-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65154Gutierrez, Laura Beatriz; Miro, Eduardo Ernesto; Irusta, S.; Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments; Elsevier Science; Microporous and Mesoporous Materials; 114; 1-3; 9-2008; 281-2921387-1811CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2008.01.014info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:07:03Zoai:ri.conicet.gov.ar:11336/65154instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:07:03.345CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments
title Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments
spellingShingle Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments
Gutierrez, Laura Beatriz
Co-Mordenites
Co-Ftir
No-Ftir
Py-Ftir
title_short Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments
title_full Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments
title_fullStr Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments
title_full_unstemmed Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments
title_sort Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments
dc.creator.none.fl_str_mv Gutierrez, Laura Beatriz
Miro, Eduardo Ernesto
Irusta, S.
author Gutierrez, Laura Beatriz
author_facet Gutierrez, Laura Beatriz
Miro, Eduardo Ernesto
Irusta, S.
author_role author
author2 Miro, Eduardo Ernesto
Irusta, S.
author2_role author
author
dc.subject.none.fl_str_mv Co-Mordenites
Co-Ftir
No-Ftir
Py-Ftir
topic Co-Mordenites
Co-Ftir
No-Ftir
Py-Ftir
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Co-mordenites were prepared by ion exchange and wet impregnation over Na-mordenite and H-mordenite. The prepared solids were calcined and aliquots of these samples were subject to redox treatments first with CO for 2 h at 773 K and then kept 2 h at the same temperature in flowing O2. A thorough characterization of the solids was carried out by TPR, XPS, CO volumetric adsorption, and FTIR with CO, NO and pyridine adsorption as probe molecules. After the redox treatment, Na based samples showed an important increase in the CO adsorption. TPR and XPS results indicated reduction of the oxides present in the calcined samples and the migration of exchanged cobalt from hidden to more exposed sites was demonstrated by FTIR. The acid catalysts did not change their CO capacity of adsorption; exchanged cobalt ions were mainly in β-type sites and remained in this position after treatment. After the redox treatments, the activity for the selective reduction of NOx with methane suffered a decrease on both types of mordenites, probably caused by the strong adsorption of NO and the reduction of β-type Co2+ to metallic cobalt that would diminish the active sites concentration and also block the channels, thus preventing the access of the reactants.
Fil: Gutierrez, Laura Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Irusta, S.. Universidad de Zaragoza; España
description Co-mordenites were prepared by ion exchange and wet impregnation over Na-mordenite and H-mordenite. The prepared solids were calcined and aliquots of these samples were subject to redox treatments first with CO for 2 h at 773 K and then kept 2 h at the same temperature in flowing O2. A thorough characterization of the solids was carried out by TPR, XPS, CO volumetric adsorption, and FTIR with CO, NO and pyridine adsorption as probe molecules. After the redox treatment, Na based samples showed an important increase in the CO adsorption. TPR and XPS results indicated reduction of the oxides present in the calcined samples and the migration of exchanged cobalt from hidden to more exposed sites was demonstrated by FTIR. The acid catalysts did not change their CO capacity of adsorption; exchanged cobalt ions were mainly in β-type sites and remained in this position after treatment. After the redox treatments, the activity for the selective reduction of NOx with methane suffered a decrease on both types of mordenites, probably caused by the strong adsorption of NO and the reduction of β-type Co2+ to metallic cobalt that would diminish the active sites concentration and also block the channels, thus preventing the access of the reactants.
publishDate 2008
dc.date.none.fl_str_mv 2008-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/65154
Gutierrez, Laura Beatriz; Miro, Eduardo Ernesto; Irusta, S.; Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments; Elsevier Science; Microporous and Mesoporous Materials; 114; 1-3; 9-2008; 281-292
1387-1811
CONICET Digital
CONICET
url http://hdl.handle.net/11336/65154
identifier_str_mv Gutierrez, Laura Beatriz; Miro, Eduardo Ernesto; Irusta, S.; Spectroscopic and catalytic characterization of Co-exchanged mordenites subject to CO/O2 redox treatments; Elsevier Science; Microporous and Mesoporous Materials; 114; 1-3; 9-2008; 281-292
1387-1811
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2008.01.014
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613925618843648
score 13.070432

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