Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates

Autores
de Castro Bubani, Franco; Sade Lichtmann, Marcos Leonel; Lovey, Francisco
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Mechanical damping applications could benefit from the large hysteresis, large pseudoelastic strain and the fact that the transformation stresses of the 18R↔6R martensite–martensite transformation depend very little on temperature in Cu-based alloys. This work presents the 18R↔6R mechanical cycling behavior of CuZnAl shape-memory alloy single crystals with electronic concentration e/a¼1.48. A fine distribution of gamma phase nanoprecipitates is introduced to prevent plastic deformation of the 6R phase. Results show that, although significant 6R stabilization is observed at very low frequencies (below 10−2 Hz), it is possible to obtain more than 1000 stable pseudoelastic cycles with only minor changes in transformation stresses and hysteresis width at frequencies above 10−1 Hz. A more pronounced decrease in transformation stresses is observed after 1000 cycles. Nevertheless, the decrease in hysteresis is small up to 2000 cycles. Reported and present results indicate that pair interchange of atoms can explain the stabilization of 6R under quasistatic experimental conditions. However, at higher frequencies of cycling, stabilization of this martensite shows additional features, leading to a dynamic stabilization with slight effects on the mechanical behavior at the required frequency and number of cycles. On the whole, the behavior of this transformation is unique and very promising.
Fil: de Castro Bubani, Franco. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Sade Lichtmann, Marcos Leonel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Lovey, Francisco. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; Argentina
Materia
Shape Memory Alloys
Mechanical Characterization
Martensitic Transformations
Strain Measurement
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/8978

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spelling Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitatesde Castro Bubani, FrancoSade Lichtmann, Marcos LeonelLovey, FranciscoShape Memory AlloysMechanical CharacterizationMartensitic TransformationsStrain Measurementhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Mechanical damping applications could benefit from the large hysteresis, large pseudoelastic strain and the fact that the transformation stresses of the 18R↔6R martensite–martensite transformation depend very little on temperature in Cu-based alloys. This work presents the 18R↔6R mechanical cycling behavior of CuZnAl shape-memory alloy single crystals with electronic concentration e/a¼1.48. A fine distribution of gamma phase nanoprecipitates is introduced to prevent plastic deformation of the 6R phase. Results show that, although significant 6R stabilization is observed at very low frequencies (below 10−2 Hz), it is possible to obtain more than 1000 stable pseudoelastic cycles with only minor changes in transformation stresses and hysteresis width at frequencies above 10−1 Hz. A more pronounced decrease in transformation stresses is observed after 1000 cycles. Nevertheless, the decrease in hysteresis is small up to 2000 cycles. Reported and present results indicate that pair interchange of atoms can explain the stabilization of 6R under quasistatic experimental conditions. However, at higher frequencies of cycling, stabilization of this martensite shows additional features, leading to a dynamic stabilization with slight effects on the mechanical behavior at the required frequency and number of cycles. On the whole, the behavior of this transformation is unique and very promising.Fil: de Castro Bubani, Franco. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Sade Lichtmann, Marcos Leonel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Lovey, Francisco. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; ArgentinaElsevier Science2013-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/8978de Castro Bubani, Franco; Sade Lichtmann, Marcos Leonel; Lovey, Francisco; Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates; Elsevier Science; Materials Science And Engineering A: Structural Materials: Properties, Microstructure And Processing; 577; 8-2013; 147-1570921-5093enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S092150931300419Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.msea.2013.04.037info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:11:50Zoai:ri.conicet.gov.ar:11336/8978instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:11:51.129CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates
title Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates
spellingShingle Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates
de Castro Bubani, Franco
Shape Memory Alloys
Mechanical Characterization
Martensitic Transformations
Strain Measurement
title_short Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates
title_full Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates
title_fullStr Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates
title_full_unstemmed Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates
title_sort Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates
dc.creator.none.fl_str_mv de Castro Bubani, Franco
Sade Lichtmann, Marcos Leonel
Lovey, Francisco
author de Castro Bubani, Franco
author_facet de Castro Bubani, Franco
Sade Lichtmann, Marcos Leonel
Lovey, Francisco
author_role author
author2 Sade Lichtmann, Marcos Leonel
Lovey, Francisco
author2_role author
author
dc.subject.none.fl_str_mv Shape Memory Alloys
Mechanical Characterization
Martensitic Transformations
Strain Measurement
topic Shape Memory Alloys
Mechanical Characterization
Martensitic Transformations
Strain Measurement
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Mechanical damping applications could benefit from the large hysteresis, large pseudoelastic strain and the fact that the transformation stresses of the 18R↔6R martensite–martensite transformation depend very little on temperature in Cu-based alloys. This work presents the 18R↔6R mechanical cycling behavior of CuZnAl shape-memory alloy single crystals with electronic concentration e/a¼1.48. A fine distribution of gamma phase nanoprecipitates is introduced to prevent plastic deformation of the 6R phase. Results show that, although significant 6R stabilization is observed at very low frequencies (below 10−2 Hz), it is possible to obtain more than 1000 stable pseudoelastic cycles with only minor changes in transformation stresses and hysteresis width at frequencies above 10−1 Hz. A more pronounced decrease in transformation stresses is observed after 1000 cycles. Nevertheless, the decrease in hysteresis is small up to 2000 cycles. Reported and present results indicate that pair interchange of atoms can explain the stabilization of 6R under quasistatic experimental conditions. However, at higher frequencies of cycling, stabilization of this martensite shows additional features, leading to a dynamic stabilization with slight effects on the mechanical behavior at the required frequency and number of cycles. On the whole, the behavior of this transformation is unique and very promising.
Fil: de Castro Bubani, Franco. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Sade Lichtmann, Marcos Leonel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Lovey, Francisco. Comision Nacional de Energia Atomica. Gerencia del Area de Investigaciones y Aplicaciones no Nucleares. Gerencia de Fisica (CAB); Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Energía Nuclear. Instituto Balseiro; Argentina
description Mechanical damping applications could benefit from the large hysteresis, large pseudoelastic strain and the fact that the transformation stresses of the 18R↔6R martensite–martensite transformation depend very little on temperature in Cu-based alloys. This work presents the 18R↔6R mechanical cycling behavior of CuZnAl shape-memory alloy single crystals with electronic concentration e/a¼1.48. A fine distribution of gamma phase nanoprecipitates is introduced to prevent plastic deformation of the 6R phase. Results show that, although significant 6R stabilization is observed at very low frequencies (below 10−2 Hz), it is possible to obtain more than 1000 stable pseudoelastic cycles with only minor changes in transformation stresses and hysteresis width at frequencies above 10−1 Hz. A more pronounced decrease in transformation stresses is observed after 1000 cycles. Nevertheless, the decrease in hysteresis is small up to 2000 cycles. Reported and present results indicate that pair interchange of atoms can explain the stabilization of 6R under quasistatic experimental conditions. However, at higher frequencies of cycling, stabilization of this martensite shows additional features, leading to a dynamic stabilization with slight effects on the mechanical behavior at the required frequency and number of cycles. On the whole, the behavior of this transformation is unique and very promising.
publishDate 2013
dc.date.none.fl_str_mv 2013-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/8978
de Castro Bubani, Franco; Sade Lichtmann, Marcos Leonel; Lovey, Francisco; Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates; Elsevier Science; Materials Science And Engineering A: Structural Materials: Properties, Microstructure And Processing; 577; 8-2013; 147-157
0921-5093
url http://hdl.handle.net/11336/8978
identifier_str_mv de Castro Bubani, Franco; Sade Lichtmann, Marcos Leonel; Lovey, Francisco; Mechanical Behavior Under Cyclic Loading of the 18R-6R High-hysteresis Martensitic Transformation in Cu-Zn-Al alloys with Nanoprecipitates; Elsevier Science; Materials Science And Engineering A: Structural Materials: Properties, Microstructure And Processing; 577; 8-2013; 147-157
0921-5093
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S092150931300419X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.msea.2013.04.037
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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