Radical amination with trimethylstannylated benzophenone imine

Autores
Lamas, Marie-Céline; Vaillard, Santiago Eduardo; Wibbeling, Birgit; Studer, Armido
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.
Fil: Lamas, Marie-Céline. Westfälische Wilhelms-Universität; Alemania
Fil: Vaillard, Santiago Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Westfälische Wilhelms-Universität; Alemania
Fil: Wibbeling, Birgit. Westfälische Wilhelms-Universität; Alemania
Fil: Studer, Armido. Westfälische Wilhelms-Universität; Alemania
Materia
Homolytic Substitution
Amination
Imines
Radicals
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/13703
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/13703
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Radical amination with trimethylstannylated benzophenone imineLamas, Marie-CélineVaillard, Santiago EduardoWibbeling, BirgitStuder, ArmidoHomolytic SubstitutionAminationIminesRadicalshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.Fil: Lamas, Marie-Céline. Westfälische Wilhelms-Universität; AlemaniaFil: Vaillard, Santiago Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Westfälische Wilhelms-Universität; AlemaniaFil: Wibbeling, Birgit. Westfälische Wilhelms-Universität; AlemaniaFil: Studer, Armido. Westfälische Wilhelms-Universität; AlemaniaAmerican Chemical Society2010-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13703Lamas, Marie-Céline; Vaillard, Santiago Eduardo; Wibbeling, Birgit; Studer, Armido; Radical amination with trimethylstannylated benzophenone imine; American Chemical Society; Organic Letters; 12; 9; 4-2010; 2072-20751523-7060enginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ol1005455info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ol1005455info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:55:02Zoai:ri.conicet.gov.ar:11336/13703instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:55:03.166CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Radical amination with trimethylstannylated benzophenone imine
title Radical amination with trimethylstannylated benzophenone imine
spellingShingle Radical amination with trimethylstannylated benzophenone imine
Lamas, Marie-Céline
Homolytic Substitution
Amination
Imines
Radicals
title_short Radical amination with trimethylstannylated benzophenone imine
title_full Radical amination with trimethylstannylated benzophenone imine
title_fullStr Radical amination with trimethylstannylated benzophenone imine
title_full_unstemmed Radical amination with trimethylstannylated benzophenone imine
title_sort Radical amination with trimethylstannylated benzophenone imine
dc.creator.none.fl_str_mv Lamas, Marie-Céline
Vaillard, Santiago Eduardo
Wibbeling, Birgit
Studer, Armido
author Lamas, Marie-Céline
author_facet Lamas, Marie-Céline
Vaillard, Santiago Eduardo
Wibbeling, Birgit
Studer, Armido
author_role author
author2 Vaillard, Santiago Eduardo
Wibbeling, Birgit
Studer, Armido
author2_role author
author
author
dc.subject.none.fl_str_mv Homolytic Substitution
Amination
Imines
Radicals
topic Homolytic Substitution
Amination
Imines
Radicals
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.
Fil: Lamas, Marie-Céline. Westfälische Wilhelms-Universität; Alemania
Fil: Vaillard, Santiago Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Westfälische Wilhelms-Universität; Alemania
Fil: Wibbeling, Birgit. Westfälische Wilhelms-Universität; Alemania
Fil: Studer, Armido. Westfälische Wilhelms-Universität; Alemania
description Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.
publishDate 2010
dc.date.none.fl_str_mv 2010-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/13703
Lamas, Marie-Céline; Vaillard, Santiago Eduardo; Wibbeling, Birgit; Studer, Armido; Radical amination with trimethylstannylated benzophenone imine; American Chemical Society; Organic Letters; 12; 9; 4-2010; 2072-2075
1523-7060
url http://hdl.handle.net/11336/13703
identifier_str_mv Lamas, Marie-Céline; Vaillard, Santiago Eduardo; Wibbeling, Birgit; Studer, Armido; Radical amination with trimethylstannylated benzophenone imine; American Chemical Society; Organic Letters; 12; 9; 4-2010; 2072-2075
1523-7060
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ol1005455
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ol1005455
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1848598279748583424
score 12.976206

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