Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry

Autores
Coneo Rodríguez, Rusbel; Yate, Luis; Coy, Emerson; Martínez Villacorta, Ángel M.; Bordoni, Andrea Veronica; Moya, Sergio; Angelome, Paula Cecilia
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The room temperature synthesis of copper (Cu) nanoparticles (NPs) supported within SiO2 mesoporous thin films (MTF) modified with either COOH or NH2 functional groups is reported. The functional groups present in the MTF surface acted as adsorption sites for Cu (II) ions, which were afterwards reduced to Cu NPs in presence of sodium borohydride at room temperature. The oxidation state of the copper NPs, corroborated by X-ray Photoelectron Spectroscopy and Electron Energy Loss Spectroscopy, was strongly dependent on the functional group present in the pores of the MTF and on the number of adsorption/reduction (A/R) cycles applied for NPs loading. Metallic Cu (0) NPs were obtained in MTFs displaying COOH groups applying 10 A/R cycles while NPs with higher oxidation state were as well present after 20 A/R cycles. For MTF functionalized with NH2 groups the copper is present as Cu (I) and Cu(II) in the NPs but no Cu (0) can be detected. The MTF-Cu(CuOx) composite materials were tested as catalysts for the reduction of 4-nitrophenol in the presence of NaBH4. Catalytic activity of composite materials depends on the oxidation state of Cu NPs, being more active those samples containing Cu (0) NPs, synthesized from COOH functionalized MTFs.
Fil: Coneo Rodríguez, Rusbel. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina
Fil: Yate, Luis. No especifíca;
Fil: Coy, Emerson. Adam Mickiewicz University; Polonia
Fil: Martínez Villacorta, Ángel M.. No especifíca;
Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina
Fil: Moya, Sergio. No especifíca;
Fil: Angelome, Paula Cecilia. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina
Materia
COPPER NANOPARTICLES
MESOPOROUS THIN FILMS
HYBRID MATERIALS
CATALYSIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/121801
Acceder
id CONICETDig_9ddf484b21c49b4ca9929a334d0fbdaa
oai_identifier_str oai:ri.conicet.gov.ar:11336/121801
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistryConeo Rodríguez, RusbelYate, LuisCoy, EmersonMartínez Villacorta, Ángel M.Bordoni, Andrea VeronicaMoya, SergioAngelome, Paula CeciliaCOPPER NANOPARTICLESMESOPOROUS THIN FILMSHYBRID MATERIALSCATALYSIShttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2The room temperature synthesis of copper (Cu) nanoparticles (NPs) supported within SiO2 mesoporous thin films (MTF) modified with either COOH or NH2 functional groups is reported. The functional groups present in the MTF surface acted as adsorption sites for Cu (II) ions, which were afterwards reduced to Cu NPs in presence of sodium borohydride at room temperature. The oxidation state of the copper NPs, corroborated by X-ray Photoelectron Spectroscopy and Electron Energy Loss Spectroscopy, was strongly dependent on the functional group present in the pores of the MTF and on the number of adsorption/reduction (A/R) cycles applied for NPs loading. Metallic Cu (0) NPs were obtained in MTFs displaying COOH groups applying 10 A/R cycles while NPs with higher oxidation state were as well present after 20 A/R cycles. For MTF functionalized with NH2 groups the copper is present as Cu (I) and Cu(II) in the NPs but no Cu (0) can be detected. The MTF-Cu(CuOx) composite materials were tested as catalysts for the reduction of 4-nitrophenol in the presence of NaBH4. Catalytic activity of composite materials depends on the oxidation state of Cu NPs, being more active those samples containing Cu (0) NPs, synthesized from COOH functionalized MTFs.Fil: Coneo Rodríguez, Rusbel. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; ArgentinaFil: Yate, Luis. No especifíca;Fil: Coy, Emerson. Adam Mickiewicz University; PoloniaFil: Martínez Villacorta, Ángel M.. No especifíca;Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; ArgentinaFil: Moya, Sergio. No especifíca;Fil: Angelome, Paula Cecilia. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaElsevier Science2019-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/121801Coneo Rodríguez, Rusbel; Yate, Luis; Coy, Emerson; Martínez Villacorta, Ángel M.; Bordoni, Andrea Veronica; et al.; Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry; Elsevier Science; Applied Surface Science; 471; 3-2019; 862-8680169-4332CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S016943321833397Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2018.12.068info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:56Zoai:ri.conicet.gov.ar:11336/121801instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:56.705CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry
title Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry
spellingShingle Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry
Coneo Rodríguez, Rusbel
COPPER NANOPARTICLES
MESOPOROUS THIN FILMS
HYBRID MATERIALS
CATALYSIS
title_short Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry
title_full Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry
title_fullStr Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry
title_full_unstemmed Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry
title_sort Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry
dc.creator.none.fl_str_mv Coneo Rodríguez, Rusbel
Yate, Luis
Coy, Emerson
Martínez Villacorta, Ángel M.
Bordoni, Andrea Veronica
Moya, Sergio
Angelome, Paula Cecilia
author Coneo Rodríguez, Rusbel
author_facet Coneo Rodríguez, Rusbel
Yate, Luis
Coy, Emerson
Martínez Villacorta, Ángel M.
Bordoni, Andrea Veronica
Moya, Sergio
Angelome, Paula Cecilia
author_role author
author2 Yate, Luis
Coy, Emerson
Martínez Villacorta, Ángel M.
Bordoni, Andrea Veronica
Moya, Sergio
Angelome, Paula Cecilia
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv COPPER NANOPARTICLES
MESOPOROUS THIN FILMS
HYBRID MATERIALS
CATALYSIS
topic COPPER NANOPARTICLES
MESOPOROUS THIN FILMS
HYBRID MATERIALS
CATALYSIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The room temperature synthesis of copper (Cu) nanoparticles (NPs) supported within SiO2 mesoporous thin films (MTF) modified with either COOH or NH2 functional groups is reported. The functional groups present in the MTF surface acted as adsorption sites for Cu (II) ions, which were afterwards reduced to Cu NPs in presence of sodium borohydride at room temperature. The oxidation state of the copper NPs, corroborated by X-ray Photoelectron Spectroscopy and Electron Energy Loss Spectroscopy, was strongly dependent on the functional group present in the pores of the MTF and on the number of adsorption/reduction (A/R) cycles applied for NPs loading. Metallic Cu (0) NPs were obtained in MTFs displaying COOH groups applying 10 A/R cycles while NPs with higher oxidation state were as well present after 20 A/R cycles. For MTF functionalized with NH2 groups the copper is present as Cu (I) and Cu(II) in the NPs but no Cu (0) can be detected. The MTF-Cu(CuOx) composite materials were tested as catalysts for the reduction of 4-nitrophenol in the presence of NaBH4. Catalytic activity of composite materials depends on the oxidation state of Cu NPs, being more active those samples containing Cu (0) NPs, synthesized from COOH functionalized MTFs.
Fil: Coneo Rodríguez, Rusbel. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina
Fil: Yate, Luis. No especifíca;
Fil: Coy, Emerson. Adam Mickiewicz University; Polonia
Fil: Martínez Villacorta, Ángel M.. No especifíca;
Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina
Fil: Moya, Sergio. No especifíca;
Fil: Angelome, Paula Cecilia. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina
description The room temperature synthesis of copper (Cu) nanoparticles (NPs) supported within SiO2 mesoporous thin films (MTF) modified with either COOH or NH2 functional groups is reported. The functional groups present in the MTF surface acted as adsorption sites for Cu (II) ions, which were afterwards reduced to Cu NPs in presence of sodium borohydride at room temperature. The oxidation state of the copper NPs, corroborated by X-ray Photoelectron Spectroscopy and Electron Energy Loss Spectroscopy, was strongly dependent on the functional group present in the pores of the MTF and on the number of adsorption/reduction (A/R) cycles applied for NPs loading. Metallic Cu (0) NPs were obtained in MTFs displaying COOH groups applying 10 A/R cycles while NPs with higher oxidation state were as well present after 20 A/R cycles. For MTF functionalized with NH2 groups the copper is present as Cu (I) and Cu(II) in the NPs but no Cu (0) can be detected. The MTF-Cu(CuOx) composite materials were tested as catalysts for the reduction of 4-nitrophenol in the presence of NaBH4. Catalytic activity of composite materials depends on the oxidation state of Cu NPs, being more active those samples containing Cu (0) NPs, synthesized from COOH functionalized MTFs.
publishDate 2019
dc.date.none.fl_str_mv 2019-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/121801
Coneo Rodríguez, Rusbel; Yate, Luis; Coy, Emerson; Martínez Villacorta, Ángel M.; Bordoni, Andrea Veronica; et al.; Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry; Elsevier Science; Applied Surface Science; 471; 3-2019; 862-868
0169-4332
CONICET Digital
CONICET
url http://hdl.handle.net/11336/121801
identifier_str_mv Coneo Rodríguez, Rusbel; Yate, Luis; Coy, Emerson; Martínez Villacorta, Ángel M.; Bordoni, Andrea Veronica; et al.; Copper nanoparticles synthesis in hybrid mesoporous thin films: Controlling oxidation state and catalytic performance through pore chemistry; Elsevier Science; Applied Surface Science; 471; 3-2019; 862-868
0169-4332
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S016943321833397X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2018.12.068
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614235561132032
score 13.070432

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