Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol

Autores
Taverna, María Eugenia; Ollearo, Rocío; Moran, Juan Ignacio; Nicolau, Veronica Viviana; Estenoz, Diana Alejandra; Frontini, Patricia Maria
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Reducing the consumption of phenol during synthesis of phenolic resins is of great technological and scientific interest because of its economic and environmental implications. In this work, the use of hydroxymethylated lignins as a partial replacement for phenol in resol phenol-formaldehyde resins used for the production of decorative laminates was experimentally studied. The work involved: i) the industrial synthesis of traditional and modified resols with 10%w/w of sodium lignosulfonate and kraft-type lignin; ii) the industrial impregnation of kraft-type paper with the produced resins; iii) the production of laminates on both laboratory and industrial scales; and iv) the measurement of their final properties. The mechanical performance of the laminates was evaluated via the determination of the Young modulus, bending strength, biaxial impact strength, and Mode-I interlaminar fracture toughness. The (modified and traditional) laminates exhibited statistically significant differences in mechanical properties. However, the partial lignin replacement did not produce effects that were detrimental effects to the overall performance of the decorative laminates.
Fil: Taverna, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Ollearo, Rocío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Moran, Juan Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina
Fil: Nicolau, Veronica Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad Tecnologica Nacional; Argentina
Fil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Materia
LAMINATE
RESOL
LIGNIN
MECHANICAL PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10043
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/10043
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for PhenolTaverna, María EugeniaOllearo, RocíoMoran, Juan IgnacioNicolau, Veronica VivianaEstenoz, Diana AlejandraFrontini, Patricia MariaLAMINATERESOLLIGNINMECHANICAL PROPERTIEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Reducing the consumption of phenol during synthesis of phenolic resins is of great technological and scientific interest because of its economic and environmental implications. In this work, the use of hydroxymethylated lignins as a partial replacement for phenol in resol phenol-formaldehyde resins used for the production of decorative laminates was experimentally studied. The work involved: i) the industrial synthesis of traditional and modified resols with 10%w/w of sodium lignosulfonate and kraft-type lignin; ii) the industrial impregnation of kraft-type paper with the produced resins; iii) the production of laminates on both laboratory and industrial scales; and iv) the measurement of their final properties. The mechanical performance of the laminates was evaluated via the determination of the Young modulus, bending strength, biaxial impact strength, and Mode-I interlaminar fracture toughness. The (modified and traditional) laminates exhibited statistically significant differences in mechanical properties. However, the partial lignin replacement did not produce effects that were detrimental effects to the overall performance of the decorative laminates.Fil: Taverna, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaFil: Ollearo, Rocío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Moran, Juan Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); ArgentinaFil: Nicolau, Veronica Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad Tecnologica Nacional; ArgentinaFil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaFil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaNorth Carolina State University. Department Of Wood And Paper Science2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10043Taverna, María Eugenia; Ollearo, Rocío; Moran, Juan Ignacio; Nicolau, Veronica Viviana; Estenoz, Diana Alejandra; et al.; Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol; North Carolina State University. Department Of Wood And Paper Science; Bioresources; 10; 4; 10-2015; 8325-83381930-2126enginfo:eu-repo/semantics/altIdentifier/url/http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_10_4_8325_Taverna_Mechanical_Evaluation_Laminates_Phenolicinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:39:13Zoai:ri.conicet.gov.ar:11336/10043instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:39:13.962CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol
title Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol
spellingShingle Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol
Taverna, María Eugenia
LAMINATE
RESOL
LIGNIN
MECHANICAL PROPERTIES
title_short Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol
title_full Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol
title_fullStr Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol
title_full_unstemmed Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol
title_sort Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol
dc.creator.none.fl_str_mv Taverna, María Eugenia
Ollearo, Rocío
Moran, Juan Ignacio
Nicolau, Veronica Viviana
Estenoz, Diana Alejandra
Frontini, Patricia Maria
author Taverna, María Eugenia
author_facet Taverna, María Eugenia
Ollearo, Rocío
Moran, Juan Ignacio
Nicolau, Veronica Viviana
Estenoz, Diana Alejandra
Frontini, Patricia Maria
author_role author
author2 Ollearo, Rocío
Moran, Juan Ignacio
Nicolau, Veronica Viviana
Estenoz, Diana Alejandra
Frontini, Patricia Maria
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv LAMINATE
RESOL
LIGNIN
MECHANICAL PROPERTIES
topic LAMINATE
RESOL
LIGNIN
MECHANICAL PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Reducing the consumption of phenol during synthesis of phenolic resins is of great technological and scientific interest because of its economic and environmental implications. In this work, the use of hydroxymethylated lignins as a partial replacement for phenol in resol phenol-formaldehyde resins used for the production of decorative laminates was experimentally studied. The work involved: i) the industrial synthesis of traditional and modified resols with 10%w/w of sodium lignosulfonate and kraft-type lignin; ii) the industrial impregnation of kraft-type paper with the produced resins; iii) the production of laminates on both laboratory and industrial scales; and iv) the measurement of their final properties. The mechanical performance of the laminates was evaluated via the determination of the Young modulus, bending strength, biaxial impact strength, and Mode-I interlaminar fracture toughness. The (modified and traditional) laminates exhibited statistically significant differences in mechanical properties. However, the partial lignin replacement did not produce effects that were detrimental effects to the overall performance of the decorative laminates.
Fil: Taverna, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Ollearo, Rocío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Moran, Juan Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina
Fil: Nicolau, Veronica Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad Tecnologica Nacional; Argentina
Fil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
description Reducing the consumption of phenol during synthesis of phenolic resins is of great technological and scientific interest because of its economic and environmental implications. In this work, the use of hydroxymethylated lignins as a partial replacement for phenol in resol phenol-formaldehyde resins used for the production of decorative laminates was experimentally studied. The work involved: i) the industrial synthesis of traditional and modified resols with 10%w/w of sodium lignosulfonate and kraft-type lignin; ii) the industrial impregnation of kraft-type paper with the produced resins; iii) the production of laminates on both laboratory and industrial scales; and iv) the measurement of their final properties. The mechanical performance of the laminates was evaluated via the determination of the Young modulus, bending strength, biaxial impact strength, and Mode-I interlaminar fracture toughness. The (modified and traditional) laminates exhibited statistically significant differences in mechanical properties. However, the partial lignin replacement did not produce effects that were detrimental effects to the overall performance of the decorative laminates.
publishDate 2015
dc.date.none.fl_str_mv 2015-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10043
Taverna, María Eugenia; Ollearo, Rocío; Moran, Juan Ignacio; Nicolau, Veronica Viviana; Estenoz, Diana Alejandra; et al.; Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol; North Carolina State University. Department Of Wood And Paper Science; Bioresources; 10; 4; 10-2015; 8325-8338
1930-2126
url http://hdl.handle.net/11336/10043
identifier_str_mv Taverna, María Eugenia; Ollearo, Rocío; Moran, Juan Ignacio; Nicolau, Veronica Viviana; Estenoz, Diana Alejandra; et al.; Mechanical Evaluation of Laminates Based on Phenolic Resins using Lignins as Partial Substitutes for Phenol; North Carolina State University. Department Of Wood And Paper Science; Bioresources; 10; 4; 10-2015; 8325-8338
1930-2126
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_10_4_8325_Taverna_Mechanical_Evaluation_Laminates_Phenolic
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv North Carolina State University. Department Of Wood And Paper Science
publisher.none.fl_str_mv North Carolina State University. Department Of Wood And Paper Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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