Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate

Autores
Riveira, Martín Jorge; Mischne, Mirta Paulina
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Ethylenediammonium diacetate readily catalyzes the Knoevenagel-type condensation between 1,3-dicarbonyl substrates and α,β-unsaturated aldehydes at room temperature under solvent-free conditions. This rapid, efficient, and convenient one-pot approach to the synthesis of 2H-pyrans stands as a significant advance over previously reported protocols. This environmentally friendly methodology has been successfully applied to the synthesis of biologically active natural products of interest zanthosimuline, N-methylflindersine, and ferprenin.
Fil: Riveira, Martín Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Fil: Mischne, Mirta Paulina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Materia
Green Chemistry
Solvent-Free
Domino Reactions
2h-Pyrans
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6133
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/6133
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetateRiveira, Martín JorgeMischne, Mirta PaulinaGreen ChemistrySolvent-FreeDomino Reactions2h-Pyranshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Ethylenediammonium diacetate readily catalyzes the Knoevenagel-type condensation between 1,3-dicarbonyl substrates and α,β-unsaturated aldehydes at room temperature under solvent-free conditions. This rapid, efficient, and convenient one-pot approach to the synthesis of 2H-pyrans stands as a significant advance over previously reported protocols. This environmentally friendly methodology has been successfully applied to the synthesis of biologically active natural products of interest zanthosimuline, N-methylflindersine, and ferprenin.Fil: Riveira, Martín Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; ArgentinaFil: Mischne, Mirta Paulina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; ArgentinaTaylor2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6133Riveira, Martín Jorge; Mischne, Mirta Paulina; Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate; Taylor; Synthetic Communications; 43; 2; 1-2013; 208-2200039-7911enginfo:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/abs/10.1080/00397911.2011.594975info:eu-repo/semantics/altIdentifier/doi/10.1080/00397911.2011.594975info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:00:25Zoai:ri.conicet.gov.ar:11336/6133instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:00:25.758CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate
title Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate
spellingShingle Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate
Riveira, Martín Jorge
Green Chemistry
Solvent-Free
Domino Reactions
2h-Pyrans
title_short Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate
title_full Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate
title_fullStr Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate
title_full_unstemmed Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate
title_sort Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate
dc.creator.none.fl_str_mv Riveira, Martín Jorge
Mischne, Mirta Paulina
author Riveira, Martín Jorge
author_facet Riveira, Martín Jorge
Mischne, Mirta Paulina
author_role author
author2 Mischne, Mirta Paulina
author2_role author
dc.subject.none.fl_str_mv Green Chemistry
Solvent-Free
Domino Reactions
2h-Pyrans
topic Green Chemistry
Solvent-Free
Domino Reactions
2h-Pyrans
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Ethylenediammonium diacetate readily catalyzes the Knoevenagel-type condensation between 1,3-dicarbonyl substrates and α,β-unsaturated aldehydes at room temperature under solvent-free conditions. This rapid, efficient, and convenient one-pot approach to the synthesis of 2H-pyrans stands as a significant advance over previously reported protocols. This environmentally friendly methodology has been successfully applied to the synthesis of biologically active natural products of interest zanthosimuline, N-methylflindersine, and ferprenin.
Fil: Riveira, Martín Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Fil: Mischne, Mirta Paulina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
description Ethylenediammonium diacetate readily catalyzes the Knoevenagel-type condensation between 1,3-dicarbonyl substrates and α,β-unsaturated aldehydes at room temperature under solvent-free conditions. This rapid, efficient, and convenient one-pot approach to the synthesis of 2H-pyrans stands as a significant advance over previously reported protocols. This environmentally friendly methodology has been successfully applied to the synthesis of biologically active natural products of interest zanthosimuline, N-methylflindersine, and ferprenin.
publishDate 2013
dc.date.none.fl_str_mv 2013-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6133
Riveira, Martín Jorge; Mischne, Mirta Paulina; Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate; Taylor; Synthetic Communications; 43; 2; 1-2013; 208-220
0039-7911
url http://hdl.handle.net/11336/6133
identifier_str_mv Riveira, Martín Jorge; Mischne, Mirta Paulina; Green one-pot synthesis of 2H-pyrans under solvent-free conditions catalyzed by ethylenediammonium diacetate; Taylor; Synthetic Communications; 43; 2; 1-2013; 208-220
0039-7911
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/abs/10.1080/00397911.2011.594975
info:eu-repo/semantics/altIdentifier/doi/10.1080/00397911.2011.594975
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor
publisher.none.fl_str_mv Taylor
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842979880065564672
score 12.48226

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