Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys

Autores
Mota, F. L.; Fabietti, Luis Maria Rodolfo; Bergeon, N.; Strutzenberg, L. L.; Karma, A.; Billia, B.; Trivedi, R.
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Different phase diagram measurements for succinonitrile-camphor alloys to date have yielded different values of the solute partition coefficient and the freezing range of the alloy. These parameters are critical to model solidification microstructure evolution. New measurements are made to precisely characterize the dilute limit of the succinonitrile-camphor phase diagram using thin-sample directional solidification experiments where convection is negligible, so that solute transport in the melt is purely diffusive, and the temperature gradient is constant in time. These results are confirmed through complementary measurements by differential scanning calorimetry and isothermal annealing. Possible measurement uncertainties in previously measured solidus lines are discussed. Experimental results were further confirmed using a boundary layer model of transient planar interface dynamics.
Fil: Mota, F. L.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; Francia. Iowa State University; Estados Unidos
Fil: Fabietti, Luis Maria Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Bergeon, N.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Strutzenberg, L. L.. Marshall Space Flight Center; Estados Unidos
Fil: Karma, A.. Northeastern University; Estados Unidos
Fil: Billia, B.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Trivedi, R.. Iowa State University; Estados Unidos
Materia
A1. Differential Scanning Calorimetry
A1. Directional Solidification
A1. Isothermal Heat Treatments
A1. Phase Diagrams
B1. Succinonitrile-Camphor
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/72245
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/72245
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloysMota, F. L.Fabietti, Luis Maria RodolfoBergeon, N.Strutzenberg, L. L.Karma, A.Billia, B.Trivedi, R.A1. Differential Scanning CalorimetryA1. Directional SolidificationA1. Isothermal Heat TreatmentsA1. Phase DiagramsB1. Succinonitrile-Camphorhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Different phase diagram measurements for succinonitrile-camphor alloys to date have yielded different values of the solute partition coefficient and the freezing range of the alloy. These parameters are critical to model solidification microstructure evolution. New measurements are made to precisely characterize the dilute limit of the succinonitrile-camphor phase diagram using thin-sample directional solidification experiments where convection is negligible, so that solute transport in the melt is purely diffusive, and the temperature gradient is constant in time. These results are confirmed through complementary measurements by differential scanning calorimetry and isothermal annealing. Possible measurement uncertainties in previously measured solidus lines are discussed. Experimental results were further confirmed using a boundary layer model of transient planar interface dynamics.Fil: Mota, F. L.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; Francia. Iowa State University; Estados UnidosFil: Fabietti, Luis Maria Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Bergeon, N.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; FranciaFil: Strutzenberg, L. L.. Marshall Space Flight Center; Estados UnidosFil: Karma, A.. Northeastern University; Estados UnidosFil: Billia, B.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; FranciaFil: Trivedi, R.. Iowa State University; Estados UnidosElsevier Science2016-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72245Mota, F. L.; Fabietti, Luis Maria Rodolfo; Bergeon, N.; Strutzenberg, L. L.; Karma, A.; et al.; Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys; Elsevier Science; Journal of Crystal Growth; 447; 8-2016; 31-350022-0248CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcrysgro.2016.04.054info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022024816302007info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:51Zoai:ri.conicet.gov.ar:11336/72245instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:51.947CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys
title Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys
spellingShingle Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys
Mota, F. L.
A1. Differential Scanning Calorimetry
A1. Directional Solidification
A1. Isothermal Heat Treatments
A1. Phase Diagrams
B1. Succinonitrile-Camphor
title_short Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys
title_full Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys
title_fullStr Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys
title_full_unstemmed Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys
title_sort Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys
dc.creator.none.fl_str_mv Mota, F. L.
Fabietti, Luis Maria Rodolfo
Bergeon, N.
Strutzenberg, L. L.
Karma, A.
Billia, B.
Trivedi, R.
author Mota, F. L.
author_facet Mota, F. L.
Fabietti, Luis Maria Rodolfo
Bergeon, N.
Strutzenberg, L. L.
Karma, A.
Billia, B.
Trivedi, R.
author_role author
author2 Fabietti, Luis Maria Rodolfo
Bergeon, N.
Strutzenberg, L. L.
Karma, A.
Billia, B.
Trivedi, R.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv A1. Differential Scanning Calorimetry
A1. Directional Solidification
A1. Isothermal Heat Treatments
A1. Phase Diagrams
B1. Succinonitrile-Camphor
topic A1. Differential Scanning Calorimetry
A1. Directional Solidification
A1. Isothermal Heat Treatments
A1. Phase Diagrams
B1. Succinonitrile-Camphor
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Different phase diagram measurements for succinonitrile-camphor alloys to date have yielded different values of the solute partition coefficient and the freezing range of the alloy. These parameters are critical to model solidification microstructure evolution. New measurements are made to precisely characterize the dilute limit of the succinonitrile-camphor phase diagram using thin-sample directional solidification experiments where convection is negligible, so that solute transport in the melt is purely diffusive, and the temperature gradient is constant in time. These results are confirmed through complementary measurements by differential scanning calorimetry and isothermal annealing. Possible measurement uncertainties in previously measured solidus lines are discussed. Experimental results were further confirmed using a boundary layer model of transient planar interface dynamics.
Fil: Mota, F. L.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; Francia. Iowa State University; Estados Unidos
Fil: Fabietti, Luis Maria Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Bergeon, N.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Strutzenberg, L. L.. Marshall Space Flight Center; Estados Unidos
Fil: Karma, A.. Northeastern University; Estados Unidos
Fil: Billia, B.. Aix-Marseille Université; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Trivedi, R.. Iowa State University; Estados Unidos
description Different phase diagram measurements for succinonitrile-camphor alloys to date have yielded different values of the solute partition coefficient and the freezing range of the alloy. These parameters are critical to model solidification microstructure evolution. New measurements are made to precisely characterize the dilute limit of the succinonitrile-camphor phase diagram using thin-sample directional solidification experiments where convection is negligible, so that solute transport in the melt is purely diffusive, and the temperature gradient is constant in time. These results are confirmed through complementary measurements by differential scanning calorimetry and isothermal annealing. Possible measurement uncertainties in previously measured solidus lines are discussed. Experimental results were further confirmed using a boundary layer model of transient planar interface dynamics.
publishDate 2016
dc.date.none.fl_str_mv 2016-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/72245
Mota, F. L.; Fabietti, Luis Maria Rodolfo; Bergeon, N.; Strutzenberg, L. L.; Karma, A.; et al.; Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys; Elsevier Science; Journal of Crystal Growth; 447; 8-2016; 31-35
0022-0248
CONICET Digital
CONICET
url http://hdl.handle.net/11336/72245
identifier_str_mv Mota, F. L.; Fabietti, Luis Maria Rodolfo; Bergeon, N.; Strutzenberg, L. L.; Karma, A.; et al.; Quantitative determination of the solidus line in the dilute limit of succinonitrile-camphor alloys; Elsevier Science; Journal of Crystal Growth; 447; 8-2016; 31-35
0022-0248
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcrysgro.2016.04.054
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022024816302007
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613260860456960
score 13.069144

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