X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide

Autores
Ellena, J.; Kremer, E.; Facchin, G.; Baran, Enrique José; Nascimento, O. R.; Costa Filho, A. J.; Torre, M. H.
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new complex, [Cu2(sulfameter)4]3 Æ 2.5H2O (sulfameter = 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide), has been synthesized. Its structure has been determined by single-crystal X-ray diffraction and its spectroscopic properties (EPR, IR, Raman, UV–Vis) have been analyzed. The structure presented three different dimeric units in the unit cell and the EPR spectra, characteristic of antiferromagnetically coupled dimers, revealed two magnetically different dimeric environments.
Fil: Ellena, J.. Universidade de Sao Paulo; Brasil
Fil: Kremer, E.. Universidad de la República; Uruguay
Fil: Facchin, G.. Universidad de la República; Uruguay
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Nascimento, O. R.. Universidade de Sao Paulo; Brasil
Fil: Costa Filho, A. J.. Universidade de Sao Paulo; Brasil
Fil: Torre, M. H.. Universidad de la República; Uruguay
Materia
Copper complexes
Sulfameter
Crystal structure
EPR
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/155474
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamideEllena, J.Kremer, E.Facchin, G.Baran, Enrique JoséNascimento, O. R.Costa Filho, A. J.Torre, M. H.Copper complexesSulfameterCrystal structureEPRhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new complex, [Cu2(sulfameter)4]3 Æ 2.5H2O (sulfameter = 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide), has been synthesized. Its structure has been determined by single-crystal X-ray diffraction and its spectroscopic properties (EPR, IR, Raman, UV–Vis) have been analyzed. The structure presented three different dimeric units in the unit cell and the EPR spectra, characteristic of antiferromagnetically coupled dimers, revealed two magnetically different dimeric environments.Fil: Ellena, J.. Universidade de Sao Paulo; BrasilFil: Kremer, E.. Universidad de la República; UruguayFil: Facchin, G.. Universidad de la República; UruguayFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Nascimento, O. R.. Universidade de Sao Paulo; BrasilFil: Costa Filho, A. J.. Universidade de Sao Paulo; BrasilFil: Torre, M. H.. Universidad de la República; UruguayElsevier2007-08-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/155474Ellena, J.; Kremer, E.; Facchin, G.; Baran, Enrique José; Nascimento, O. R.; et al.; X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide; Elsevier; Polyhedron; 26; 13; 06-8-2007; 3277-32850277-5387CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.poly.2007.03.005info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S027753870700143X?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:37:46Zoai:ri.conicet.gov.ar:11336/155474instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:37:47.134CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide
title X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide
spellingShingle X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide
Ellena, J.
Copper complexes
Sulfameter
Crystal structure
EPR
title_short X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide
title_full X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide
title_fullStr X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide
title_full_unstemmed X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide
title_sort X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide
dc.creator.none.fl_str_mv Ellena, J.
Kremer, E.
Facchin, G.
Baran, Enrique José
Nascimento, O. R.
Costa Filho, A. J.
Torre, M. H.
author Ellena, J.
author_facet Ellena, J.
Kremer, E.
Facchin, G.
Baran, Enrique José
Nascimento, O. R.
Costa Filho, A. J.
Torre, M. H.
author_role author
author2 Kremer, E.
Facchin, G.
Baran, Enrique José
Nascimento, O. R.
Costa Filho, A. J.
Torre, M. H.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Copper complexes
Sulfameter
Crystal structure
EPR
topic Copper complexes
Sulfameter
Crystal structure
EPR
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A new complex, [Cu2(sulfameter)4]3 Æ 2.5H2O (sulfameter = 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide), has been synthesized. Its structure has been determined by single-crystal X-ray diffraction and its spectroscopic properties (EPR, IR, Raman, UV–Vis) have been analyzed. The structure presented three different dimeric units in the unit cell and the EPR spectra, characteristic of antiferromagnetically coupled dimers, revealed two magnetically different dimeric environments.
Fil: Ellena, J.. Universidade de Sao Paulo; Brasil
Fil: Kremer, E.. Universidad de la República; Uruguay
Fil: Facchin, G.. Universidad de la República; Uruguay
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Nascimento, O. R.. Universidade de Sao Paulo; Brasil
Fil: Costa Filho, A. J.. Universidade de Sao Paulo; Brasil
Fil: Torre, M. H.. Universidad de la República; Uruguay
description A new complex, [Cu2(sulfameter)4]3 Æ 2.5H2O (sulfameter = 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide), has been synthesized. Its structure has been determined by single-crystal X-ray diffraction and its spectroscopic properties (EPR, IR, Raman, UV–Vis) have been analyzed. The structure presented three different dimeric units in the unit cell and the EPR spectra, characteristic of antiferromagnetically coupled dimers, revealed two magnetically different dimeric environments.
publishDate 2007
dc.date.none.fl_str_mv 2007-08-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/155474
Ellena, J.; Kremer, E.; Facchin, G.; Baran, Enrique José; Nascimento, O. R.; et al.; X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide; Elsevier; Polyhedron; 26; 13; 06-8-2007; 3277-3285
0277-5387
CONICET Digital
CONICET
url http://hdl.handle.net/11336/155474
identifier_str_mv Ellena, J.; Kremer, E.; Facchin, G.; Baran, Enrique José; Nascimento, O. R.; et al.; X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide; Elsevier; Polyhedron; 26; 13; 06-8-2007; 3277-3285
0277-5387
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.poly.2007.03.005
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S027753870700143X?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614398950244352
score 13.069144

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