Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites

Autores
Manthey, Nathan W.; Cardona, Francisco; Francucci, Gaston Martin; Aravinthan, Thiru
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Novel epoxidized hemp oil-based biocomposites containing jute fibre reinforcement were produced at the Centre of Excellence in Engineered Fibre Composites (CEEFC) owing to the need to develop new types of biobased materials. Mechanical properties (tensile, flexural, Charpy impact and interlaminar shear), thermo-mechanical properties (glass transition temperature, storage modulus and crosslink density) and moisture-absorption properties (saturation moisture level and diffusion coefficient) were investigated and compared with samples containing commercially produced epoxidized soybean oil and a synthetic bisphenol A diglycidyl ether-based epoxy control, R246TX cured with a blend of triethylenetetramine and isophorone diamine. Scanning electron microscopy was also performed to investigate the fibre–matrix interface. Epoxidized hemp oil-based samples were found to have marginally superior mechanical, dynamic mechanical and similar water-absorption properties in comparison to samples made with epoxidized soybean oil bioresin; however, both sample types were limited to bioresin concentrations below 30%. Synthetic epoxy-based samples exhibited the highest mechanical, dynamic mechanical and lowest water-absorption properties of all investigated samples. This study has also determined that epoxidized hemp oil-based bioresins when applied to jute fibre-reinforced biocomposites can compete with commercially produced epoxidized soybean oil in biocomposite applications.
Fil: Manthey, Nathan W.. University of Southern Queensland; Australia
Fil: Cardona, Francisco. University of Southern Queensland; Australia
Fil: Francucci, Gaston Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. University of Southern Queensland; Australia
Fil: Aravinthan, Thiru. University of Southern Queensland; Australia
Materia
Biocomposite
Dynamic Mechanical Analysis
Mechanical Properties
Moisture Absorption
Natural Fibres
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2918
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2918
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocompositesManthey, Nathan W.Cardona, FranciscoFrancucci, Gaston MartinAravinthan, ThiruBiocompositeDynamic Mechanical AnalysisMechanical PropertiesMoisture AbsorptionNatural Fibreshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Novel epoxidized hemp oil-based biocomposites containing jute fibre reinforcement were produced at the Centre of Excellence in Engineered Fibre Composites (CEEFC) owing to the need to develop new types of biobased materials. Mechanical properties (tensile, flexural, Charpy impact and interlaminar shear), thermo-mechanical properties (glass transition temperature, storage modulus and crosslink density) and moisture-absorption properties (saturation moisture level and diffusion coefficient) were investigated and compared with samples containing commercially produced epoxidized soybean oil and a synthetic bisphenol A diglycidyl ether-based epoxy control, R246TX cured with a blend of triethylenetetramine and isophorone diamine. Scanning electron microscopy was also performed to investigate the fibre–matrix interface. Epoxidized hemp oil-based samples were found to have marginally superior mechanical, dynamic mechanical and similar water-absorption properties in comparison to samples made with epoxidized soybean oil bioresin; however, both sample types were limited to bioresin concentrations below 30%. Synthetic epoxy-based samples exhibited the highest mechanical, dynamic mechanical and lowest water-absorption properties of all investigated samples. This study has also determined that epoxidized hemp oil-based bioresins when applied to jute fibre-reinforced biocomposites can compete with commercially produced epoxidized soybean oil in biocomposite applications.Fil: Manthey, Nathan W.. University of Southern Queensland; AustraliaFil: Cardona, Francisco. University of Southern Queensland; AustraliaFil: Francucci, Gaston Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. University of Southern Queensland; AustraliaFil: Aravinthan, Thiru. University of Southern Queensland; AustraliaSage Publications Ltd2013-06-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2918Manthey, Nathan W.; Cardona, Francisco; Francucci, Gaston Martin; Aravinthan, Thiru; Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites; Sage Publications Ltd; Journal Of Reinforced Plastics And Composites; 32; 19; 26-6-2013; 1444-14560731-6844enginfo:eu-repo/semantics/altIdentifier/doi/10.1177/0731684413493030info:eu-repo/semantics/altIdentifier/url/http://jrp.sagepub.com/content/32/19/1444info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:03:20Zoai:ri.conicet.gov.ar:11336/2918instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:03:20.481CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites
title Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites
spellingShingle Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites
Manthey, Nathan W.
Biocomposite
Dynamic Mechanical Analysis
Mechanical Properties
Moisture Absorption
Natural Fibres
title_short Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites
title_full Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites
title_fullStr Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites
title_full_unstemmed Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites
title_sort Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites
dc.creator.none.fl_str_mv Manthey, Nathan W.
Cardona, Francisco
Francucci, Gaston Martin
Aravinthan, Thiru
author Manthey, Nathan W.
author_facet Manthey, Nathan W.
Cardona, Francisco
Francucci, Gaston Martin
Aravinthan, Thiru
author_role author
author2 Cardona, Francisco
Francucci, Gaston Martin
Aravinthan, Thiru
author2_role author
author
author
dc.subject.none.fl_str_mv Biocomposite
Dynamic Mechanical Analysis
Mechanical Properties
Moisture Absorption
Natural Fibres
topic Biocomposite
Dynamic Mechanical Analysis
Mechanical Properties
Moisture Absorption
Natural Fibres
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Novel epoxidized hemp oil-based biocomposites containing jute fibre reinforcement were produced at the Centre of Excellence in Engineered Fibre Composites (CEEFC) owing to the need to develop new types of biobased materials. Mechanical properties (tensile, flexural, Charpy impact and interlaminar shear), thermo-mechanical properties (glass transition temperature, storage modulus and crosslink density) and moisture-absorption properties (saturation moisture level and diffusion coefficient) were investigated and compared with samples containing commercially produced epoxidized soybean oil and a synthetic bisphenol A diglycidyl ether-based epoxy control, R246TX cured with a blend of triethylenetetramine and isophorone diamine. Scanning electron microscopy was also performed to investigate the fibre–matrix interface. Epoxidized hemp oil-based samples were found to have marginally superior mechanical, dynamic mechanical and similar water-absorption properties in comparison to samples made with epoxidized soybean oil bioresin; however, both sample types were limited to bioresin concentrations below 30%. Synthetic epoxy-based samples exhibited the highest mechanical, dynamic mechanical and lowest water-absorption properties of all investigated samples. This study has also determined that epoxidized hemp oil-based bioresins when applied to jute fibre-reinforced biocomposites can compete with commercially produced epoxidized soybean oil in biocomposite applications.
Fil: Manthey, Nathan W.. University of Southern Queensland; Australia
Fil: Cardona, Francisco. University of Southern Queensland; Australia
Fil: Francucci, Gaston Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. University of Southern Queensland; Australia
Fil: Aravinthan, Thiru. University of Southern Queensland; Australia
description Novel epoxidized hemp oil-based biocomposites containing jute fibre reinforcement were produced at the Centre of Excellence in Engineered Fibre Composites (CEEFC) owing to the need to develop new types of biobased materials. Mechanical properties (tensile, flexural, Charpy impact and interlaminar shear), thermo-mechanical properties (glass transition temperature, storage modulus and crosslink density) and moisture-absorption properties (saturation moisture level and diffusion coefficient) were investigated and compared with samples containing commercially produced epoxidized soybean oil and a synthetic bisphenol A diglycidyl ether-based epoxy control, R246TX cured with a blend of triethylenetetramine and isophorone diamine. Scanning electron microscopy was also performed to investigate the fibre–matrix interface. Epoxidized hemp oil-based samples were found to have marginally superior mechanical, dynamic mechanical and similar water-absorption properties in comparison to samples made with epoxidized soybean oil bioresin; however, both sample types were limited to bioresin concentrations below 30%. Synthetic epoxy-based samples exhibited the highest mechanical, dynamic mechanical and lowest water-absorption properties of all investigated samples. This study has also determined that epoxidized hemp oil-based bioresins when applied to jute fibre-reinforced biocomposites can compete with commercially produced epoxidized soybean oil in biocomposite applications.
publishDate 2013
dc.date.none.fl_str_mv 2013-06-26
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2918
Manthey, Nathan W.; Cardona, Francisco; Francucci, Gaston Martin; Aravinthan, Thiru; Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites; Sage Publications Ltd; Journal Of Reinforced Plastics And Composites; 32; 19; 26-6-2013; 1444-1456
0731-6844
url http://hdl.handle.net/11336/2918
identifier_str_mv Manthey, Nathan W.; Cardona, Francisco; Francucci, Gaston Martin; Aravinthan, Thiru; Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites; Sage Publications Ltd; Journal Of Reinforced Plastics And Composites; 32; 19; 26-6-2013; 1444-1456
0731-6844
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1177/0731684413493030
info:eu-repo/semantics/altIdentifier/url/http://jrp.sagepub.com/content/32/19/1444
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Sage Publications Ltd
publisher.none.fl_str_mv Sage Publications Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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