Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells

Autores
Guerrero León, L. Andrés; Bautista Quijano, José Roberto; Heffner, Herman; Shilovskikh, Vladimir; Campos, Raquel; Rivkin, Boris; Vaynzof, Yana
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Despite the remarkable advances in the field of perovskite photovoltaics, the use of toxic solvents for their fabrication poses a significant challenge to their scale-up and commercialization. The vast majority of studies rely on using the highly hazardous N, N-Dimethylformamide (DMF), with green alternatives remaining scarce. In this work, the use of glycerol formal (Gly-F) is reported as a green solvent for fabricating quasi-2D (n = 5) perovskite solar cells. Quasi-2D perovskite films processed from Gly-F exhibit a high degree of uniformity and a compact microstructure. When integrated into solar cells, the green solvent-processed films reach a promising power conversion efficiency of 14.53%. This performance is lower than that of DMF-based perovskites, most likely due to the presence of laterally oriented low n perovskite phases. Interestingly, while the performance of DMF-based devices is rather irreproducible, the performance of Gly-F-based devices is robust and consistent. These results demonstrate the potential of Gly-F- as a promising green alternative to DMF.
Fil: Guerrero León, L. Andrés. Technische Universität Dresden.; Alemania
Fil: Bautista Quijano, José Roberto. Technische Universität Dresden.; Alemania
Fil: Heffner, Herman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Technische Universität Dresden.; Alemania
Fil: Shilovskikh, Vladimir. Technische Universität Dresden.; Alemania
Fil: Campos, Raquel. Technische Universität Dresden.; Alemania
Fil: Rivkin, Boris. Technische Universität Dresden.; Alemania
Fil: Vaynzof, Yana. Technische Universität Dresden.; Alemania
Materia
PEROVSKITE
GLYCEROL
FORMAL
SOLAR
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/256427
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar CellsGuerrero León, L. AndrésBautista Quijano, José RobertoHeffner, HermanShilovskikh, VladimirCampos, RaquelRivkin, BorisVaynzof, YanaPEROVSKITEGLYCEROLFORMALSOLARhttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Despite the remarkable advances in the field of perovskite photovoltaics, the use of toxic solvents for their fabrication poses a significant challenge to their scale-up and commercialization. The vast majority of studies rely on using the highly hazardous N, N-Dimethylformamide (DMF), with green alternatives remaining scarce. In this work, the use of glycerol formal (Gly-F) is reported as a green solvent for fabricating quasi-2D (n = 5) perovskite solar cells. Quasi-2D perovskite films processed from Gly-F exhibit a high degree of uniformity and a compact microstructure. When integrated into solar cells, the green solvent-processed films reach a promising power conversion efficiency of 14.53%. This performance is lower than that of DMF-based perovskites, most likely due to the presence of laterally oriented low n perovskite phases. Interestingly, while the performance of DMF-based devices is rather irreproducible, the performance of Gly-F-based devices is robust and consistent. These results demonstrate the potential of Gly-F- as a promising green alternative to DMF.Fil: Guerrero León, L. Andrés. Technische Universität Dresden.; AlemaniaFil: Bautista Quijano, José Roberto. Technische Universität Dresden.; AlemaniaFil: Heffner, Herman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Technische Universität Dresden.; AlemaniaFil: Shilovskikh, Vladimir. Technische Universität Dresden.; AlemaniaFil: Campos, Raquel. Technische Universität Dresden.; AlemaniaFil: Rivkin, Boris. Technische Universität Dresden.; AlemaniaFil: Vaynzof, Yana. Technische Universität Dresden.; AlemaniaWiley2024-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/256427Guerrero León, L. Andrés; Bautista Quijano, José Roberto; Heffner, Herman; Shilovskikh, Vladimir; Campos, Raquel; et al.; Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells; Wiley; Advanced Energy Materials; 14; 45; 10-2024; 1-81614-68321614-6840CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/aenm.202402916info:eu-repo/semantics/altIdentifier/doi/10.1002/aenm.202402916info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:52:20Zoai:ri.conicet.gov.ar:11336/256427instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:52:20.922CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells
title Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells
spellingShingle Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells
Guerrero León, L. Andrés
PEROVSKITE
GLYCEROL
FORMAL
SOLAR
title_short Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells
title_full Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells
title_fullStr Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells
title_full_unstemmed Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells
title_sort Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells
dc.creator.none.fl_str_mv Guerrero León, L. Andrés
Bautista Quijano, José Roberto
Heffner, Herman
Shilovskikh, Vladimir
Campos, Raquel
Rivkin, Boris
Vaynzof, Yana
author Guerrero León, L. Andrés
author_facet Guerrero León, L. Andrés
Bautista Quijano, José Roberto
Heffner, Herman
Shilovskikh, Vladimir
Campos, Raquel
Rivkin, Boris
Vaynzof, Yana
author_role author
author2 Bautista Quijano, José Roberto
Heffner, Herman
Shilovskikh, Vladimir
Campos, Raquel
Rivkin, Boris
Vaynzof, Yana
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv PEROVSKITE
GLYCEROL
FORMAL
SOLAR
topic PEROVSKITE
GLYCEROL
FORMAL
SOLAR
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Despite the remarkable advances in the field of perovskite photovoltaics, the use of toxic solvents for their fabrication poses a significant challenge to their scale-up and commercialization. The vast majority of studies rely on using the highly hazardous N, N-Dimethylformamide (DMF), with green alternatives remaining scarce. In this work, the use of glycerol formal (Gly-F) is reported as a green solvent for fabricating quasi-2D (n = 5) perovskite solar cells. Quasi-2D perovskite films processed from Gly-F exhibit a high degree of uniformity and a compact microstructure. When integrated into solar cells, the green solvent-processed films reach a promising power conversion efficiency of 14.53%. This performance is lower than that of DMF-based perovskites, most likely due to the presence of laterally oriented low n perovskite phases. Interestingly, while the performance of DMF-based devices is rather irreproducible, the performance of Gly-F-based devices is robust and consistent. These results demonstrate the potential of Gly-F- as a promising green alternative to DMF.
Fil: Guerrero León, L. Andrés. Technische Universität Dresden.; Alemania
Fil: Bautista Quijano, José Roberto. Technische Universität Dresden.; Alemania
Fil: Heffner, Herman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Technische Universität Dresden.; Alemania
Fil: Shilovskikh, Vladimir. Technische Universität Dresden.; Alemania
Fil: Campos, Raquel. Technische Universität Dresden.; Alemania
Fil: Rivkin, Boris. Technische Universität Dresden.; Alemania
Fil: Vaynzof, Yana. Technische Universität Dresden.; Alemania
description Despite the remarkable advances in the field of perovskite photovoltaics, the use of toxic solvents for their fabrication poses a significant challenge to their scale-up and commercialization. The vast majority of studies rely on using the highly hazardous N, N-Dimethylformamide (DMF), with green alternatives remaining scarce. In this work, the use of glycerol formal (Gly-F) is reported as a green solvent for fabricating quasi-2D (n = 5) perovskite solar cells. Quasi-2D perovskite films processed from Gly-F exhibit a high degree of uniformity and a compact microstructure. When integrated into solar cells, the green solvent-processed films reach a promising power conversion efficiency of 14.53%. This performance is lower than that of DMF-based perovskites, most likely due to the presence of laterally oriented low n perovskite phases. Interestingly, while the performance of DMF-based devices is rather irreproducible, the performance of Gly-F-based devices is robust and consistent. These results demonstrate the potential of Gly-F- as a promising green alternative to DMF.
publishDate 2024
dc.date.none.fl_str_mv 2024-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/256427
Guerrero León, L. Andrés; Bautista Quijano, José Roberto; Heffner, Herman; Shilovskikh, Vladimir; Campos, Raquel; et al.; Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells; Wiley; Advanced Energy Materials; 14; 45; 10-2024; 1-8
1614-6832
1614-6840
CONICET Digital
CONICET
url http://hdl.handle.net/11336/256427
identifier_str_mv Guerrero León, L. Andrés; Bautista Quijano, José Roberto; Heffner, Herman; Shilovskikh, Vladimir; Campos, Raquel; et al.; Novel Green Solvent for Sustainable Fabrication of Quasi‐2D Perovskite Solar Cells; Wiley; Advanced Energy Materials; 14; 45; 10-2024; 1-8
1614-6832
1614-6840
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/aenm.202402916
info:eu-repo/semantics/altIdentifier/doi/10.1002/aenm.202402916
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613605635391488
score 13.070432

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