Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal

Autores
Rodriguez Ramirez, Carlos Alejandro; Tasque, Joana Elisa; Garcia, Nancy Lis; D'accorso, Norma Beatriz
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Novel materials using biowaste as adsorbents in wastewater treatment have been allocated considerable interest. Herein, we present the synthesis of different hydrogels of crosslinked polyacrylamide in presence of hemicelluloses with/ without bentonite, using a soft reaction condition. The structure of new hydrogels was characterized by spectroscopic, thermal and microscopic experiments. The semi-interpenetrated network with hemicelluloses: 10 %; acrylamide 79 %; bentonite 10 %; N,N,N′,N′-tetramethylethylenediamine: 1 % allows reducing 20 % the use of non-renewable acrylamide, without changing its decomposition temperatures and keeping its water absorption capacity. This hydrogel was applied to dye removals, such as rhodamine B, methylene red and methylene blue in aqueous solutions. In the case of methylene blue, highest removal is observed with maximum adsorption of qmax = 140.66 mg/g, compared to material without hemicelluloses that only a qmax = 88.495 mg/g. The adsorption kinetics and equilibrium adsorption isotherms are in accordance with the pseudo-second-order kinetic model and Langmuir isotherm model, respectively. The developed hydrogel from hemicelluloses represents a potential alternative adsorbent for a sustainable system of sewage treatment.
Fil: Rodriguez Ramirez, Carlos Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Fil: Tasque, Joana Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina. YPF - Tecnología; Argentina
Fil: Garcia, Nancy Lis. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Fil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Materia
ADSORPTION
DYES
HEMICELLULOSES
HYDROGEL
POLYSACCHARIDE
WASTEWATER
Nivel de accesibilidad
acceso embargado
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/224783
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/224783
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removalRodriguez Ramirez, Carlos AlejandroTasque, Joana ElisaGarcia, Nancy LisD'accorso, Norma BeatrizADSORPTIONDYESHEMICELLULOSESHYDROGELPOLYSACCHARIDEWASTEWATERhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Novel materials using biowaste as adsorbents in wastewater treatment have been allocated considerable interest. Herein, we present the synthesis of different hydrogels of crosslinked polyacrylamide in presence of hemicelluloses with/ without bentonite, using a soft reaction condition. The structure of new hydrogels was characterized by spectroscopic, thermal and microscopic experiments. The semi-interpenetrated network with hemicelluloses: 10 %; acrylamide 79 %; bentonite 10 %; N,N,N′,N′-tetramethylethylenediamine: 1 % allows reducing 20 % the use of non-renewable acrylamide, without changing its decomposition temperatures and keeping its water absorption capacity. This hydrogel was applied to dye removals, such as rhodamine B, methylene red and methylene blue in aqueous solutions. In the case of methylene blue, highest removal is observed with maximum adsorption of qmax = 140.66 mg/g, compared to material without hemicelluloses that only a qmax = 88.495 mg/g. The adsorption kinetics and equilibrium adsorption isotherms are in accordance with the pseudo-second-order kinetic model and Langmuir isotherm model, respectively. The developed hydrogel from hemicelluloses represents a potential alternative adsorbent for a sustainable system of sewage treatment.Fil: Rodriguez Ramirez, Carlos Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; ArgentinaFil: Tasque, Joana Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina. YPF - Tecnología; ArgentinaFil: Garcia, Nancy Lis. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; ArgentinaFil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; ArgentinaElsevier Science2023-12info:eu-repo/date/embargoEnd/2024-06-25info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/224783Rodriguez Ramirez, Carlos Alejandro; Tasque, Joana Elisa; Garcia, Nancy Lis; D'accorso, Norma Beatriz; Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal; Elsevier Science; International Journal of Biological Macromolecules; 253; 12-2023; 1-360141-8130CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0141813023039077info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijbiomac.2023.127010info:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:17:20Zoai:ri.conicet.gov.ar:11336/224783instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:17:21.212CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal
title Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal
spellingShingle Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal
Rodriguez Ramirez, Carlos Alejandro
ADSORPTION
DYES
HEMICELLULOSES
HYDROGEL
POLYSACCHARIDE
WASTEWATER
title_short Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal
title_full Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal
title_fullStr Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal
title_full_unstemmed Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal
title_sort Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal
dc.creator.none.fl_str_mv Rodriguez Ramirez, Carlos Alejandro
Tasque, Joana Elisa
Garcia, Nancy Lis
D'accorso, Norma Beatriz
author Rodriguez Ramirez, Carlos Alejandro
author_facet Rodriguez Ramirez, Carlos Alejandro
Tasque, Joana Elisa
Garcia, Nancy Lis
D'accorso, Norma Beatriz
author_role author
author2 Tasque, Joana Elisa
Garcia, Nancy Lis
D'accorso, Norma Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv ADSORPTION
DYES
HEMICELLULOSES
HYDROGEL
POLYSACCHARIDE
WASTEWATER
topic ADSORPTION
DYES
HEMICELLULOSES
HYDROGEL
POLYSACCHARIDE
WASTEWATER
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Novel materials using biowaste as adsorbents in wastewater treatment have been allocated considerable interest. Herein, we present the synthesis of different hydrogels of crosslinked polyacrylamide in presence of hemicelluloses with/ without bentonite, using a soft reaction condition. The structure of new hydrogels was characterized by spectroscopic, thermal and microscopic experiments. The semi-interpenetrated network with hemicelluloses: 10 %; acrylamide 79 %; bentonite 10 %; N,N,N′,N′-tetramethylethylenediamine: 1 % allows reducing 20 % the use of non-renewable acrylamide, without changing its decomposition temperatures and keeping its water absorption capacity. This hydrogel was applied to dye removals, such as rhodamine B, methylene red and methylene blue in aqueous solutions. In the case of methylene blue, highest removal is observed with maximum adsorption of qmax = 140.66 mg/g, compared to material without hemicelluloses that only a qmax = 88.495 mg/g. The adsorption kinetics and equilibrium adsorption isotherms are in accordance with the pseudo-second-order kinetic model and Langmuir isotherm model, respectively. The developed hydrogel from hemicelluloses represents a potential alternative adsorbent for a sustainable system of sewage treatment.
Fil: Rodriguez Ramirez, Carlos Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Fil: Tasque, Joana Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina. YPF - Tecnología; Argentina
Fil: Garcia, Nancy Lis. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Fil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
description Novel materials using biowaste as adsorbents in wastewater treatment have been allocated considerable interest. Herein, we present the synthesis of different hydrogels of crosslinked polyacrylamide in presence of hemicelluloses with/ without bentonite, using a soft reaction condition. The structure of new hydrogels was characterized by spectroscopic, thermal and microscopic experiments. The semi-interpenetrated network with hemicelluloses: 10 %; acrylamide 79 %; bentonite 10 %; N,N,N′,N′-tetramethylethylenediamine: 1 % allows reducing 20 % the use of non-renewable acrylamide, without changing its decomposition temperatures and keeping its water absorption capacity. This hydrogel was applied to dye removals, such as rhodamine B, methylene red and methylene blue in aqueous solutions. In the case of methylene blue, highest removal is observed with maximum adsorption of qmax = 140.66 mg/g, compared to material without hemicelluloses that only a qmax = 88.495 mg/g. The adsorption kinetics and equilibrium adsorption isotherms are in accordance with the pseudo-second-order kinetic model and Langmuir isotherm model, respectively. The developed hydrogel from hemicelluloses represents a potential alternative adsorbent for a sustainable system of sewage treatment.
publishDate 2023
dc.date.none.fl_str_mv 2023-12
info:eu-repo/date/embargoEnd/2024-06-25
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/224783
Rodriguez Ramirez, Carlos Alejandro; Tasque, Joana Elisa; Garcia, Nancy Lis; D'accorso, Norma Beatriz; Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal; Elsevier Science; International Journal of Biological Macromolecules; 253; 12-2023; 1-36
0141-8130
CONICET Digital
CONICET
url http://hdl.handle.net/11336/224783
identifier_str_mv Rodriguez Ramirez, Carlos Alejandro; Tasque, Joana Elisa; Garcia, Nancy Lis; D'accorso, Norma Beatriz; Hemicelluloses hydrogel: Synthesis, characterization, and application in dye removal; Elsevier Science; International Journal of Biological Macromolecules; 253; 12-2023; 1-36
0141-8130
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0141813023039077
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijbiomac.2023.127010
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv embargoedAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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