Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air
- Autores
- Gaona Colmán, Elizabeth; Blanco, Maria Belen; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Rate coefficients for the gas-phase reactions of Cl atoms with β-ocimene and camphene were determined to be (in units of 10-10 cm3 per molecule per s) 5.5 ± 0.7 and 3.3 ± 0.4, respectively. The experiments were performed by the relative technique in an environmental chamber with FTIR detection of the reactants at 298 K and 760 torr. Product identification experiments were carried out by gas chromatography with mass spectrometry detection (GC-MS) using the solid-phase microextraction (SPME) method employing on-fiber carbonyl compound derivatization with o-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine hydrochloride. An analysis of the available rates of addition of Cl atoms and OH radicals to the double bond of alkenes and cyclic and acyclic terpenes with a conjugated double bond at 298 K is presented. The atmospheric persistence of these compounds was calculated taking into account the measured rate coefficients. In addition, tropospheric chemical mechanisms for the title reactions are postulated.
Fil: Gaona Colmán, Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Barnes, Ian. Bergische Universitat Wuppertal; Alemania
Fil: Wiesen, Peter. Bergische Universitat Wuppertal; Alemania
Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
-
BVOCS
FTIR SMOG CHAMBER
MECHANISMS
KINETICS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/90464
Ver los metadatos del registro completo
id |
CONICETDig_931526d097a4c3ddf27ce1e19139644b |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/90464 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-AirGaona Colmán, ElizabethBlanco, Maria BelenBarnes, IanWiesen, PeterTeruel, Mariano AndresBVOCSFTIR SMOG CHAMBERMECHANISMSKINETICShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Rate coefficients for the gas-phase reactions of Cl atoms with β-ocimene and camphene were determined to be (in units of 10-10 cm3 per molecule per s) 5.5 ± 0.7 and 3.3 ± 0.4, respectively. The experiments were performed by the relative technique in an environmental chamber with FTIR detection of the reactants at 298 K and 760 torr. Product identification experiments were carried out by gas chromatography with mass spectrometry detection (GC-MS) using the solid-phase microextraction (SPME) method employing on-fiber carbonyl compound derivatization with o-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine hydrochloride. An analysis of the available rates of addition of Cl atoms and OH radicals to the double bond of alkenes and cyclic and acyclic terpenes with a conjugated double bond at 298 K is presented. The atmospheric persistence of these compounds was calculated taking into account the measured rate coefficients. In addition, tropospheric chemical mechanisms for the title reactions are postulated.Fil: Gaona Colmán, Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Barnes, Ian. Bergische Universitat Wuppertal; AlemaniaFil: Wiesen, Peter. Bergische Universitat Wuppertal; AlemaniaFil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaRoyal Society of Chemistry2018-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/90464Gaona Colmán, Elizabeth; Blanco, Maria Belen; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres; Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air; Royal Society of Chemistry; RSC Advances; 8; 48; 7-2018; 27054-270632046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c8ra04931ainfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/RA/C8RA04931A#!divAbstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:14Zoai:ri.conicet.gov.ar:11336/90464instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:14.745CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air |
title |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air |
spellingShingle |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air Gaona Colmán, Elizabeth BVOCS FTIR SMOG CHAMBER MECHANISMS KINETICS |
title_short |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air |
title_full |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air |
title_fullStr |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air |
title_full_unstemmed |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air |
title_sort |
Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air |
dc.creator.none.fl_str_mv |
Gaona Colmán, Elizabeth Blanco, Maria Belen Barnes, Ian Wiesen, Peter Teruel, Mariano Andres |
author |
Gaona Colmán, Elizabeth |
author_facet |
Gaona Colmán, Elizabeth Blanco, Maria Belen Barnes, Ian Wiesen, Peter Teruel, Mariano Andres |
author_role |
author |
author2 |
Blanco, Maria Belen Barnes, Ian Wiesen, Peter Teruel, Mariano Andres |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
BVOCS FTIR SMOG CHAMBER MECHANISMS KINETICS |
topic |
BVOCS FTIR SMOG CHAMBER MECHANISMS KINETICS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Rate coefficients for the gas-phase reactions of Cl atoms with β-ocimene and camphene were determined to be (in units of 10-10 cm3 per molecule per s) 5.5 ± 0.7 and 3.3 ± 0.4, respectively. The experiments were performed by the relative technique in an environmental chamber with FTIR detection of the reactants at 298 K and 760 torr. Product identification experiments were carried out by gas chromatography with mass spectrometry detection (GC-MS) using the solid-phase microextraction (SPME) method employing on-fiber carbonyl compound derivatization with o-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine hydrochloride. An analysis of the available rates of addition of Cl atoms and OH radicals to the double bond of alkenes and cyclic and acyclic terpenes with a conjugated double bond at 298 K is presented. The atmospheric persistence of these compounds was calculated taking into account the measured rate coefficients. In addition, tropospheric chemical mechanisms for the title reactions are postulated. Fil: Gaona Colmán, Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Barnes, Ian. Bergische Universitat Wuppertal; Alemania Fil: Wiesen, Peter. Bergische Universitat Wuppertal; Alemania Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
description |
Rate coefficients for the gas-phase reactions of Cl atoms with β-ocimene and camphene were determined to be (in units of 10-10 cm3 per molecule per s) 5.5 ± 0.7 and 3.3 ± 0.4, respectively. The experiments were performed by the relative technique in an environmental chamber with FTIR detection of the reactants at 298 K and 760 torr. Product identification experiments were carried out by gas chromatography with mass spectrometry detection (GC-MS) using the solid-phase microextraction (SPME) method employing on-fiber carbonyl compound derivatization with o-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine hydrochloride. An analysis of the available rates of addition of Cl atoms and OH radicals to the double bond of alkenes and cyclic and acyclic terpenes with a conjugated double bond at 298 K is presented. The atmospheric persistence of these compounds was calculated taking into account the measured rate coefficients. In addition, tropospheric chemical mechanisms for the title reactions are postulated. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-07 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/90464 Gaona Colmán, Elizabeth; Blanco, Maria Belen; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres; Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air; Royal Society of Chemistry; RSC Advances; 8; 48; 7-2018; 27054-27063 2046-2069 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/90464 |
identifier_str_mv |
Gaona Colmán, Elizabeth; Blanco, Maria Belen; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres; Atmospheric sink of β-ocimene and camphene initiated by Cl atoms: Kinetics and products at NOx free-Air; Royal Society of Chemistry; RSC Advances; 8; 48; 7-2018; 27054-27063 2046-2069 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1039/c8ra04931a info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2018/RA/C8RA04931A#!divAbstract |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842270073572556800 |
score |
13.13397 |