Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst

Autores
Bressa, Sergio Patricio; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando
Año de publicación
2003
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A kinetic investigation of the vapor-phase hydrogenation and hydroisomerization of 1-butene and cis- and trans-2-butene is presented. This investigation is aimed at validating a practical set of rate equations. The experiments were performed at approximately atmospheric pressure using a commercial Pd/Al2O3 catalyst of the eggshell type in an integral fixed-bed isothermal reactor. The outlet composition was measured under 120 sets of operating conditions at six levels of temperature between −8 and 30 °C. The mole fractions of 1-butene and hydrogen in the feed were varied between 0.5 and 3% and between 0.5 and 50%, respectively. Space-time covered the range of (5−55) × 10-3 s. Internal diffusion limitations affected the effective reaction rates and product distribution. Hence, the mass conservation equations inside the catalyst had to be solved to estimate the intrinsic values of the kinetic parameters. Two rival kinetic models of the Langmuir−Hinshelwood−Hougen−Watson type were proposed, one of which could be confidently discriminated as the better of the two models considered. An essential feature of the chosen model is that hydrogen concentration exhibits distinct effects on the hydrogenation and hydroisomerization reactions of n-butenes. The selected model predicts the experimental results with an average deviation of 8.8%. The estimates of the kinetic parameters show inference intervals in the range of ±10−30%.
Fil: Bressa, Sergio Patricio. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Martinez, Osvaldo Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; Argentina
Fil: Barreto, Guillermo Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Materia
Kinetics
Hydrogenation Hydroisomerization
N-Butenes
Palladium/Alumina Catalyst
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/62991
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/62991
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalystBressa, Sergio PatricioMartinez, Osvaldo MiguelBarreto, Guillermo FernandoKineticsHydrogenation HydroisomerizationN-ButenesPalladium/Alumina Catalysthttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A kinetic investigation of the vapor-phase hydrogenation and hydroisomerization of 1-butene and cis- and trans-2-butene is presented. This investigation is aimed at validating a practical set of rate equations. The experiments were performed at approximately atmospheric pressure using a commercial Pd/Al2O3 catalyst of the eggshell type in an integral fixed-bed isothermal reactor. The outlet composition was measured under 120 sets of operating conditions at six levels of temperature between −8 and 30 °C. The mole fractions of 1-butene and hydrogen in the feed were varied between 0.5 and 3% and between 0.5 and 50%, respectively. Space-time covered the range of (5−55) × 10-3 s. Internal diffusion limitations affected the effective reaction rates and product distribution. Hence, the mass conservation equations inside the catalyst had to be solved to estimate the intrinsic values of the kinetic parameters. Two rival kinetic models of the Langmuir−Hinshelwood−Hougen−Watson type were proposed, one of which could be confidently discriminated as the better of the two models considered. An essential feature of the chosen model is that hydrogen concentration exhibits distinct effects on the hydrogenation and hydroisomerization reactions of n-butenes. The selected model predicts the experimental results with an average deviation of 8.8%. The estimates of the kinetic parameters show inference intervals in the range of ±10−30%.Fil: Bressa, Sergio Patricio. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Martinez, Osvaldo Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; ArgentinaFil: Barreto, Guillermo Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaAmerican Chemical Society2003-04-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62991Bressa, Sergio Patricio; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst; American Chemical Society; Industrial & Engineering Chemical Research; 42; 10; 9-4-2003; 2081-20920888-58851520-5045CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/toc/iecred/42/10info:eu-repo/semantics/altIdentifier/doi/10.1021/ie0209879info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:10:04Zoai:ri.conicet.gov.ar:11336/62991instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:10:05.178CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst
title Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst
spellingShingle Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst
Bressa, Sergio Patricio
Kinetics
Hydrogenation Hydroisomerization
N-Butenes
Palladium/Alumina Catalyst
title_short Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst
title_full Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst
title_fullStr Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst
title_full_unstemmed Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst
title_sort Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst
dc.creator.none.fl_str_mv Bressa, Sergio Patricio
Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author Bressa, Sergio Patricio
author_facet Bressa, Sergio Patricio
Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author_role author
author2 Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author2_role author
author
dc.subject.none.fl_str_mv Kinetics
Hydrogenation Hydroisomerization
N-Butenes
Palladium/Alumina Catalyst
topic Kinetics
Hydrogenation Hydroisomerization
N-Butenes
Palladium/Alumina Catalyst
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A kinetic investigation of the vapor-phase hydrogenation and hydroisomerization of 1-butene and cis- and trans-2-butene is presented. This investigation is aimed at validating a practical set of rate equations. The experiments were performed at approximately atmospheric pressure using a commercial Pd/Al2O3 catalyst of the eggshell type in an integral fixed-bed isothermal reactor. The outlet composition was measured under 120 sets of operating conditions at six levels of temperature between −8 and 30 °C. The mole fractions of 1-butene and hydrogen in the feed were varied between 0.5 and 3% and between 0.5 and 50%, respectively. Space-time covered the range of (5−55) × 10-3 s. Internal diffusion limitations affected the effective reaction rates and product distribution. Hence, the mass conservation equations inside the catalyst had to be solved to estimate the intrinsic values of the kinetic parameters. Two rival kinetic models of the Langmuir−Hinshelwood−Hougen−Watson type were proposed, one of which could be confidently discriminated as the better of the two models considered. An essential feature of the chosen model is that hydrogen concentration exhibits distinct effects on the hydrogenation and hydroisomerization reactions of n-butenes. The selected model predicts the experimental results with an average deviation of 8.8%. The estimates of the kinetic parameters show inference intervals in the range of ±10−30%.
Fil: Bressa, Sergio Patricio. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Martinez, Osvaldo Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina. Universidad Nacional de La Plata. Facultad de Ingenierí­a. Departamento de Ingeniería Química; Argentina
Fil: Barreto, Guillermo Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
description A kinetic investigation of the vapor-phase hydrogenation and hydroisomerization of 1-butene and cis- and trans-2-butene is presented. This investigation is aimed at validating a practical set of rate equations. The experiments were performed at approximately atmospheric pressure using a commercial Pd/Al2O3 catalyst of the eggshell type in an integral fixed-bed isothermal reactor. The outlet composition was measured under 120 sets of operating conditions at six levels of temperature between −8 and 30 °C. The mole fractions of 1-butene and hydrogen in the feed were varied between 0.5 and 3% and between 0.5 and 50%, respectively. Space-time covered the range of (5−55) × 10-3 s. Internal diffusion limitations affected the effective reaction rates and product distribution. Hence, the mass conservation equations inside the catalyst had to be solved to estimate the intrinsic values of the kinetic parameters. Two rival kinetic models of the Langmuir−Hinshelwood−Hougen−Watson type were proposed, one of which could be confidently discriminated as the better of the two models considered. An essential feature of the chosen model is that hydrogen concentration exhibits distinct effects on the hydrogenation and hydroisomerization reactions of n-butenes. The selected model predicts the experimental results with an average deviation of 8.8%. The estimates of the kinetic parameters show inference intervals in the range of ±10−30%.
publishDate 2003
dc.date.none.fl_str_mv 2003-04-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/62991
Bressa, Sergio Patricio; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst; American Chemical Society; Industrial & Engineering Chemical Research; 42; 10; 9-4-2003; 2081-2092
0888-5885
1520-5045
CONICET Digital
CONICET
url http://hdl.handle.net/11336/62991
identifier_str_mv Bressa, Sergio Patricio; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst; American Chemical Society; Industrial & Engineering Chemical Research; 42; 10; 9-4-2003; 2081-2092
0888-5885
1520-5045
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/toc/iecred/42/10
info:eu-repo/semantics/altIdentifier/doi/10.1021/ie0209879
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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