Testing phosphate ions as corrosion inhibitors for construction steel in mortars

Autores
Yohai del Cerro, Lucía; Valcarce, María Beatriz; Vazquez, Marcela Vivian
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The purpose of this investigation is to analyze the effectiveness of phosphates as inhibiting agents for steel bars embedded in mortars. Three mix designs were selected for this study: mix A had no admixed chlorides and was used as reference; mix designs B and C were contaminated with 1% in weight of chlorides/weight of cement and mix C also incorporated 7% Na3PO4.12 H2O. After setting for 48 h, the samples were cured for 7 days immersed in water. Three specimens of each group were then immersed in aerated saline solutions 0.5 mol L−1 NaCl during 720 days. The corrosion potential (Ecorr), the polarization resistance (Rp) and the electrochemical impedance spectra were recorded regularly. After 720 days of immersion one set of mortars was anodically polarized and another set cathodically polarized. After that, Raman spectra of corrosion products were registered. Additional specimens were used to evaluate porosity and chloride profiles. The presence of phosphate ions as inhibitors has no effect on Ecorr values and suggests mixed-type inhibition. Mix C remains passive until 180 days of exposure, with Rt> 100 kΩ cm2. At longer times, Rt decreases in time but the inhibition percentage is always higher than 95% when evaluated by impedance spectra. Using Rp, inhibition stays above 70%. Anodic and cathodic polarization curves, together with corrosion potential values, suggest that phosphates behave as a mixed-type inhibitor.
Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Phosphate Ions
Construction Steel
Mortar
Corrosion
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34403
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/34403
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Testing phosphate ions as corrosion inhibitors for construction steel in mortarsYohai del Cerro, LucíaValcarce, María BeatrizVazquez, Marcela VivianPhosphate IonsConstruction SteelMortarCorrosionhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The purpose of this investigation is to analyze the effectiveness of phosphates as inhibiting agents for steel bars embedded in mortars. Three mix designs were selected for this study: mix A had no admixed chlorides and was used as reference; mix designs B and C were contaminated with 1% in weight of chlorides/weight of cement and mix C also incorporated 7% Na3PO4.12 H2O. After setting for 48 h, the samples were cured for 7 days immersed in water. Three specimens of each group were then immersed in aerated saline solutions 0.5 mol L−1 NaCl during 720 days. The corrosion potential (Ecorr), the polarization resistance (Rp) and the electrochemical impedance spectra were recorded regularly. After 720 days of immersion one set of mortars was anodically polarized and another set cathodically polarized. After that, Raman spectra of corrosion products were registered. Additional specimens were used to evaluate porosity and chloride profiles. The presence of phosphate ions as inhibitors has no effect on Ecorr values and suggests mixed-type inhibition. Mix C remains passive until 180 days of exposure, with Rt> 100 kΩ cm2. At longer times, Rt decreases in time but the inhibition percentage is always higher than 95% when evaluated by impedance spectra. Using Rp, inhibition stays above 70%. Anodic and cathodic polarization curves, together with corrosion potential values, suggest that phosphates behave as a mixed-type inhibitor.Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaPergamon-Elsevier Science Ltd.2015-12-22info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34403Yohai del Cerro, Lucía; Valcarce, María Beatriz; Vazquez, Marcela Vivian; Testing phosphate ions as corrosion inhibitors for construction steel in mortars; Pergamon-Elsevier Science Ltd.; Electrochimica Acta; 202; 22-12-2015; 316-3240013-4686CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0013468615310483info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2015.12.124info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:06:59Zoai:ri.conicet.gov.ar:11336/34403instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:06:59.686CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Testing phosphate ions as corrosion inhibitors for construction steel in mortars
title Testing phosphate ions as corrosion inhibitors for construction steel in mortars
spellingShingle Testing phosphate ions as corrosion inhibitors for construction steel in mortars
Yohai del Cerro, Lucía
Phosphate Ions
Construction Steel
Mortar
Corrosion
title_short Testing phosphate ions as corrosion inhibitors for construction steel in mortars
title_full Testing phosphate ions as corrosion inhibitors for construction steel in mortars
title_fullStr Testing phosphate ions as corrosion inhibitors for construction steel in mortars
title_full_unstemmed Testing phosphate ions as corrosion inhibitors for construction steel in mortars
title_sort Testing phosphate ions as corrosion inhibitors for construction steel in mortars
dc.creator.none.fl_str_mv Yohai del Cerro, Lucía
Valcarce, María Beatriz
Vazquez, Marcela Vivian
author Yohai del Cerro, Lucía
author_facet Yohai del Cerro, Lucía
Valcarce, María Beatriz
Vazquez, Marcela Vivian
author_role author
author2 Valcarce, María Beatriz
Vazquez, Marcela Vivian
author2_role author
author
dc.subject.none.fl_str_mv Phosphate Ions
Construction Steel
Mortar
Corrosion
topic Phosphate Ions
Construction Steel
Mortar
Corrosion
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The purpose of this investigation is to analyze the effectiveness of phosphates as inhibiting agents for steel bars embedded in mortars. Three mix designs were selected for this study: mix A had no admixed chlorides and was used as reference; mix designs B and C were contaminated with 1% in weight of chlorides/weight of cement and mix C also incorporated 7% Na3PO4.12 H2O. After setting for 48 h, the samples were cured for 7 days immersed in water. Three specimens of each group were then immersed in aerated saline solutions 0.5 mol L−1 NaCl during 720 days. The corrosion potential (Ecorr), the polarization resistance (Rp) and the electrochemical impedance spectra were recorded regularly. After 720 days of immersion one set of mortars was anodically polarized and another set cathodically polarized. After that, Raman spectra of corrosion products were registered. Additional specimens were used to evaluate porosity and chloride profiles. The presence of phosphate ions as inhibitors has no effect on Ecorr values and suggests mixed-type inhibition. Mix C remains passive until 180 days of exposure, with Rt> 100 kΩ cm2. At longer times, Rt decreases in time but the inhibition percentage is always higher than 95% when evaluated by impedance spectra. Using Rp, inhibition stays above 70%. Anodic and cathodic polarization curves, together with corrosion potential values, suggest that phosphates behave as a mixed-type inhibitor.
Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The purpose of this investigation is to analyze the effectiveness of phosphates as inhibiting agents for steel bars embedded in mortars. Three mix designs were selected for this study: mix A had no admixed chlorides and was used as reference; mix designs B and C were contaminated with 1% in weight of chlorides/weight of cement and mix C also incorporated 7% Na3PO4.12 H2O. After setting for 48 h, the samples were cured for 7 days immersed in water. Three specimens of each group were then immersed in aerated saline solutions 0.5 mol L−1 NaCl during 720 days. The corrosion potential (Ecorr), the polarization resistance (Rp) and the electrochemical impedance spectra were recorded regularly. After 720 days of immersion one set of mortars was anodically polarized and another set cathodically polarized. After that, Raman spectra of corrosion products were registered. Additional specimens were used to evaluate porosity and chloride profiles. The presence of phosphate ions as inhibitors has no effect on Ecorr values and suggests mixed-type inhibition. Mix C remains passive until 180 days of exposure, with Rt> 100 kΩ cm2. At longer times, Rt decreases in time but the inhibition percentage is always higher than 95% when evaluated by impedance spectra. Using Rp, inhibition stays above 70%. Anodic and cathodic polarization curves, together with corrosion potential values, suggest that phosphates behave as a mixed-type inhibitor.
publishDate 2015
dc.date.none.fl_str_mv 2015-12-22
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34403
Yohai del Cerro, Lucía; Valcarce, María Beatriz; Vazquez, Marcela Vivian; Testing phosphate ions as corrosion inhibitors for construction steel in mortars; Pergamon-Elsevier Science Ltd.; Electrochimica Acta; 202; 22-12-2015; 316-324
0013-4686
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34403
identifier_str_mv Yohai del Cerro, Lucía; Valcarce, María Beatriz; Vazquez, Marcela Vivian; Testing phosphate ions as corrosion inhibitors for construction steel in mortars; Pergamon-Elsevier Science Ltd.; Electrochimica Acta; 202; 22-12-2015; 316-324
0013-4686
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0013468615310483
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2015.12.124
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd.
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd.
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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