Testing phosphate ions as corrosion inhibitors for construction steel in mortars
- Autores
- Yohai del Cerro, Lucía; Valcarce, María Beatriz; Vazquez, Marcela Vivian
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The purpose of this investigation is to analyze the effectiveness of phosphates as inhibiting agents for steel bars embedded in mortars. Three mix designs were selected for this study: mix A had no admixed chlorides and was used as reference; mix designs B and C were contaminated with 1% in weight of chlorides/weight of cement and mix C also incorporated 7% Na3PO4.12 H2O. After setting for 48 h, the samples were cured for 7 days immersed in water. Three specimens of each group were then immersed in aerated saline solutions 0.5 mol L−1 NaCl during 720 days. The corrosion potential (Ecorr), the polarization resistance (Rp) and the electrochemical impedance spectra were recorded regularly. After 720 days of immersion one set of mortars was anodically polarized and another set cathodically polarized. After that, Raman spectra of corrosion products were registered. Additional specimens were used to evaluate porosity and chloride profiles. The presence of phosphate ions as inhibitors has no effect on Ecorr values and suggests mixed-type inhibition. Mix C remains passive until 180 days of exposure, with Rt> 100 kΩ cm2. At longer times, Rt decreases in time but the inhibition percentage is always higher than 95% when evaluated by impedance spectra. Using Rp, inhibition stays above 70%. Anodic and cathodic polarization curves, together with corrosion potential values, suggest that phosphates behave as a mixed-type inhibitor.
Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Phosphate Ions
Construction Steel
Mortar
Corrosion - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/34403
Ver los metadatos del registro completo
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Testing phosphate ions as corrosion inhibitors for construction steel in mortarsYohai del Cerro, LucíaValcarce, María BeatrizVazquez, Marcela VivianPhosphate IonsConstruction SteelMortarCorrosionhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The purpose of this investigation is to analyze the effectiveness of phosphates as inhibiting agents for steel bars embedded in mortars. Three mix designs were selected for this study: mix A had no admixed chlorides and was used as reference; mix designs B and C were contaminated with 1% in weight of chlorides/weight of cement and mix C also incorporated 7% Na3PO4.12 H2O. After setting for 48 h, the samples were cured for 7 days immersed in water. Three specimens of each group were then immersed in aerated saline solutions 0.5 mol L−1 NaCl during 720 days. The corrosion potential (Ecorr), the polarization resistance (Rp) and the electrochemical impedance spectra were recorded regularly. After 720 days of immersion one set of mortars was anodically polarized and another set cathodically polarized. After that, Raman spectra of corrosion products were registered. Additional specimens were used to evaluate porosity and chloride profiles. The presence of phosphate ions as inhibitors has no effect on Ecorr values and suggests mixed-type inhibition. Mix C remains passive until 180 days of exposure, with Rt> 100 kΩ cm2. At longer times, Rt decreases in time but the inhibition percentage is always higher than 95% when evaluated by impedance spectra. Using Rp, inhibition stays above 70%. Anodic and cathodic polarization curves, together with corrosion potential values, suggest that phosphates behave as a mixed-type inhibitor.Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaPergamon-Elsevier Science Ltd.2015-12-22info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34403Yohai del Cerro, Lucía; Valcarce, María Beatriz; Vazquez, Marcela Vivian; Testing phosphate ions as corrosion inhibitors for construction steel in mortars; Pergamon-Elsevier Science Ltd.; Electrochimica Acta; 202; 22-12-2015; 316-3240013-4686CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0013468615310483info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2015.12.124info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:42Zoai:ri.conicet.gov.ar:11336/34403instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:42.347CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Testing phosphate ions as corrosion inhibitors for construction steel in mortars |
title |
Testing phosphate ions as corrosion inhibitors for construction steel in mortars |
spellingShingle |
Testing phosphate ions as corrosion inhibitors for construction steel in mortars Yohai del Cerro, Lucía Phosphate Ions Construction Steel Mortar Corrosion |
title_short |
Testing phosphate ions as corrosion inhibitors for construction steel in mortars |
title_full |
Testing phosphate ions as corrosion inhibitors for construction steel in mortars |
title_fullStr |
Testing phosphate ions as corrosion inhibitors for construction steel in mortars |
title_full_unstemmed |
Testing phosphate ions as corrosion inhibitors for construction steel in mortars |
title_sort |
Testing phosphate ions as corrosion inhibitors for construction steel in mortars |
dc.creator.none.fl_str_mv |
Yohai del Cerro, Lucía Valcarce, María Beatriz Vazquez, Marcela Vivian |
author |
Yohai del Cerro, Lucía |
author_facet |
Yohai del Cerro, Lucía Valcarce, María Beatriz Vazquez, Marcela Vivian |
author_role |
author |
author2 |
Valcarce, María Beatriz Vazquez, Marcela Vivian |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Phosphate Ions Construction Steel Mortar Corrosion |
topic |
Phosphate Ions Construction Steel Mortar Corrosion |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The purpose of this investigation is to analyze the effectiveness of phosphates as inhibiting agents for steel bars embedded in mortars. Three mix designs were selected for this study: mix A had no admixed chlorides and was used as reference; mix designs B and C were contaminated with 1% in weight of chlorides/weight of cement and mix C also incorporated 7% Na3PO4.12 H2O. After setting for 48 h, the samples were cured for 7 days immersed in water. Three specimens of each group were then immersed in aerated saline solutions 0.5 mol L−1 NaCl during 720 days. The corrosion potential (Ecorr), the polarization resistance (Rp) and the electrochemical impedance spectra were recorded regularly. After 720 days of immersion one set of mortars was anodically polarized and another set cathodically polarized. After that, Raman spectra of corrosion products were registered. Additional specimens were used to evaluate porosity and chloride profiles. The presence of phosphate ions as inhibitors has no effect on Ecorr values and suggests mixed-type inhibition. Mix C remains passive until 180 days of exposure, with Rt> 100 kΩ cm2. At longer times, Rt decreases in time but the inhibition percentage is always higher than 95% when evaluated by impedance spectra. Using Rp, inhibition stays above 70%. Anodic and cathodic polarization curves, together with corrosion potential values, suggest that phosphates behave as a mixed-type inhibitor. Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
The purpose of this investigation is to analyze the effectiveness of phosphates as inhibiting agents for steel bars embedded in mortars. Three mix designs were selected for this study: mix A had no admixed chlorides and was used as reference; mix designs B and C were contaminated with 1% in weight of chlorides/weight of cement and mix C also incorporated 7% Na3PO4.12 H2O. After setting for 48 h, the samples were cured for 7 days immersed in water. Three specimens of each group were then immersed in aerated saline solutions 0.5 mol L−1 NaCl during 720 days. The corrosion potential (Ecorr), the polarization resistance (Rp) and the electrochemical impedance spectra were recorded regularly. After 720 days of immersion one set of mortars was anodically polarized and another set cathodically polarized. After that, Raman spectra of corrosion products were registered. Additional specimens were used to evaluate porosity and chloride profiles. The presence of phosphate ions as inhibitors has no effect on Ecorr values and suggests mixed-type inhibition. Mix C remains passive until 180 days of exposure, with Rt> 100 kΩ cm2. At longer times, Rt decreases in time but the inhibition percentage is always higher than 95% when evaluated by impedance spectra. Using Rp, inhibition stays above 70%. Anodic and cathodic polarization curves, together with corrosion potential values, suggest that phosphates behave as a mixed-type inhibitor. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-12-22 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/34403 Yohai del Cerro, Lucía; Valcarce, María Beatriz; Vazquez, Marcela Vivian; Testing phosphate ions as corrosion inhibitors for construction steel in mortars; Pergamon-Elsevier Science Ltd.; Electrochimica Acta; 202; 22-12-2015; 316-324 0013-4686 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/34403 |
identifier_str_mv |
Yohai del Cerro, Lucía; Valcarce, María Beatriz; Vazquez, Marcela Vivian; Testing phosphate ions as corrosion inhibitors for construction steel in mortars; Pergamon-Elsevier Science Ltd.; Electrochimica Acta; 202; 22-12-2015; 316-324 0013-4686 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0013468615310483 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2015.12.124 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd. |
publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd. |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613223648591872 |
score |
13.070432 |