Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion
- Autores
- Neyertz, Claudia A; Banus, Ezequiel David; Miro, Eduardo Ernesto; Querini, Carlos Alberto
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This work presents a comparative study of Ce0.65Zr0.35O2 and CeO2 catalysts supported on cordierite for soot combustion, and the effect of potassium on the catalytic performance. The catalysts were prepared by sequential impregnation over the monolith. The activity in the soot combustion by O2 was studied by successive temperature programmed oxidation cycles, using a loose-contact mode between the soot and the catalyst. A deactivation was observed after ten cycles of combustion for potassium catalysts. This deactivation was attributed to potassium loss at high temperatures. On the other hand, the catalysts without K showed activation after the ten soot combustions. When catalysts with the same cerium molar loading were compared, an improvement in the activity of the mixed oxide compared with the pure ceria was observed. The soot combustion was improved for K/Ce0.65Zr0.35O2/cordierite and K/CeO2/cordierite with NO/O2 presence. However, the catalyst K/CeO2/cordierite was still more active. By X-ray diffraction analyses, it was found that insertion of zirconium into the CeO2 structure took place during preparation. However, a Raman and SEM/EPMA studies indicated heterogeneity in Ce0.65Zr0.35O2. Domains of cerium–zirconium inside the cordierite channel with a ratio different from the nominal value were observed by scanning electron microscopy analyses. This heterogeneity could decrease the catalytic activity of the cerium–zirconium oxide mixture. The catalytic activity in supported catalysts strongly depends on the effect of Zr, the number of Ce4+/Ce3+ redox surface sites, the BET area and the structural changes induced by high temperatures.
Fil: Neyertz, Claudia A. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Banus, Ezequiel David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina - Materia
-
Diesel Soot
Cerium
Zirconium
Cordierite - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/31646
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Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustionNeyertz, Claudia ABanus, Ezequiel DavidMiro, Eduardo ErnestoQuerini, Carlos AlbertoDiesel SootCeriumZirconiumCordieritehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This work presents a comparative study of Ce0.65Zr0.35O2 and CeO2 catalysts supported on cordierite for soot combustion, and the effect of potassium on the catalytic performance. The catalysts were prepared by sequential impregnation over the monolith. The activity in the soot combustion by O2 was studied by successive temperature programmed oxidation cycles, using a loose-contact mode between the soot and the catalyst. A deactivation was observed after ten cycles of combustion for potassium catalysts. This deactivation was attributed to potassium loss at high temperatures. On the other hand, the catalysts without K showed activation after the ten soot combustions. When catalysts with the same cerium molar loading were compared, an improvement in the activity of the mixed oxide compared with the pure ceria was observed. The soot combustion was improved for K/Ce0.65Zr0.35O2/cordierite and K/CeO2/cordierite with NO/O2 presence. However, the catalyst K/CeO2/cordierite was still more active. By X-ray diffraction analyses, it was found that insertion of zirconium into the CeO2 structure took place during preparation. However, a Raman and SEM/EPMA studies indicated heterogeneity in Ce0.65Zr0.35O2. Domains of cerium–zirconium inside the cordierite channel with a ratio different from the nominal value were observed by scanning electron microscopy analyses. This heterogeneity could decrease the catalytic activity of the cerium–zirconium oxide mixture. The catalytic activity in supported catalysts strongly depends on the effect of Zr, the number of Ce4+/Ce3+ redox surface sites, the BET area and the structural changes induced by high temperatures.Fil: Neyertz, Claudia A. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Banus, Ezequiel David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier2014-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31646Banus, Ezequiel David; Miro, Eduardo Ernesto; Neyertz, Claudia A; Querini, Carlos Alberto; Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion; Elsevier; Chemical Engineering Journal; 248; 3-2014; 394-4051385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S138589471400326Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2014.03.048info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:21Zoai:ri.conicet.gov.ar:11336/31646instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:21.58CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion |
title |
Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion |
spellingShingle |
Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion Neyertz, Claudia A Diesel Soot Cerium Zirconium Cordierite |
title_short |
Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion |
title_full |
Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion |
title_fullStr |
Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion |
title_full_unstemmed |
Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion |
title_sort |
Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion |
dc.creator.none.fl_str_mv |
Neyertz, Claudia A Banus, Ezequiel David Miro, Eduardo Ernesto Querini, Carlos Alberto |
author |
Neyertz, Claudia A |
author_facet |
Neyertz, Claudia A Banus, Ezequiel David Miro, Eduardo Ernesto Querini, Carlos Alberto |
author_role |
author |
author2 |
Banus, Ezequiel David Miro, Eduardo Ernesto Querini, Carlos Alberto |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Diesel Soot Cerium Zirconium Cordierite |
topic |
Diesel Soot Cerium Zirconium Cordierite |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
This work presents a comparative study of Ce0.65Zr0.35O2 and CeO2 catalysts supported on cordierite for soot combustion, and the effect of potassium on the catalytic performance. The catalysts were prepared by sequential impregnation over the monolith. The activity in the soot combustion by O2 was studied by successive temperature programmed oxidation cycles, using a loose-contact mode between the soot and the catalyst. A deactivation was observed after ten cycles of combustion for potassium catalysts. This deactivation was attributed to potassium loss at high temperatures. On the other hand, the catalysts without K showed activation after the ten soot combustions. When catalysts with the same cerium molar loading were compared, an improvement in the activity of the mixed oxide compared with the pure ceria was observed. The soot combustion was improved for K/Ce0.65Zr0.35O2/cordierite and K/CeO2/cordierite with NO/O2 presence. However, the catalyst K/CeO2/cordierite was still more active. By X-ray diffraction analyses, it was found that insertion of zirconium into the CeO2 structure took place during preparation. However, a Raman and SEM/EPMA studies indicated heterogeneity in Ce0.65Zr0.35O2. Domains of cerium–zirconium inside the cordierite channel with a ratio different from the nominal value were observed by scanning electron microscopy analyses. This heterogeneity could decrease the catalytic activity of the cerium–zirconium oxide mixture. The catalytic activity in supported catalysts strongly depends on the effect of Zr, the number of Ce4+/Ce3+ redox surface sites, the BET area and the structural changes induced by high temperatures. Fil: Neyertz, Claudia A. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Banus, Ezequiel David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina |
description |
This work presents a comparative study of Ce0.65Zr0.35O2 and CeO2 catalysts supported on cordierite for soot combustion, and the effect of potassium on the catalytic performance. The catalysts were prepared by sequential impregnation over the monolith. The activity in the soot combustion by O2 was studied by successive temperature programmed oxidation cycles, using a loose-contact mode between the soot and the catalyst. A deactivation was observed after ten cycles of combustion for potassium catalysts. This deactivation was attributed to potassium loss at high temperatures. On the other hand, the catalysts without K showed activation after the ten soot combustions. When catalysts with the same cerium molar loading were compared, an improvement in the activity of the mixed oxide compared with the pure ceria was observed. The soot combustion was improved for K/Ce0.65Zr0.35O2/cordierite and K/CeO2/cordierite with NO/O2 presence. However, the catalyst K/CeO2/cordierite was still more active. By X-ray diffraction analyses, it was found that insertion of zirconium into the CeO2 structure took place during preparation. However, a Raman and SEM/EPMA studies indicated heterogeneity in Ce0.65Zr0.35O2. Domains of cerium–zirconium inside the cordierite channel with a ratio different from the nominal value were observed by scanning electron microscopy analyses. This heterogeneity could decrease the catalytic activity of the cerium–zirconium oxide mixture. The catalytic activity in supported catalysts strongly depends on the effect of Zr, the number of Ce4+/Ce3+ redox surface sites, the BET area and the structural changes induced by high temperatures. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/31646 Banus, Ezequiel David; Miro, Eduardo Ernesto; Neyertz, Claudia A; Querini, Carlos Alberto; Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion; Elsevier; Chemical Engineering Journal; 248; 3-2014; 394-405 1385-8947 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/31646 |
identifier_str_mv |
Banus, Ezequiel David; Miro, Eduardo Ernesto; Neyertz, Claudia A; Querini, Carlos Alberto; Potassium-promoted Ce0.65Zr0.35O2 monolithic catalysts for diesel soot combustion; Elsevier; Chemical Engineering Journal; 248; 3-2014; 394-405 1385-8947 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S138589471400326X info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2014.03.048 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269339616542720 |
score |
13.13397 |