Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies

Autores
Imoberdorf, Gustavo Eduardo; Cassano, Alberto Enrique; Irazoqui, Horacio Antonio; Alfano, Orlando Mario
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A multi-annular photocatalytic reactor was designed, that shows good effectiveness for perchloroethylene (PCE) removal from contaminated air streams. In a previous work, a rigorous physical and mathematical model of the photocatalytic reactor was developed and experimentally verified. In this work, this mathematical model was used to study the radiative energy efficiency of the multi-annular photoreactor. The total quantum efficiency is defined as the ratio of the number of molecules of PCE reacted to the number of photons emitted by the lamp, and it is expressed as the product of the following factors: the reactor radiation incidence efficiency, the catalyst radiation absorption efficiency, and the overall reaction quantum efficiency. For the employed reactor, the numerical values of each one were 83%, 92%, and <2.5%, respectively. Particularly, the dependence of the overall reaction quantum efficiency upon operating variables such as the PCE feed concentration, gas flow rate, irradiation level and relative air humidity was analyzed. These results are useful to optimize the operating conditions and design parameters of the photocatalytic reactor.
Fil: Imoberdorf, Gustavo Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Irazoqui, Horacio Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/26411
Acceder
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spelling Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy EfficienciesImoberdorf, Gustavo EduardoCassano, Alberto EnriqueIrazoqui, Horacio AntonioAlfano, Orlando Mariohttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A multi-annular photocatalytic reactor was designed, that shows good effectiveness for perchloroethylene (PCE) removal from contaminated air streams. In a previous work, a rigorous physical and mathematical model of the photocatalytic reactor was developed and experimentally verified. In this work, this mathematical model was used to study the radiative energy efficiency of the multi-annular photoreactor. The total quantum efficiency is defined as the ratio of the number of molecules of PCE reacted to the number of photons emitted by the lamp, and it is expressed as the product of the following factors: the reactor radiation incidence efficiency, the catalyst radiation absorption efficiency, and the overall reaction quantum efficiency. For the employed reactor, the numerical values of each one were 83%, 92%, and <2.5%, respectively. Particularly, the dependence of the overall reaction quantum efficiency upon operating variables such as the PCE feed concentration, gas flow rate, irradiation level and relative air humidity was analyzed. These results are useful to optimize the operating conditions and design parameters of the photocatalytic reactor.Fil: Imoberdorf, Gustavo Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Irazoqui, Horacio Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaElsevier2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/26411Imoberdorf, Gustavo Eduardo; Cassano, Alberto Enrique; Irazoqui, Horacio Antonio; Alfano, Orlando Mario; Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies; Elsevier; Chemical Engineering Science; 62; 4; 12-2006; 1138-11540009-2509CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2006.10.024info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009250906006804info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:16:56Zoai:ri.conicet.gov.ar:11336/26411instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:16:56.732CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies
title Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies
spellingShingle Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies
Imoberdorf, Gustavo Eduardo
title_short Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies
title_full Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies
title_fullStr Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies
title_full_unstemmed Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies
title_sort Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies
dc.creator.none.fl_str_mv Imoberdorf, Gustavo Eduardo
Cassano, Alberto Enrique
Irazoqui, Horacio Antonio
Alfano, Orlando Mario
author Imoberdorf, Gustavo Eduardo
author_facet Imoberdorf, Gustavo Eduardo
Cassano, Alberto Enrique
Irazoqui, Horacio Antonio
Alfano, Orlando Mario
author_role author
author2 Cassano, Alberto Enrique
Irazoqui, Horacio Antonio
Alfano, Orlando Mario
author2_role author
author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A multi-annular photocatalytic reactor was designed, that shows good effectiveness for perchloroethylene (PCE) removal from contaminated air streams. In a previous work, a rigorous physical and mathematical model of the photocatalytic reactor was developed and experimentally verified. In this work, this mathematical model was used to study the radiative energy efficiency of the multi-annular photoreactor. The total quantum efficiency is defined as the ratio of the number of molecules of PCE reacted to the number of photons emitted by the lamp, and it is expressed as the product of the following factors: the reactor radiation incidence efficiency, the catalyst radiation absorption efficiency, and the overall reaction quantum efficiency. For the employed reactor, the numerical values of each one were 83%, 92%, and <2.5%, respectively. Particularly, the dependence of the overall reaction quantum efficiency upon operating variables such as the PCE feed concentration, gas flow rate, irradiation level and relative air humidity was analyzed. These results are useful to optimize the operating conditions and design parameters of the photocatalytic reactor.
Fil: Imoberdorf, Gustavo Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Irazoqui, Horacio Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description A multi-annular photocatalytic reactor was designed, that shows good effectiveness for perchloroethylene (PCE) removal from contaminated air streams. In a previous work, a rigorous physical and mathematical model of the photocatalytic reactor was developed and experimentally verified. In this work, this mathematical model was used to study the radiative energy efficiency of the multi-annular photoreactor. The total quantum efficiency is defined as the ratio of the number of molecules of PCE reacted to the number of photons emitted by the lamp, and it is expressed as the product of the following factors: the reactor radiation incidence efficiency, the catalyst radiation absorption efficiency, and the overall reaction quantum efficiency. For the employed reactor, the numerical values of each one were 83%, 92%, and <2.5%, respectively. Particularly, the dependence of the overall reaction quantum efficiency upon operating variables such as the PCE feed concentration, gas flow rate, irradiation level and relative air humidity was analyzed. These results are useful to optimize the operating conditions and design parameters of the photocatalytic reactor.
publishDate 2006
dc.date.none.fl_str_mv 2006-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/26411
Imoberdorf, Gustavo Eduardo; Cassano, Alberto Enrique; Irazoqui, Horacio Antonio; Alfano, Orlando Mario; Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies; Elsevier; Chemical Engineering Science; 62; 4; 12-2006; 1138-1154
0009-2509
CONICET Digital
CONICET
url http://hdl.handle.net/11336/26411
identifier_str_mv Imoberdorf, Gustavo Eduardo; Cassano, Alberto Enrique; Irazoqui, Horacio Antonio; Alfano, Orlando Mario; Simulation of a Multi-annular Photocatalytic Reactor for Degradation of Perchloroethylene in Air: Parametric Analysis of Radiative Energy Efficiencies; Elsevier; Chemical Engineering Science; 62; 4; 12-2006; 1138-1154
0009-2509
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2006.10.024
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009250906006804
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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