In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane

Autores
Faroldi, Betina María Cecilia; Múnera Agudelo, John Fernando; Cornaglia, Laura Maria
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A lanthanum oxycarbonate phase (La2O2CO3) with high surface area was prepared as support of Ru catalysts. The metal was added by wet impregnation or incorporated during the oxycarbonate synthesis. The reactivity of the lanthanum and ruthenium species was studied through in situ Raman under dry reforming of methane conditions with and without oxygen addition. When Ru was incorporated by wet impregnation, the solid showed a higher reactivity of lanthanum oxycarbonate to the formation of La2O3 in a hydrogen flow even at low temperatures while RuOx was completely reduced at 400 °C. It was also found that the reduced ruthenium species could be re-oxidized by CO2 at the reaction temperature (550 °C). Under the dry reforming of methane, the metallic Ru did not change its oxidation state and the formation of graphitic carbon and oxycarbonate was observed. With the addition of oxygen, the same phase transformation occurred as in the case of the dry reforming of methane. However, the re-oxidation of Ru0 species was observed through in situ Laser Raman spectroscopy and pseudo in situ XPS measurements. These measurements allowed us to advance in the understanding of the solid transformations produced during methane reforming reactions.
Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Combined Reforming of Methane
La2o2co3
Ruthenium
Hydrogen Production
Pseudo in Situ Xps And in Situ Lrs
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31734
Acceder
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network_name_str CONICET Digital (CONICET)
spelling In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methaneFaroldi, Betina María CeciliaMúnera Agudelo, John FernandoCornaglia, Laura MariaCombined Reforming of MethaneLa2o2co3RutheniumHydrogen ProductionPseudo in Situ Xps And in Situ Lrshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A lanthanum oxycarbonate phase (La2O2CO3) with high surface area was prepared as support of Ru catalysts. The metal was added by wet impregnation or incorporated during the oxycarbonate synthesis. The reactivity of the lanthanum and ruthenium species was studied through in situ Raman under dry reforming of methane conditions with and without oxygen addition. When Ru was incorporated by wet impregnation, the solid showed a higher reactivity of lanthanum oxycarbonate to the formation of La2O3 in a hydrogen flow even at low temperatures while RuOx was completely reduced at 400 °C. It was also found that the reduced ruthenium species could be re-oxidized by CO2 at the reaction temperature (550 °C). Under the dry reforming of methane, the metallic Ru did not change its oxidation state and the formation of graphitic carbon and oxycarbonate was observed. With the addition of oxygen, the same phase transformation occurred as in the case of the dry reforming of methane. However, the re-oxidation of Ru0 species was observed through in situ Laser Raman spectroscopy and pseudo in situ XPS measurements. These measurements allowed us to advance in the understanding of the solid transformations produced during methane reforming reactions.Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier2013-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31734Cornaglia, Laura Maria; Múnera Agudelo, John Fernando; Faroldi, Betina María Cecilia; In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane; Elsevier; Applied Catalysis B: Environmental; 150-151; 12-2013; 126-1370926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2013.12.005info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926337313007509info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:27:29Zoai:ri.conicet.gov.ar:11336/31734instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:27:29.314CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane
title In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane
spellingShingle In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane
Faroldi, Betina María Cecilia
Combined Reforming of Methane
La2o2co3
Ruthenium
Hydrogen Production
Pseudo in Situ Xps And in Situ Lrs
title_short In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane
title_full In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane
title_fullStr In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane
title_full_unstemmed In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane
title_sort In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane
dc.creator.none.fl_str_mv Faroldi, Betina María Cecilia
Múnera Agudelo, John Fernando
Cornaglia, Laura Maria
author Faroldi, Betina María Cecilia
author_facet Faroldi, Betina María Cecilia
Múnera Agudelo, John Fernando
Cornaglia, Laura Maria
author_role author
author2 Múnera Agudelo, John Fernando
Cornaglia, Laura Maria
author2_role author
author
dc.subject.none.fl_str_mv Combined Reforming of Methane
La2o2co3
Ruthenium
Hydrogen Production
Pseudo in Situ Xps And in Situ Lrs
topic Combined Reforming of Methane
La2o2co3
Ruthenium
Hydrogen Production
Pseudo in Situ Xps And in Situ Lrs
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A lanthanum oxycarbonate phase (La2O2CO3) with high surface area was prepared as support of Ru catalysts. The metal was added by wet impregnation or incorporated during the oxycarbonate synthesis. The reactivity of the lanthanum and ruthenium species was studied through in situ Raman under dry reforming of methane conditions with and without oxygen addition. When Ru was incorporated by wet impregnation, the solid showed a higher reactivity of lanthanum oxycarbonate to the formation of La2O3 in a hydrogen flow even at low temperatures while RuOx was completely reduced at 400 °C. It was also found that the reduced ruthenium species could be re-oxidized by CO2 at the reaction temperature (550 °C). Under the dry reforming of methane, the metallic Ru did not change its oxidation state and the formation of graphitic carbon and oxycarbonate was observed. With the addition of oxygen, the same phase transformation occurred as in the case of the dry reforming of methane. However, the re-oxidation of Ru0 species was observed through in situ Laser Raman spectroscopy and pseudo in situ XPS measurements. These measurements allowed us to advance in the understanding of the solid transformations produced during methane reforming reactions.
Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description A lanthanum oxycarbonate phase (La2O2CO3) with high surface area was prepared as support of Ru catalysts. The metal was added by wet impregnation or incorporated during the oxycarbonate synthesis. The reactivity of the lanthanum and ruthenium species was studied through in situ Raman under dry reforming of methane conditions with and without oxygen addition. When Ru was incorporated by wet impregnation, the solid showed a higher reactivity of lanthanum oxycarbonate to the formation of La2O3 in a hydrogen flow even at low temperatures while RuOx was completely reduced at 400 °C. It was also found that the reduced ruthenium species could be re-oxidized by CO2 at the reaction temperature (550 °C). Under the dry reforming of methane, the metallic Ru did not change its oxidation state and the formation of graphitic carbon and oxycarbonate was observed. With the addition of oxygen, the same phase transformation occurred as in the case of the dry reforming of methane. However, the re-oxidation of Ru0 species was observed through in situ Laser Raman spectroscopy and pseudo in situ XPS measurements. These measurements allowed us to advance in the understanding of the solid transformations produced during methane reforming reactions.
publishDate 2013
dc.date.none.fl_str_mv 2013-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31734
Cornaglia, Laura Maria; Múnera Agudelo, John Fernando; Faroldi, Betina María Cecilia; In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane; Elsevier; Applied Catalysis B: Environmental; 150-151; 12-2013; 126-137
0926-3373
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31734
identifier_str_mv Cornaglia, Laura Maria; Múnera Agudelo, John Fernando; Faroldi, Betina María Cecilia; In situ characterization of phase transformation and reactivity of high surface area lanthanum-based Ru catalysts for the combined reforming of methane; Elsevier; Applied Catalysis B: Environmental; 150-151; 12-2013; 126-137
0926-3373
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2013.12.005
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926337313007509
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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