Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene
- Autores
- Zelin, Juan; Nieres, Pablo Daniel; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Abstract The activity and selectivity of silica-supported Hoveyda-Grubbs (HG) complex for the cross-metathesis of methyl oleate with 1-hexene to obtain 1-decene, methyl 9-tetradecenoate, 5-tetradecene and methyl 9-decenoate were studied in a batch reactor. The HG complex loading was varied between 0.87 and 11.6 wt%. Competitive secondary reactions were the self-metathesis of methyl oleate and the self-metathesis of 1-hexene. The yield to cross-metathesis products (ηC-M) was 47% when a 1-hexene/methyl oleate reactant ratio (RC6/MO) of one was employed. The ηC-M value increased with increasing 1-hexene initial concentration, reaching 87% for RC6/MO = 7. The selectivity to terminal olefins also increased at the expense of internal olefins among the cross-metathesis products when the concentration of 1-hexene was increased.
 Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
 Fil: Nieres, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
 Fil: Trasarti, Andres Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
 Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
- Materia
- 
            
        1-Hexene
 Cross-Metathesis
 Fame
 Hoveyda-Grubbs Catalysts,
 Methyl Oleate
 Oleochemistry
- Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg) 
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/36653
Ver los metadatos del registro completo
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| spelling | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexeneZelin, JuanNieres, Pablo DanielTrasarti, Andres FernandoApesteguia, Carlos Rodolfo1-HexeneCross-MetathesisFameHoveyda-Grubbs Catalysts,Methyl OleateOleochemistryhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Abstract The activity and selectivity of silica-supported Hoveyda-Grubbs (HG) complex for the cross-metathesis of methyl oleate with 1-hexene to obtain 1-decene, methyl 9-tetradecenoate, 5-tetradecene and methyl 9-decenoate were studied in a batch reactor. The HG complex loading was varied between 0.87 and 11.6 wt%. Competitive secondary reactions were the self-metathesis of methyl oleate and the self-metathesis of 1-hexene. The yield to cross-metathesis products (ηC-M) was 47% when a 1-hexene/methyl oleate reactant ratio (RC6/MO) of one was employed. The ηC-M value increased with increasing 1-hexene initial concentration, reaching 87% for RC6/MO = 7. The selectivity to terminal olefins also increased at the expense of internal olefins among the cross-metathesis products when the concentration of 1-hexene was increased.Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Nieres, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Trasarti, Andres Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier2015-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/36653Zelin, Juan; Nieres, Pablo Daniel; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo; Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene; Elsevier; Applied Catalysis A: General; 502; 7-2015; 410-4170926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2015.06.021info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X15300375info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-29T11:14:34Zoai:ri.conicet.gov.ar:11336/36653instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-29 11:14:34.915CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse | 
| dc.title.none.fl_str_mv | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene | 
| title | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene | 
| spellingShingle | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene Zelin, Juan 1-Hexene Cross-Metathesis Fame Hoveyda-Grubbs Catalysts, Methyl Oleate Oleochemistry | 
| title_short | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene | 
| title_full | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene | 
| title_fullStr | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene | 
| title_full_unstemmed | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene | 
| title_sort | Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene | 
| dc.creator.none.fl_str_mv | Zelin, Juan Nieres, Pablo Daniel Trasarti, Andres Fernando Apesteguia, Carlos Rodolfo | 
| author | Zelin, Juan | 
| author_facet | Zelin, Juan Nieres, Pablo Daniel Trasarti, Andres Fernando Apesteguia, Carlos Rodolfo | 
| author_role | author | 
| author2 | Nieres, Pablo Daniel Trasarti, Andres Fernando Apesteguia, Carlos Rodolfo | 
| author2_role | author author author | 
| dc.subject.none.fl_str_mv | 1-Hexene Cross-Metathesis Fame Hoveyda-Grubbs Catalysts, Methyl Oleate Oleochemistry | 
| topic | 1-Hexene Cross-Metathesis Fame Hoveyda-Grubbs Catalysts, Methyl Oleate Oleochemistry | 
| purl_subject.fl_str_mv | https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 | 
| dc.description.none.fl_txt_mv | Abstract The activity and selectivity of silica-supported Hoveyda-Grubbs (HG) complex for the cross-metathesis of methyl oleate with 1-hexene to obtain 1-decene, methyl 9-tetradecenoate, 5-tetradecene and methyl 9-decenoate were studied in a batch reactor. The HG complex loading was varied between 0.87 and 11.6 wt%. Competitive secondary reactions were the self-metathesis of methyl oleate and the self-metathesis of 1-hexene. The yield to cross-metathesis products (ηC-M) was 47% when a 1-hexene/methyl oleate reactant ratio (RC6/MO) of one was employed. The ηC-M value increased with increasing 1-hexene initial concentration, reaching 87% for RC6/MO = 7. The selectivity to terminal olefins also increased at the expense of internal olefins among the cross-metathesis products when the concentration of 1-hexene was increased. Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Nieres, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Trasarti, Andres Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina | 
| description | Abstract The activity and selectivity of silica-supported Hoveyda-Grubbs (HG) complex for the cross-metathesis of methyl oleate with 1-hexene to obtain 1-decene, methyl 9-tetradecenoate, 5-tetradecene and methyl 9-decenoate were studied in a batch reactor. The HG complex loading was varied between 0.87 and 11.6 wt%. Competitive secondary reactions were the self-metathesis of methyl oleate and the self-metathesis of 1-hexene. The yield to cross-metathesis products (ηC-M) was 47% when a 1-hexene/methyl oleate reactant ratio (RC6/MO) of one was employed. The ηC-M value increased with increasing 1-hexene initial concentration, reaching 87% for RC6/MO = 7. The selectivity to terminal olefins also increased at the expense of internal olefins among the cross-metathesis products when the concentration of 1-hexene was increased. | 
| publishDate | 2015 | 
| dc.date.none.fl_str_mv | 2015-07 | 
| dc.type.none.fl_str_mv | info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo | 
| format | article | 
| status_str | publishedVersion | 
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/11336/36653 Zelin, Juan; Nieres, Pablo Daniel; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo; Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene; Elsevier; Applied Catalysis A: General; 502; 7-2015; 410-417 0926-860X CONICET Digital CONICET | 
| url | http://hdl.handle.net/11336/36653 | 
| identifier_str_mv | Zelin, Juan; Nieres, Pablo Daniel; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo; Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene; Elsevier; Applied Catalysis A: General; 502; 7-2015; 410-417 0926-860X CONICET Digital CONICET | 
| dc.language.none.fl_str_mv | eng | 
| language | eng | 
| dc.relation.none.fl_str_mv | info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2015.06.021 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X15300375 | 
| dc.rights.none.fl_str_mv | info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | 
| eu_rights_str_mv | openAccess | 
| rights_invalid_str_mv | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | 
| dc.format.none.fl_str_mv | application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf | 
| dc.publisher.none.fl_str_mv | Elsevier | 
| publisher.none.fl_str_mv | Elsevier | 
| dc.source.none.fl_str_mv | reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas | 
| reponame_str | CONICET Digital (CONICET) | 
| collection | CONICET Digital (CONICET) | 
| instname_str | Consejo Nacional de Investigaciones Científicas y Técnicas | 
| repository.name.fl_str_mv | CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas | 
| repository.mail.fl_str_mv | dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar | 
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| score | 13.10058 |