Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers

Autores
Guzmán, Eduardo; Ritacco, Hernán Alejandro; Ortega, Francisco; Rubio, Ramón G.
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
X-ray reflectivity and adsorption kinetics of two different polyelectrolyte multilayers have been studied for polyelectrolyte multilayers (PEMs) composed of poly(diallyldimethyl ammonium chloride) (PDADMAC) and poly(sodium 4-styrenesulfonate) (PSS) polyelectrolyte pair and of poly(allylamine hydrochloride) (PAH) and PSS. The two characteristic times that describe the adsorption kinetics were found to be related to the X-ray reflectivity results, and their dependence on the number of adsorbed layers is depends on the growth mechanisms (linear or superlinear) of the films. Therefore, it has been concluded that there is a correlation between the adsorption kinetics and the internal structure of the films. The time allowed for the adsorption of each polyelectrolyte controls the extension of the interdiffusion within the multilayer, and therefore whether the film is formed by stratified layers or it has a uniform structure except for the first and last layers. While the roughness of the (PDADMAC + PSS)n films strongly depends on the adsorption time, it is almost independent of it for the (PAH + PSS)n multilayer. This behavior correlates with that of the longest characteristic time of the adsorption kinetics.
Fil: Guzmán, Eduardo. Universidad Complutense de Madrid; España
Fil: Ritacco, Hernán Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; Argentina
Fil: Ortega, Francisco. Universidad Complutense de Madrid; España
Fil: Rubio, Ramón G.. Universidad Complutense de Madrid; España
Materia
Polyeletrolyte Multilayers
Adsorption Kinetics
Stratification
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66162
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/66162
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayersGuzmán, EduardoRitacco, Hernán AlejandroOrtega, FranciscoRubio, Ramón G.Polyeletrolyte MultilayersAdsorption KineticsStratificationhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1X-ray reflectivity and adsorption kinetics of two different polyelectrolyte multilayers have been studied for polyelectrolyte multilayers (PEMs) composed of poly(diallyldimethyl ammonium chloride) (PDADMAC) and poly(sodium 4-styrenesulfonate) (PSS) polyelectrolyte pair and of poly(allylamine hydrochloride) (PAH) and PSS. The two characteristic times that describe the adsorption kinetics were found to be related to the X-ray reflectivity results, and their dependence on the number of adsorbed layers is depends on the growth mechanisms (linear or superlinear) of the films. Therefore, it has been concluded that there is a correlation between the adsorption kinetics and the internal structure of the films. The time allowed for the adsorption of each polyelectrolyte controls the extension of the interdiffusion within the multilayer, and therefore whether the film is formed by stratified layers or it has a uniform structure except for the first and last layers. While the roughness of the (PDADMAC + PSS)n films strongly depends on the adsorption time, it is almost independent of it for the (PAH + PSS)n multilayer. This behavior correlates with that of the longest characteristic time of the adsorption kinetics.Fil: Guzmán, Eduardo. Universidad Complutense de Madrid; EspañaFil: Ritacco, Hernán Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; ArgentinaFil: Ortega, Francisco. Universidad Complutense de Madrid; EspañaFil: Rubio, Ramón G.. Universidad Complutense de Madrid; EspañaElsevier Science2011-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66162Guzmán, Eduardo ; Ritacco, Hernán Alejandro; Ortega, Francisco ; Rubio, Ramón G. ; Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 384; 5-2011; 274-2810927-7757CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2011.04.005info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:07:30Zoai:ri.conicet.gov.ar:11336/66162instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:07:30.99CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers
title Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers
spellingShingle Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers
Guzmán, Eduardo
Polyeletrolyte Multilayers
Adsorption Kinetics
Stratification
title_short Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers
title_full Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers
title_fullStr Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers
title_full_unstemmed Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers
title_sort Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers
dc.creator.none.fl_str_mv Guzmán, Eduardo
Ritacco, Hernán Alejandro
Ortega, Francisco
Rubio, Ramón G.
author Guzmán, Eduardo
author_facet Guzmán, Eduardo
Ritacco, Hernán Alejandro
Ortega, Francisco
Rubio, Ramón G.
author_role author
author2 Ritacco, Hernán Alejandro
Ortega, Francisco
Rubio, Ramón G.
author2_role author
author
author
dc.subject.none.fl_str_mv Polyeletrolyte Multilayers
Adsorption Kinetics
Stratification
topic Polyeletrolyte Multilayers
Adsorption Kinetics
Stratification
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv X-ray reflectivity and adsorption kinetics of two different polyelectrolyte multilayers have been studied for polyelectrolyte multilayers (PEMs) composed of poly(diallyldimethyl ammonium chloride) (PDADMAC) and poly(sodium 4-styrenesulfonate) (PSS) polyelectrolyte pair and of poly(allylamine hydrochloride) (PAH) and PSS. The two characteristic times that describe the adsorption kinetics were found to be related to the X-ray reflectivity results, and their dependence on the number of adsorbed layers is depends on the growth mechanisms (linear or superlinear) of the films. Therefore, it has been concluded that there is a correlation between the adsorption kinetics and the internal structure of the films. The time allowed for the adsorption of each polyelectrolyte controls the extension of the interdiffusion within the multilayer, and therefore whether the film is formed by stratified layers or it has a uniform structure except for the first and last layers. While the roughness of the (PDADMAC + PSS)n films strongly depends on the adsorption time, it is almost independent of it for the (PAH + PSS)n multilayer. This behavior correlates with that of the longest characteristic time of the adsorption kinetics.
Fil: Guzmán, Eduardo. Universidad Complutense de Madrid; España
Fil: Ritacco, Hernán Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; Argentina
Fil: Ortega, Francisco. Universidad Complutense de Madrid; España
Fil: Rubio, Ramón G.. Universidad Complutense de Madrid; España
description X-ray reflectivity and adsorption kinetics of two different polyelectrolyte multilayers have been studied for polyelectrolyte multilayers (PEMs) composed of poly(diallyldimethyl ammonium chloride) (PDADMAC) and poly(sodium 4-styrenesulfonate) (PSS) polyelectrolyte pair and of poly(allylamine hydrochloride) (PAH) and PSS. The two characteristic times that describe the adsorption kinetics were found to be related to the X-ray reflectivity results, and their dependence on the number of adsorbed layers is depends on the growth mechanisms (linear or superlinear) of the films. Therefore, it has been concluded that there is a correlation between the adsorption kinetics and the internal structure of the films. The time allowed for the adsorption of each polyelectrolyte controls the extension of the interdiffusion within the multilayer, and therefore whether the film is formed by stratified layers or it has a uniform structure except for the first and last layers. While the roughness of the (PDADMAC + PSS)n films strongly depends on the adsorption time, it is almost independent of it for the (PAH + PSS)n multilayer. This behavior correlates with that of the longest characteristic time of the adsorption kinetics.
publishDate 2011
dc.date.none.fl_str_mv 2011-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66162
Guzmán, Eduardo ; Ritacco, Hernán Alejandro; Ortega, Francisco ; Rubio, Ramón G. ; Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 384; 5-2011; 274-281
0927-7757
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66162
identifier_str_mv Guzmán, Eduardo ; Ritacco, Hernán Alejandro; Ortega, Francisco ; Rubio, Ramón G. ; Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 384; 5-2011; 274-281
0927-7757
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2011.04.005
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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