Effects of plasticizers on the properties of oat starch films

Autores
Galdeano, Melícia Cíntia; Mali, Suzana; Grossmann, Maria Victória E.; Yamashita, Fábio; Garcia, Maria Alejandra
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Oat starch films were prepared by casting using glycerol, sorbitol, glycerol-sorbitol mixture, urea and sucrose as plasticizers. The effects of these plasticizers on the microstructure, moisture sorption, water vapor permeability (WVP) and mechanical properties were investigated using films stored under a range of relative humidities. The plasticizer type did not affect significantly (p ≤ 0.05) the equilibrium moisture content of films, except at 90% relative humidity (RH). Films without plasticizer adsorbed less water and showed higher WVP than plasticized ones, indicating the antiplasticizing effect observed in this work. In general, a decrease in stress at break and Young's modulus and an increase in strain at break were observed when RH increased in all film formulations. Films without plasticizer showed higher stress at break values than the plasticized ones and presented stable strain at break under a range of RH. Sucrose films were the most fragile at low RH while glycerol films were the most hygroscopic.
Fil: Galdeano, Melícia Cíntia. Universidade Estadual de Londrina; Brasil
Fil: Mali, Suzana. Universidade Estadual de Londrina; Brasil
Fil: Grossmann, Maria Victória E.. Universidade Estadual de Londrina; Brasil
Fil: Yamashita, Fábio. Universidade Estadual de Londrina; Brasil
Fil: Garcia, Maria Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Materia
BIODEGRADABLE PACKAGING
MICROSTRUCTURE AND MECHANICAL PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/161799

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spelling Effects of plasticizers on the properties of oat starch filmsGaldeano, Melícia CíntiaMali, SuzanaGrossmann, Maria Victória E.Yamashita, FábioGarcia, Maria AlejandraBIODEGRADABLE PACKAGINGMICROSTRUCTURE AND MECHANICAL PROPERTIEShttps://purl.org/becyt/ford/2.11https://purl.org/becyt/ford/2Oat starch films were prepared by casting using glycerol, sorbitol, glycerol-sorbitol mixture, urea and sucrose as plasticizers. The effects of these plasticizers on the microstructure, moisture sorption, water vapor permeability (WVP) and mechanical properties were investigated using films stored under a range of relative humidities. The plasticizer type did not affect significantly (p ≤ 0.05) the equilibrium moisture content of films, except at 90% relative humidity (RH). Films without plasticizer adsorbed less water and showed higher WVP than plasticized ones, indicating the antiplasticizing effect observed in this work. In general, a decrease in stress at break and Young's modulus and an increase in strain at break were observed when RH increased in all film formulations. Films without plasticizer showed higher stress at break values than the plasticized ones and presented stable strain at break under a range of RH. Sucrose films were the most fragile at low RH while glycerol films were the most hygroscopic.Fil: Galdeano, Melícia Cíntia. Universidade Estadual de Londrina; BrasilFil: Mali, Suzana. Universidade Estadual de Londrina; BrasilFil: Grossmann, Maria Victória E.. Universidade Estadual de Londrina; BrasilFil: Yamashita, Fábio. Universidade Estadual de Londrina; BrasilFil: Garcia, Maria Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaElsevier Science2009-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/161799Galdeano, Melícia Cíntia; Mali, Suzana; Grossmann, Maria Victória E.; Yamashita, Fábio; Garcia, Maria Alejandra; Effects of plasticizers on the properties of oat starch films; Elsevier Science; Materials Science and Engineering: C; 29; 2; 3-2009; 532-5380928-49311873-0191CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0928493108002737info:eu-repo/semantics/altIdentifier/doi/10.1016/j.msec.2008.09.034info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:58:44Zoai:ri.conicet.gov.ar:11336/161799instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:58:44.918CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effects of plasticizers on the properties of oat starch films
title Effects of plasticizers on the properties of oat starch films
spellingShingle Effects of plasticizers on the properties of oat starch films
Galdeano, Melícia Cíntia
BIODEGRADABLE PACKAGING
MICROSTRUCTURE AND MECHANICAL PROPERTIES
title_short Effects of plasticizers on the properties of oat starch films
title_full Effects of plasticizers on the properties of oat starch films
title_fullStr Effects of plasticizers on the properties of oat starch films
title_full_unstemmed Effects of plasticizers on the properties of oat starch films
title_sort Effects of plasticizers on the properties of oat starch films
dc.creator.none.fl_str_mv Galdeano, Melícia Cíntia
Mali, Suzana
Grossmann, Maria Victória E.
Yamashita, Fábio
Garcia, Maria Alejandra
author Galdeano, Melícia Cíntia
author_facet Galdeano, Melícia Cíntia
Mali, Suzana
Grossmann, Maria Victória E.
Yamashita, Fábio
Garcia, Maria Alejandra
author_role author
author2 Mali, Suzana
Grossmann, Maria Victória E.
Yamashita, Fábio
Garcia, Maria Alejandra
author2_role author
author
author
author
dc.subject.none.fl_str_mv BIODEGRADABLE PACKAGING
MICROSTRUCTURE AND MECHANICAL PROPERTIES
topic BIODEGRADABLE PACKAGING
MICROSTRUCTURE AND MECHANICAL PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Oat starch films were prepared by casting using glycerol, sorbitol, glycerol-sorbitol mixture, urea and sucrose as plasticizers. The effects of these plasticizers on the microstructure, moisture sorption, water vapor permeability (WVP) and mechanical properties were investigated using films stored under a range of relative humidities. The plasticizer type did not affect significantly (p ≤ 0.05) the equilibrium moisture content of films, except at 90% relative humidity (RH). Films without plasticizer adsorbed less water and showed higher WVP than plasticized ones, indicating the antiplasticizing effect observed in this work. In general, a decrease in stress at break and Young's modulus and an increase in strain at break were observed when RH increased in all film formulations. Films without plasticizer showed higher stress at break values than the plasticized ones and presented stable strain at break under a range of RH. Sucrose films were the most fragile at low RH while glycerol films were the most hygroscopic.
Fil: Galdeano, Melícia Cíntia. Universidade Estadual de Londrina; Brasil
Fil: Mali, Suzana. Universidade Estadual de Londrina; Brasil
Fil: Grossmann, Maria Victória E.. Universidade Estadual de Londrina; Brasil
Fil: Yamashita, Fábio. Universidade Estadual de Londrina; Brasil
Fil: Garcia, Maria Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
description Oat starch films were prepared by casting using glycerol, sorbitol, glycerol-sorbitol mixture, urea and sucrose as plasticizers. The effects of these plasticizers on the microstructure, moisture sorption, water vapor permeability (WVP) and mechanical properties were investigated using films stored under a range of relative humidities. The plasticizer type did not affect significantly (p ≤ 0.05) the equilibrium moisture content of films, except at 90% relative humidity (RH). Films without plasticizer adsorbed less water and showed higher WVP than plasticized ones, indicating the antiplasticizing effect observed in this work. In general, a decrease in stress at break and Young's modulus and an increase in strain at break were observed when RH increased in all film formulations. Films without plasticizer showed higher stress at break values than the plasticized ones and presented stable strain at break under a range of RH. Sucrose films were the most fragile at low RH while glycerol films were the most hygroscopic.
publishDate 2009
dc.date.none.fl_str_mv 2009-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/161799
Galdeano, Melícia Cíntia; Mali, Suzana; Grossmann, Maria Victória E.; Yamashita, Fábio; Garcia, Maria Alejandra; Effects of plasticizers on the properties of oat starch films; Elsevier Science; Materials Science and Engineering: C; 29; 2; 3-2009; 532-538
0928-4931
1873-0191
CONICET Digital
CONICET
url http://hdl.handle.net/11336/161799
identifier_str_mv Galdeano, Melícia Cíntia; Mali, Suzana; Grossmann, Maria Victória E.; Yamashita, Fábio; Garcia, Maria Alejandra; Effects of plasticizers on the properties of oat starch films; Elsevier Science; Materials Science and Engineering: C; 29; 2; 3-2009; 532-538
0928-4931
1873-0191
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0928493108002737
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.msec.2008.09.034
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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