A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)

Autores
Passeggi, Mario Cesar Guillermo; Prieto, J.E.; Miranda, R.; Gallego, J.M.
Año de publicación
2000
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report a scanning tunnelling microscopy study of the growth of iron on Cu(111) using lead as a surfactant. In the absence of surfactant, the growth of iron on Cu(111) proceeds in the form of three-dimensional islands, giving rise to an irregular granular film, with the presence of both face-centred cubic (fcc) and body-centred cubic crystallites whose relative population depends on the film thickness. The deposition of iron is accompanied by an active etching process, which results in chemical heterogeneity of the islands and the appearance of vacancy islands in the substrate surface. On the contrary, during the growth of iron on Pb/Cu(111): (1) the reaction at the interface is considerably limited, producing initially an almost perfect two-dimensional bilayer; (2) the subsequent growth results in a multi-level rough film due to limited interlayer mass transport; and (3) the iron film, continuous and monocrystalline, has the fcc structure as suggested by the persistence of a (4 ×4) lead superstructure present on the top surface layer up to at least six monolayers.
Fil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Prieto, J.E.. Universidad Autónoma de Madrid; España
Fil: Miranda, R.. Universidad Autónoma de Madrid; España
Fil: Gallego, J.M.. Instituto de Ciencia de Materiales de Madrid; España
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/27764

id CONICETDig_8cf2a56c034674cc055f7dbc036c3266
oai_identifier_str oai:ri.conicet.gov.ar:11336/27764
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)Passeggi, Mario Cesar GuillermoPrieto, J.E.Miranda, R.Gallego, J.M.https://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1We report a scanning tunnelling microscopy study of the growth of iron on Cu(111) using lead as a surfactant. In the absence of surfactant, the growth of iron on Cu(111) proceeds in the form of three-dimensional islands, giving rise to an irregular granular film, with the presence of both face-centred cubic (fcc) and body-centred cubic crystallites whose relative population depends on the film thickness. The deposition of iron is accompanied by an active etching process, which results in chemical heterogeneity of the islands and the appearance of vacancy islands in the substrate surface. On the contrary, during the growth of iron on Pb/Cu(111): (1) the reaction at the interface is considerably limited, producing initially an almost perfect two-dimensional bilayer; (2) the subsequent growth results in a multi-level rough film due to limited interlayer mass transport; and (3) the iron film, continuous and monocrystalline, has the fcc structure as suggested by the persistence of a (4 ×4) lead superstructure present on the top surface layer up to at least six monolayers.Fil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Prieto, J.E.. Universidad Autónoma de Madrid; EspañaFil: Miranda, R.. Universidad Autónoma de Madrid; EspañaFil: Gallego, J.M.. Instituto de Ciencia de Materiales de Madrid; EspañaElsevier Science2000-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/27764Passeggi, Mario Cesar Guillermo; Prieto, J.E.; Miranda, R.; Gallego, J.M.; A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111); Elsevier Science; Surface Science; 462; 1-3; 8-2000; 45-540039-6028CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/S0039-6028(00)00460-Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-29T11:47:39Zoai:ri.conicet.gov.ar:11336/27764instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-29 11:47:40.293CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)
title A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)
spellingShingle A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)
Passeggi, Mario Cesar Guillermo
title_short A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)
title_full A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)
title_fullStr A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)
title_full_unstemmed A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)
title_sort A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111)
dc.creator.none.fl_str_mv Passeggi, Mario Cesar Guillermo
Prieto, J.E.
Miranda, R.
Gallego, J.M.
author Passeggi, Mario Cesar Guillermo
author_facet Passeggi, Mario Cesar Guillermo
Prieto, J.E.
Miranda, R.
Gallego, J.M.
author_role author
author2 Prieto, J.E.
Miranda, R.
Gallego, J.M.
author2_role author
author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report a scanning tunnelling microscopy study of the growth of iron on Cu(111) using lead as a surfactant. In the absence of surfactant, the growth of iron on Cu(111) proceeds in the form of three-dimensional islands, giving rise to an irregular granular film, with the presence of both face-centred cubic (fcc) and body-centred cubic crystallites whose relative population depends on the film thickness. The deposition of iron is accompanied by an active etching process, which results in chemical heterogeneity of the islands and the appearance of vacancy islands in the substrate surface. On the contrary, during the growth of iron on Pb/Cu(111): (1) the reaction at the interface is considerably limited, producing initially an almost perfect two-dimensional bilayer; (2) the subsequent growth results in a multi-level rough film due to limited interlayer mass transport; and (3) the iron film, continuous and monocrystalline, has the fcc structure as suggested by the persistence of a (4 ×4) lead superstructure present on the top surface layer up to at least six monolayers.
Fil: Passeggi, Mario Cesar Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Prieto, J.E.. Universidad Autónoma de Madrid; España
Fil: Miranda, R.. Universidad Autónoma de Madrid; España
Fil: Gallego, J.M.. Instituto de Ciencia de Materiales de Madrid; España
description We report a scanning tunnelling microscopy study of the growth of iron on Cu(111) using lead as a surfactant. In the absence of surfactant, the growth of iron on Cu(111) proceeds in the form of three-dimensional islands, giving rise to an irregular granular film, with the presence of both face-centred cubic (fcc) and body-centred cubic crystallites whose relative population depends on the film thickness. The deposition of iron is accompanied by an active etching process, which results in chemical heterogeneity of the islands and the appearance of vacancy islands in the substrate surface. On the contrary, during the growth of iron on Pb/Cu(111): (1) the reaction at the interface is considerably limited, producing initially an almost perfect two-dimensional bilayer; (2) the subsequent growth results in a multi-level rough film due to limited interlayer mass transport; and (3) the iron film, continuous and monocrystalline, has the fcc structure as suggested by the persistence of a (4 ×4) lead superstructure present on the top surface layer up to at least six monolayers.
publishDate 2000
dc.date.none.fl_str_mv 2000-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/27764
Passeggi, Mario Cesar Guillermo; Prieto, J.E.; Miranda, R.; Gallego, J.M.; A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111); Elsevier Science; Surface Science; 462; 1-3; 8-2000; 45-54
0039-6028
CONICET Digital
CONICET
url http://hdl.handle.net/11336/27764
identifier_str_mv Passeggi, Mario Cesar Guillermo; Prieto, J.E.; Miranda, R.; Gallego, J.M.; A scanning tunnelling microscopy view of the surfactant-assisted growth of iron on Cu(111); Elsevier Science; Surface Science; 462; 1-3; 8-2000; 45-54
0039-6028
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/S0039-6028(00)00460-X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1847426481707286528
score 13.10058