Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent

Autores
Ninago, Mario Daniel; Ciolino, Andrés Eduardo; Villar, Marcelo Armando; Giacomelli, Fernando C.; Cernoch, Petr; Stepánek, Petr; Schmidt, Vanesa; Giacomelli, Cristiano
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The synthesis of poly(styrene)-block-poly(dimethylsiloxane) (PS-b-PDMS) copolymers through sequential anionic polymerization, and their self-assembly behavior in bulk (thin films) and in solution (nanoparticles) is herein reported. The results obtained in bulk showed the formation of original island-type nanostructures with periodic separation and uniform height for thin films prepared by spin coating on silicon substrates followed by thermo- or solvent annealing, as evidenced by atomic force microscopy (AFM). In selective solvent (dimethylformamide), micellar core (PDMS) - shell (PS) nanoparticles originated upon direct dissolution, and the corresponding structure was determined in details by combining static and dynamic light scattering (SDLS) measurements.
Fil: Ninago, Mario Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Giacomelli, Fernando C.. Insitute of Macromolecular Chemistry; República Checa
Fil: Cernoch, Petr. Insitute of Macromolecular Chemistry; República Checa
Fil: Stepánek, Petr. Insitute of Macromolecular Chemistry; República Checa
Fil: Schmidt, Vanesa. Universidade de Caxias do Sul; Brasil
Fil: Giacomelli, Cristiano. Centro de Ciências Exatas E Tecnologia; Brasil
Materia
model block copolymers
self-assembly
solution properties
nanoorganization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/43274
Acceder
id CONICETDig_8ce31ddb124eba55d888a2b4a1c65669
oai_identifier_str oai:ri.conicet.gov.ar:11336/43274
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective SolventNinago, Mario DanielCiolino, Andrés EduardoVillar, Marcelo ArmandoGiacomelli, Fernando C.Cernoch, PetrStepánek, PetrSchmidt, VanesaGiacomelli, Cristianomodel block copolymersself-assemblysolution propertiesnanoorganizationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The synthesis of poly(styrene)-block-poly(dimethylsiloxane) (PS-b-PDMS) copolymers through sequential anionic polymerization, and their self-assembly behavior in bulk (thin films) and in solution (nanoparticles) is herein reported. The results obtained in bulk showed the formation of original island-type nanostructures with periodic separation and uniform height for thin films prepared by spin coating on silicon substrates followed by thermo- or solvent annealing, as evidenced by atomic force microscopy (AFM). In selective solvent (dimethylformamide), micellar core (PDMS) - shell (PS) nanoparticles originated upon direct dissolution, and the corresponding structure was determined in details by combining static and dynamic light scattering (SDLS) measurements.Fil: Ninago, Mario Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Giacomelli, Fernando C.. Insitute of Macromolecular Chemistry; República ChecaFil: Cernoch, Petr. Insitute of Macromolecular Chemistry; República ChecaFil: Stepánek, Petr. Insitute of Macromolecular Chemistry; República ChecaFil: Schmidt, Vanesa. Universidade de Caxias do Sul; BrasilFil: Giacomelli, Cristiano. Centro de Ciências Exatas E Tecnologia; BrasilAssociacione Italiana de Ingegneria Chimica2009-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/43274Ninago, Mario Daniel; Ciolino, Andrés Eduardo; Villar, Marcelo Armando; Giacomelli, Fernando C.; Cernoch, Petr; et al.; Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent; Associacione Italiana de Ingegneria Chimica; Chemical Engineering Transactions; 17; 5-2009; 1807-1812978-88-95606-01-31974-9791CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.3303/CET0917302info:eu-repo/semantics/altIdentifier/url/http://www.aidic.it/cet/09/17/302.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:45Zoai:ri.conicet.gov.ar:11336/43274instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:46.037CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent
title Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent
spellingShingle Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent
Ninago, Mario Daniel
model block copolymers
self-assembly
solution properties
nanoorganization
title_short Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent
title_full Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent
title_fullStr Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent
title_full_unstemmed Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent
title_sort Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent
dc.creator.none.fl_str_mv Ninago, Mario Daniel
Ciolino, Andrés Eduardo
Villar, Marcelo Armando
Giacomelli, Fernando C.
Cernoch, Petr
Stepánek, Petr
Schmidt, Vanesa
Giacomelli, Cristiano
author Ninago, Mario Daniel
author_facet Ninago, Mario Daniel
Ciolino, Andrés Eduardo
Villar, Marcelo Armando
Giacomelli, Fernando C.
Cernoch, Petr
Stepánek, Petr
Schmidt, Vanesa
Giacomelli, Cristiano
author_role author
author2 Ciolino, Andrés Eduardo
Villar, Marcelo Armando
Giacomelli, Fernando C.
Cernoch, Petr
Stepánek, Petr
Schmidt, Vanesa
Giacomelli, Cristiano
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv model block copolymers
self-assembly
solution properties
nanoorganization
topic model block copolymers
self-assembly
solution properties
nanoorganization
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The synthesis of poly(styrene)-block-poly(dimethylsiloxane) (PS-b-PDMS) copolymers through sequential anionic polymerization, and their self-assembly behavior in bulk (thin films) and in solution (nanoparticles) is herein reported. The results obtained in bulk showed the formation of original island-type nanostructures with periodic separation and uniform height for thin films prepared by spin coating on silicon substrates followed by thermo- or solvent annealing, as evidenced by atomic force microscopy (AFM). In selective solvent (dimethylformamide), micellar core (PDMS) - shell (PS) nanoparticles originated upon direct dissolution, and the corresponding structure was determined in details by combining static and dynamic light scattering (SDLS) measurements.
Fil: Ninago, Mario Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Giacomelli, Fernando C.. Insitute of Macromolecular Chemistry; República Checa
Fil: Cernoch, Petr. Insitute of Macromolecular Chemistry; República Checa
Fil: Stepánek, Petr. Insitute of Macromolecular Chemistry; República Checa
Fil: Schmidt, Vanesa. Universidade de Caxias do Sul; Brasil
Fil: Giacomelli, Cristiano. Centro de Ciências Exatas E Tecnologia; Brasil
description The synthesis of poly(styrene)-block-poly(dimethylsiloxane) (PS-b-PDMS) copolymers through sequential anionic polymerization, and their self-assembly behavior in bulk (thin films) and in solution (nanoparticles) is herein reported. The results obtained in bulk showed the formation of original island-type nanostructures with periodic separation and uniform height for thin films prepared by spin coating on silicon substrates followed by thermo- or solvent annealing, as evidenced by atomic force microscopy (AFM). In selective solvent (dimethylformamide), micellar core (PDMS) - shell (PS) nanoparticles originated upon direct dissolution, and the corresponding structure was determined in details by combining static and dynamic light scattering (SDLS) measurements.
publishDate 2009
dc.date.none.fl_str_mv 2009-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/43274
Ninago, Mario Daniel; Ciolino, Andrés Eduardo; Villar, Marcelo Armando; Giacomelli, Fernando C.; Cernoch, Petr; et al.; Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent; Associacione Italiana de Ingegneria Chimica; Chemical Engineering Transactions; 17; 5-2009; 1807-1812
978-88-95606-01-3
1974-9791
CONICET Digital
CONICET
url http://hdl.handle.net/11336/43274
identifier_str_mv Ninago, Mario Daniel; Ciolino, Andrés Eduardo; Villar, Marcelo Armando; Giacomelli, Fernando C.; Cernoch, Petr; et al.; Self-Assembly of Well Defined PS-b-PDMS Copolymers in Bulk and in Selective Solvent; Associacione Italiana de Ingegneria Chimica; Chemical Engineering Transactions; 17; 5-2009; 1807-1812
978-88-95606-01-3
1974-9791
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3303/CET0917302
info:eu-repo/semantics/altIdentifier/url/http://www.aidic.it/cet/09/17/302.pdf
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Associacione Italiana de Ingegneria Chimica
publisher.none.fl_str_mv Associacione Italiana de Ingegneria Chimica
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269365094842368
score 13.13397

Publicaciones similares