Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries

Autores
Borlaf, Mario; Picchio, Matías Luis; Luque, Gisela Carina; Criado Gonzalez, Miryam; Guzmán Gonzalez, Gregorio; Pérez Antolin, Daniel; Lingua, Gabriele; Mecerreyes, David; Ventosa, Edgar
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The development of new battery concepts, chemistries and fabrication processesis driven by the bloom of emerging applications in a variety of fields ranging fromthe Internet of Things to Smart Healthcare. Shape factor-free and shapeconformablepower sources are highly desired for integration with complex-shapeelectronic devices. Herein, a new fabrication process for shape-conformablebatteries is explored. Battery cells having targeted shapes are fabricated andassisted by 3D printing. Then, flowable semi-solid electrodes are used to fill inthe prefabricated parts of the battery cell. The use of injectable hydrogelelectrolytes enables semi-solid electrodes to possess special rheologicalproperties as they are flowable during fabrication process, while gelation of theelectrolytes ensures their immobility during battery operation. Herein, poly(vinylalcohol) : gallic acid gels are investigated for aqueous Zn – LiFePO4 batteries.After evaluation of the effect of electrode formulation in the rheological propertiesas well as the ionic and electronic properties, simple-shape and UBU-shapebatteries were fabricated using the best formulation. The prototype achievedareal capacities above 3 mAh cm-2, utilization rate between 150 and 180 mAh g-1 (LFP), and capacity fading of 0.2 % h-1. While the prototype demonstrated thefeasibility of the proposed fabrication process, improvements are still required.Shrinking of gel electrolytes and parasitic electrochemical reactions associatedwith the battery chemistry and the operation conditions are identified as the mainchallenges to be addressed for improving the performances.
Fil: Borlaf, Mario. Universidad de Burgos. Departamento de Didácticas Específicas; España
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Luque, Gisela Carina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Criado Gonzalez, Miryam. Universidad del Pais Vasco. Polymat.; España
Fil: Guzmán Gonzalez, Gregorio. Universidad del Pais Vasco. Polymat.; España
Fil: Pérez Antolin, Daniel. Universidad de Burgos. Departamento de Didácticas Específicas; España
Fil: Lingua, Gabriele. Universidad del Pais Vasco. Polymat.; España
Fil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; España
Fil: Ventosa, Edgar. Universidad de Burgos. Departamento de Didácticas Específicas; España
Materia
zinc batteries
inyectable hydrogels
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/245548
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/245548
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteriesBorlaf, MarioPicchio, Matías LuisLuque, Gisela CarinaCriado Gonzalez, MiryamGuzmán Gonzalez, GregorioPérez Antolin, DanielLingua, GabrieleMecerreyes, DavidVentosa, Edgarzinc batteriesinyectable hydrogelshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The development of new battery concepts, chemistries and fabrication processesis driven by the bloom of emerging applications in a variety of fields ranging fromthe Internet of Things to Smart Healthcare. Shape factor-free and shapeconformablepower sources are highly desired for integration with complex-shapeelectronic devices. Herein, a new fabrication process for shape-conformablebatteries is explored. Battery cells having targeted shapes are fabricated andassisted by 3D printing. Then, flowable semi-solid electrodes are used to fill inthe prefabricated parts of the battery cell. The use of injectable hydrogelelectrolytes enables semi-solid electrodes to possess special rheologicalproperties as they are flowable during fabrication process, while gelation of theelectrolytes ensures their immobility during battery operation. Herein, poly(vinylalcohol) : gallic acid gels are investigated for aqueous Zn – LiFePO4 batteries.After evaluation of the effect of electrode formulation in the rheological propertiesas well as the ionic and electronic properties, simple-shape and UBU-shapebatteries were fabricated using the best formulation. The prototype achievedareal capacities above 3 mAh cm-2, utilization rate between 150 and 180 mAh g-1 (LFP), and capacity fading of 0.2 % h-1. While the prototype demonstrated thefeasibility of the proposed fabrication process, improvements are still required.Shrinking of gel electrolytes and parasitic electrochemical reactions associatedwith the battery chemistry and the operation conditions are identified as the mainchallenges to be addressed for improving the performances.Fil: Borlaf, Mario. Universidad de Burgos. Departamento de Didácticas Específicas; EspañaFil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Luque, Gisela Carina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Criado Gonzalez, Miryam. Universidad del Pais Vasco. Polymat.; EspañaFil: Guzmán Gonzalez, Gregorio. Universidad del Pais Vasco. Polymat.; EspañaFil: Pérez Antolin, Daniel. Universidad de Burgos. Departamento de Didácticas Específicas; EspañaFil: Lingua, Gabriele. Universidad del Pais Vasco. Polymat.; EspañaFil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; EspañaFil: Ventosa, Edgar. Universidad de Burgos. Departamento de Didácticas Específicas; EspañaRoyal Society of Chemistry2023-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/245548Borlaf, Mario; Picchio, Matías Luis; Luque, Gisela Carina; Criado Gonzalez, Miryam; Guzmán Gonzalez, Gregorio; et al.; Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries; Royal Society of Chemistry; Energy Advances; 2; 11; 9-2023; 1872-18812753-1457CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2023/ya/d3ya00333ginfo:eu-repo/semantics/altIdentifier/doi/10.1039/D3YA00333Ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:24:09Zoai:ri.conicet.gov.ar:11336/245548instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:24:09.531CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
title Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
spellingShingle Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
Borlaf, Mario
zinc batteries
inyectable hydrogels
title_short Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
title_full Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
title_fullStr Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
title_full_unstemmed Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
title_sort Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
dc.creator.none.fl_str_mv Borlaf, Mario
Picchio, Matías Luis
Luque, Gisela Carina
Criado Gonzalez, Miryam
Guzmán Gonzalez, Gregorio
Pérez Antolin, Daniel
Lingua, Gabriele
Mecerreyes, David
Ventosa, Edgar
author Borlaf, Mario
author_facet Borlaf, Mario
Picchio, Matías Luis
Luque, Gisela Carina
Criado Gonzalez, Miryam
Guzmán Gonzalez, Gregorio
Pérez Antolin, Daniel
Lingua, Gabriele
Mecerreyes, David
Ventosa, Edgar
author_role author
author2 Picchio, Matías Luis
Luque, Gisela Carina
Criado Gonzalez, Miryam
Guzmán Gonzalez, Gregorio
Pérez Antolin, Daniel
Lingua, Gabriele
Mecerreyes, David
Ventosa, Edgar
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv zinc batteries
inyectable hydrogels
topic zinc batteries
inyectable hydrogels
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The development of new battery concepts, chemistries and fabrication processesis driven by the bloom of emerging applications in a variety of fields ranging fromthe Internet of Things to Smart Healthcare. Shape factor-free and shapeconformablepower sources are highly desired for integration with complex-shapeelectronic devices. Herein, a new fabrication process for shape-conformablebatteries is explored. Battery cells having targeted shapes are fabricated andassisted by 3D printing. Then, flowable semi-solid electrodes are used to fill inthe prefabricated parts of the battery cell. The use of injectable hydrogelelectrolytes enables semi-solid electrodes to possess special rheologicalproperties as they are flowable during fabrication process, while gelation of theelectrolytes ensures their immobility during battery operation. Herein, poly(vinylalcohol) : gallic acid gels are investigated for aqueous Zn – LiFePO4 batteries.After evaluation of the effect of electrode formulation in the rheological propertiesas well as the ionic and electronic properties, simple-shape and UBU-shapebatteries were fabricated using the best formulation. The prototype achievedareal capacities above 3 mAh cm-2, utilization rate between 150 and 180 mAh g-1 (LFP), and capacity fading of 0.2 % h-1. While the prototype demonstrated thefeasibility of the proposed fabrication process, improvements are still required.Shrinking of gel electrolytes and parasitic electrochemical reactions associatedwith the battery chemistry and the operation conditions are identified as the mainchallenges to be addressed for improving the performances.
Fil: Borlaf, Mario. Universidad de Burgos. Departamento de Didácticas Específicas; España
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Luque, Gisela Carina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Criado Gonzalez, Miryam. Universidad del Pais Vasco. Polymat.; España
Fil: Guzmán Gonzalez, Gregorio. Universidad del Pais Vasco. Polymat.; España
Fil: Pérez Antolin, Daniel. Universidad de Burgos. Departamento de Didácticas Específicas; España
Fil: Lingua, Gabriele. Universidad del Pais Vasco. Polymat.; España
Fil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; España
Fil: Ventosa, Edgar. Universidad de Burgos. Departamento de Didácticas Específicas; España
description The development of new battery concepts, chemistries and fabrication processesis driven by the bloom of emerging applications in a variety of fields ranging fromthe Internet of Things to Smart Healthcare. Shape factor-free and shapeconformablepower sources are highly desired for integration with complex-shapeelectronic devices. Herein, a new fabrication process for shape-conformablebatteries is explored. Battery cells having targeted shapes are fabricated andassisted by 3D printing. Then, flowable semi-solid electrodes are used to fill inthe prefabricated parts of the battery cell. The use of injectable hydrogelelectrolytes enables semi-solid electrodes to possess special rheologicalproperties as they are flowable during fabrication process, while gelation of theelectrolytes ensures their immobility during battery operation. Herein, poly(vinylalcohol) : gallic acid gels are investigated for aqueous Zn – LiFePO4 batteries.After evaluation of the effect of electrode formulation in the rheological propertiesas well as the ionic and electronic properties, simple-shape and UBU-shapebatteries were fabricated using the best formulation. The prototype achievedareal capacities above 3 mAh cm-2, utilization rate between 150 and 180 mAh g-1 (LFP), and capacity fading of 0.2 % h-1. While the prototype demonstrated thefeasibility of the proposed fabrication process, improvements are still required.Shrinking of gel electrolytes and parasitic electrochemical reactions associatedwith the battery chemistry and the operation conditions are identified as the mainchallenges to be addressed for improving the performances.
publishDate 2023
dc.date.none.fl_str_mv 2023-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/245548
Borlaf, Mario; Picchio, Matías Luis; Luque, Gisela Carina; Criado Gonzalez, Miryam; Guzmán Gonzalez, Gregorio; et al.; Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries; Royal Society of Chemistry; Energy Advances; 2; 11; 9-2023; 1872-1881
2753-1457
CONICET Digital
CONICET
url http://hdl.handle.net/11336/245548
identifier_str_mv Borlaf, Mario; Picchio, Matías Luis; Luque, Gisela Carina; Criado Gonzalez, Miryam; Guzmán Gonzalez, Gregorio; et al.; Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries; Royal Society of Chemistry; Energy Advances; 2; 11; 9-2023; 1872-1881
2753-1457
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2023/ya/d3ya00333g
info:eu-repo/semantics/altIdentifier/doi/10.1039/D3YA00333G
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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