Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries
- Autores
- Borlaf, Mario; Picchio, Matías Luis; Luque, Gisela Carina; Criado Gonzalez, Miryam; Guzmán Gonzalez, Gregorio; Pérez Antolin, Daniel; Lingua, Gabriele; Mecerreyes, David; Ventosa, Edgar
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The development of new battery concepts, chemistries and fabrication processesis driven by the bloom of emerging applications in a variety of fields ranging fromthe Internet of Things to Smart Healthcare. Shape factor-free and shapeconformablepower sources are highly desired for integration with complex-shapeelectronic devices. Herein, a new fabrication process for shape-conformablebatteries is explored. Battery cells having targeted shapes are fabricated andassisted by 3D printing. Then, flowable semi-solid electrodes are used to fill inthe prefabricated parts of the battery cell. The use of injectable hydrogelelectrolytes enables semi-solid electrodes to possess special rheologicalproperties as they are flowable during fabrication process, while gelation of theelectrolytes ensures their immobility during battery operation. Herein, poly(vinylalcohol) : gallic acid gels are investigated for aqueous Zn – LiFePO4 batteries.After evaluation of the effect of electrode formulation in the rheological propertiesas well as the ionic and electronic properties, simple-shape and UBU-shapebatteries were fabricated using the best formulation. The prototype achievedareal capacities above 3 mAh cm-2, utilization rate between 150 and 180 mAh g-1 (LFP), and capacity fading of 0.2 % h-1. While the prototype demonstrated thefeasibility of the proposed fabrication process, improvements are still required.Shrinking of gel electrolytes and parasitic electrochemical reactions associatedwith the battery chemistry and the operation conditions are identified as the mainchallenges to be addressed for improving the performances.
Fil: Borlaf, Mario. Universidad de Burgos. Departamento de Didácticas Específicas; España
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Luque, Gisela Carina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Criado Gonzalez, Miryam. Universidad del Pais Vasco. Polymat.; España
Fil: Guzmán Gonzalez, Gregorio. Universidad del Pais Vasco. Polymat.; España
Fil: Pérez Antolin, Daniel. Universidad de Burgos. Departamento de Didácticas Específicas; España
Fil: Lingua, Gabriele. Universidad del Pais Vasco. Polymat.; España
Fil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; España
Fil: Ventosa, Edgar. Universidad de Burgos. Departamento de Didácticas Específicas; España - Materia
-
zinc batteries
inyectable hydrogels - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/245548
Ver los metadatos del registro completo
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Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteriesBorlaf, MarioPicchio, Matías LuisLuque, Gisela CarinaCriado Gonzalez, MiryamGuzmán Gonzalez, GregorioPérez Antolin, DanielLingua, GabrieleMecerreyes, DavidVentosa, Edgarzinc batteriesinyectable hydrogelshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The development of new battery concepts, chemistries and fabrication processesis driven by the bloom of emerging applications in a variety of fields ranging fromthe Internet of Things to Smart Healthcare. Shape factor-free and shapeconformablepower sources are highly desired for integration with complex-shapeelectronic devices. Herein, a new fabrication process for shape-conformablebatteries is explored. Battery cells having targeted shapes are fabricated andassisted by 3D printing. Then, flowable semi-solid electrodes are used to fill inthe prefabricated parts of the battery cell. The use of injectable hydrogelelectrolytes enables semi-solid electrodes to possess special rheologicalproperties as they are flowable during fabrication process, while gelation of theelectrolytes ensures their immobility during battery operation. Herein, poly(vinylalcohol) : gallic acid gels are investigated for aqueous Zn – LiFePO4 batteries.After evaluation of the effect of electrode formulation in the rheological propertiesas well as the ionic and electronic properties, simple-shape and UBU-shapebatteries were fabricated using the best formulation. The prototype achievedareal capacities above 3 mAh cm-2, utilization rate between 150 and 180 mAh g-1 (LFP), and capacity fading of 0.2 % h-1. While the prototype demonstrated thefeasibility of the proposed fabrication process, improvements are still required.Shrinking of gel electrolytes and parasitic electrochemical reactions associatedwith the battery chemistry and the operation conditions are identified as the mainchallenges to be addressed for improving the performances.Fil: Borlaf, Mario. Universidad de Burgos. Departamento de Didácticas Específicas; EspañaFil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Luque, Gisela Carina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Criado Gonzalez, Miryam. Universidad del Pais Vasco. Polymat.; EspañaFil: Guzmán Gonzalez, Gregorio. Universidad del Pais Vasco. Polymat.; EspañaFil: Pérez Antolin, Daniel. Universidad de Burgos. Departamento de Didácticas Específicas; EspañaFil: Lingua, Gabriele. Universidad del Pais Vasco. Polymat.; EspañaFil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; EspañaFil: Ventosa, Edgar. Universidad de Burgos. Departamento de Didácticas Específicas; EspañaRoyal Society of Chemistry2023-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/245548Borlaf, Mario; Picchio, Matías Luis; Luque, Gisela Carina; Criado Gonzalez, Miryam; Guzmán Gonzalez, Gregorio; et al.; Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries; Royal Society of Chemistry; Energy Advances; 2; 11; 9-2023; 1872-18812753-1457CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2023/ya/d3ya00333ginfo:eu-repo/semantics/altIdentifier/doi/10.1039/D3YA00333Ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:36Zoai:ri.conicet.gov.ar:11336/245548instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:37.111CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries |
title |
Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries |
spellingShingle |
Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries Borlaf, Mario zinc batteries inyectable hydrogels |
title_short |
Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries |
title_full |
Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries |
title_fullStr |
Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries |
title_full_unstemmed |
Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries |
title_sort |
Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries |
dc.creator.none.fl_str_mv |
Borlaf, Mario Picchio, Matías Luis Luque, Gisela Carina Criado Gonzalez, Miryam Guzmán Gonzalez, Gregorio Pérez Antolin, Daniel Lingua, Gabriele Mecerreyes, David Ventosa, Edgar |
author |
Borlaf, Mario |
author_facet |
Borlaf, Mario Picchio, Matías Luis Luque, Gisela Carina Criado Gonzalez, Miryam Guzmán Gonzalez, Gregorio Pérez Antolin, Daniel Lingua, Gabriele Mecerreyes, David Ventosa, Edgar |
author_role |
author |
author2 |
Picchio, Matías Luis Luque, Gisela Carina Criado Gonzalez, Miryam Guzmán Gonzalez, Gregorio Pérez Antolin, Daniel Lingua, Gabriele Mecerreyes, David Ventosa, Edgar |
author2_role |
author author author author author author author author |
dc.subject.none.fl_str_mv |
zinc batteries inyectable hydrogels |
topic |
zinc batteries inyectable hydrogels |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The development of new battery concepts, chemistries and fabrication processesis driven by the bloom of emerging applications in a variety of fields ranging fromthe Internet of Things to Smart Healthcare. Shape factor-free and shapeconformablepower sources are highly desired for integration with complex-shapeelectronic devices. Herein, a new fabrication process for shape-conformablebatteries is explored. Battery cells having targeted shapes are fabricated andassisted by 3D printing. Then, flowable semi-solid electrodes are used to fill inthe prefabricated parts of the battery cell. The use of injectable hydrogelelectrolytes enables semi-solid electrodes to possess special rheologicalproperties as they are flowable during fabrication process, while gelation of theelectrolytes ensures their immobility during battery operation. Herein, poly(vinylalcohol) : gallic acid gels are investigated for aqueous Zn – LiFePO4 batteries.After evaluation of the effect of electrode formulation in the rheological propertiesas well as the ionic and electronic properties, simple-shape and UBU-shapebatteries were fabricated using the best formulation. The prototype achievedareal capacities above 3 mAh cm-2, utilization rate between 150 and 180 mAh g-1 (LFP), and capacity fading of 0.2 % h-1. While the prototype demonstrated thefeasibility of the proposed fabrication process, improvements are still required.Shrinking of gel electrolytes and parasitic electrochemical reactions associatedwith the battery chemistry and the operation conditions are identified as the mainchallenges to be addressed for improving the performances. Fil: Borlaf, Mario. Universidad de Burgos. Departamento de Didácticas Específicas; España Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Luque, Gisela Carina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Criado Gonzalez, Miryam. Universidad del Pais Vasco. Polymat.; España Fil: Guzmán Gonzalez, Gregorio. Universidad del Pais Vasco. Polymat.; España Fil: Pérez Antolin, Daniel. Universidad de Burgos. Departamento de Didácticas Específicas; España Fil: Lingua, Gabriele. Universidad del Pais Vasco. Polymat.; España Fil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; España Fil: Ventosa, Edgar. Universidad de Burgos. Departamento de Didácticas Específicas; España |
description |
The development of new battery concepts, chemistries and fabrication processesis driven by the bloom of emerging applications in a variety of fields ranging fromthe Internet of Things to Smart Healthcare. Shape factor-free and shapeconformablepower sources are highly desired for integration with complex-shapeelectronic devices. Herein, a new fabrication process for shape-conformablebatteries is explored. Battery cells having targeted shapes are fabricated andassisted by 3D printing. Then, flowable semi-solid electrodes are used to fill inthe prefabricated parts of the battery cell. The use of injectable hydrogelelectrolytes enables semi-solid electrodes to possess special rheologicalproperties as they are flowable during fabrication process, while gelation of theelectrolytes ensures their immobility during battery operation. Herein, poly(vinylalcohol) : gallic acid gels are investigated for aqueous Zn – LiFePO4 batteries.After evaluation of the effect of electrode formulation in the rheological propertiesas well as the ionic and electronic properties, simple-shape and UBU-shapebatteries were fabricated using the best formulation. The prototype achievedareal capacities above 3 mAh cm-2, utilization rate between 150 and 180 mAh g-1 (LFP), and capacity fading of 0.2 % h-1. While the prototype demonstrated thefeasibility of the proposed fabrication process, improvements are still required.Shrinking of gel electrolytes and parasitic electrochemical reactions associatedwith the battery chemistry and the operation conditions are identified as the mainchallenges to be addressed for improving the performances. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/245548 Borlaf, Mario; Picchio, Matías Luis; Luque, Gisela Carina; Criado Gonzalez, Miryam; Guzmán Gonzalez, Gregorio; et al.; Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries; Royal Society of Chemistry; Energy Advances; 2; 11; 9-2023; 1872-1881 2753-1457 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/245548 |
identifier_str_mv |
Borlaf, Mario; Picchio, Matías Luis; Luque, Gisela Carina; Criado Gonzalez, Miryam; Guzmán Gonzalez, Gregorio; et al.; Semi-solid electrodes based on injectable hydrogel electrolytes for shape-conformable batteries; Royal Society of Chemistry; Energy Advances; 2; 11; 9-2023; 1872-1881 2753-1457 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2023/ya/d3ya00333g info:eu-repo/semantics/altIdentifier/doi/10.1039/D3YA00333G |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613110897311744 |
score |
13.070432 |