Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers

Autores
Casado, Ulises Martín; Aranguren, Mirta Ines; Marcovich, Norma Esther
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Conducting polyaniline (PANI) and cellulose coated PANI (PANI-NC) nanostructures with sizes of about 80–100 nm, doped with hydrochloric acid were synthesized by a sonochemical method. Both type of particles resulted electrically conductive (direct current conductivity of 0.059 and 0.075 S/cm for PANI and PANI-NC structures, respectively) and could be dispersed easily in water, leading to green colored suspensions that remain stable for more than 4 h. The morphology, crystallinity, electrical conductivity (r) and thermal stability of the obtained PANI based structures were investigated and compared. Furthermore, UV–Vis spectroscopy and rheology of water suspensions were used to explain the measured properties. Although the concentration of cellulose fibers used to synthesize the PANI-NC structures was very low, important differences respect to the neat PANI fibers regarding the microstructure, electrical conductivity and suspension behavior were found.
Fil: Casado, Ulises Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Marcovich, Norma Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Polyaniline
Nanocellulose
Conductive Nanoparticles
Stable Suspensions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/27873
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibersCasado, Ulises MartínAranguren, Mirta InesMarcovich, Norma EstherPolyanilineNanocelluloseConductive NanoparticlesStable Suspensionshttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Conducting polyaniline (PANI) and cellulose coated PANI (PANI-NC) nanostructures with sizes of about 80–100 nm, doped with hydrochloric acid were synthesized by a sonochemical method. Both type of particles resulted electrically conductive (direct current conductivity of 0.059 and 0.075 S/cm for PANI and PANI-NC structures, respectively) and could be dispersed easily in water, leading to green colored suspensions that remain stable for more than 4 h. The morphology, crystallinity, electrical conductivity (r) and thermal stability of the obtained PANI based structures were investigated and compared. Furthermore, UV–Vis spectroscopy and rheology of water suspensions were used to explain the measured properties. Although the concentration of cellulose fibers used to synthesize the PANI-NC structures was very low, important differences respect to the neat PANI fibers regarding the microstructure, electrical conductivity and suspension behavior were found.Fil: Casado, Ulises Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Marcovich, Norma Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier Science2014-03-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/27873Casado, Ulises Martín; Aranguren, Mirta Ines; Marcovich, Norma Esther; Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers; Elsevier Science; Ultrasonics Sonochemistry; 21; 5; 21-3-2014; 1641-16481350-4177CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ultsonch.2014.03.012info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1350417714001023?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:57Zoai:ri.conicet.gov.ar:11336/27873instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:57.49CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers
title Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers
spellingShingle Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers
Casado, Ulises Martín
Polyaniline
Nanocellulose
Conductive Nanoparticles
Stable Suspensions
title_short Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers
title_full Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers
title_fullStr Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers
title_full_unstemmed Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers
title_sort Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers
dc.creator.none.fl_str_mv Casado, Ulises Martín
Aranguren, Mirta Ines
Marcovich, Norma Esther
author Casado, Ulises Martín
author_facet Casado, Ulises Martín
Aranguren, Mirta Ines
Marcovich, Norma Esther
author_role author
author2 Aranguren, Mirta Ines
Marcovich, Norma Esther
author2_role author
author
dc.subject.none.fl_str_mv Polyaniline
Nanocellulose
Conductive Nanoparticles
Stable Suspensions
topic Polyaniline
Nanocellulose
Conductive Nanoparticles
Stable Suspensions
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Conducting polyaniline (PANI) and cellulose coated PANI (PANI-NC) nanostructures with sizes of about 80–100 nm, doped with hydrochloric acid were synthesized by a sonochemical method. Both type of particles resulted electrically conductive (direct current conductivity of 0.059 and 0.075 S/cm for PANI and PANI-NC structures, respectively) and could be dispersed easily in water, leading to green colored suspensions that remain stable for more than 4 h. The morphology, crystallinity, electrical conductivity (r) and thermal stability of the obtained PANI based structures were investigated and compared. Furthermore, UV–Vis spectroscopy and rheology of water suspensions were used to explain the measured properties. Although the concentration of cellulose fibers used to synthesize the PANI-NC structures was very low, important differences respect to the neat PANI fibers regarding the microstructure, electrical conductivity and suspension behavior were found.
Fil: Casado, Ulises Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Marcovich, Norma Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Conducting polyaniline (PANI) and cellulose coated PANI (PANI-NC) nanostructures with sizes of about 80–100 nm, doped with hydrochloric acid were synthesized by a sonochemical method. Both type of particles resulted electrically conductive (direct current conductivity of 0.059 and 0.075 S/cm for PANI and PANI-NC structures, respectively) and could be dispersed easily in water, leading to green colored suspensions that remain stable for more than 4 h. The morphology, crystallinity, electrical conductivity (r) and thermal stability of the obtained PANI based structures were investigated and compared. Furthermore, UV–Vis spectroscopy and rheology of water suspensions were used to explain the measured properties. Although the concentration of cellulose fibers used to synthesize the PANI-NC structures was very low, important differences respect to the neat PANI fibers regarding the microstructure, electrical conductivity and suspension behavior were found.
publishDate 2014
dc.date.none.fl_str_mv 2014-03-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/27873
Casado, Ulises Martín; Aranguren, Mirta Ines; Marcovich, Norma Esther; Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers; Elsevier Science; Ultrasonics Sonochemistry; 21; 5; 21-3-2014; 1641-1648
1350-4177
CONICET Digital
CONICET
url http://hdl.handle.net/11336/27873
identifier_str_mv Casado, Ulises Martín; Aranguren, Mirta Ines; Marcovich, Norma Esther; Preparation and characterization of conductive nanostructured particles based on polyaniline and cellulose nanofibers; Elsevier Science; Ultrasonics Sonochemistry; 21; 5; 21-3-2014; 1641-1648
1350-4177
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ultsonch.2014.03.012
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1350417714001023?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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