Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites

Autores
Perez, Ezequiel Martin; Bernal, Celina Raquel; Piacquadio, Maria Natividad
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Multifractal analyses were performed to elucidate the effect of incorporating maleic anhydride grafted polypropylene (MAPP) into a Polypropylene matrix: (i) on the dispersion of CaCO3 particles and (ii) on the fracture morphology of tensile samples. The box-counting method was applied considering the number of particles and the mean gray value distribution as measured properties of composites. The dispersion analysis exhibited, for the composite with MAPP, a reduction of larger agglomerates sizes without variation of the most frequent size. Similar results were achieved by a typical particle size distribution. Moreover, the morphology of fractured surfaces showed an irregular topography for composites without MAPP suggesting a complex fracture process. Composites with MAPP, on the contrary, displayed a regular surface morphology suggesting a more regular fracture process with an important reduction of ductile mechanisms. This fracture behavior was related to the variation of the singularity width Δα. The results obtained suggest that multifractal theory can be applied to elucidate the relationship between structure and mechanical behavior of PP–CaCO3 composite materials.
Fil: Perez, Ezequiel Martin. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Mecánica. Grupo de Materiales Avanzados; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Bernal, Celina Raquel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Mecánica. Grupo de Materiales Avanzados; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Piacquadio, Maria Natividad. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina
Materia
Multifractal Spectrum
Filler Dispersion
Mechanical Properties
Fracture Surface
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/20024

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spelling Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 compositesPerez, Ezequiel MartinBernal, Celina RaquelPiacquadio, Maria NatividadMultifractal SpectrumFiller DispersionMechanical PropertiesFracture Surfacehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Multifractal analyses were performed to elucidate the effect of incorporating maleic anhydride grafted polypropylene (MAPP) into a Polypropylene matrix: (i) on the dispersion of CaCO3 particles and (ii) on the fracture morphology of tensile samples. The box-counting method was applied considering the number of particles and the mean gray value distribution as measured properties of composites. The dispersion analysis exhibited, for the composite with MAPP, a reduction of larger agglomerates sizes without variation of the most frequent size. Similar results were achieved by a typical particle size distribution. Moreover, the morphology of fractured surfaces showed an irregular topography for composites without MAPP suggesting a complex fracture process. Composites with MAPP, on the contrary, displayed a regular surface morphology suggesting a more regular fracture process with an important reduction of ductile mechanisms. This fracture behavior was related to the variation of the singularity width Δα. The results obtained suggest that multifractal theory can be applied to elucidate the relationship between structure and mechanical behavior of PP–CaCO3 composite materials.Fil: Perez, Ezequiel Martin. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Mecánica. Grupo de Materiales Avanzados; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Bernal, Celina Raquel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Mecánica. Grupo de Materiales Avanzados; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Piacquadio, Maria Natividad. Universidad de Buenos Aires. Facultad de Ingeniería; ArgentinaElsevier Science2012-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/20024Perez, Ezequiel Martin; Bernal, Celina Raquel; Piacquadio, Maria Natividad; Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites; Elsevier Science; Applied Surface Science; 258; 22; 9-2012; 8940-89450169-4332CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2012.05.124info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S016943321200983Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:09:56Zoai:ri.conicet.gov.ar:11336/20024instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:09:57.167CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites
title Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites
spellingShingle Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites
Perez, Ezequiel Martin
Multifractal Spectrum
Filler Dispersion
Mechanical Properties
Fracture Surface
title_short Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites
title_full Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites
title_fullStr Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites
title_full_unstemmed Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites
title_sort Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites
dc.creator.none.fl_str_mv Perez, Ezequiel Martin
Bernal, Celina Raquel
Piacquadio, Maria Natividad
author Perez, Ezequiel Martin
author_facet Perez, Ezequiel Martin
Bernal, Celina Raquel
Piacquadio, Maria Natividad
author_role author
author2 Bernal, Celina Raquel
Piacquadio, Maria Natividad
author2_role author
author
dc.subject.none.fl_str_mv Multifractal Spectrum
Filler Dispersion
Mechanical Properties
Fracture Surface
topic Multifractal Spectrum
Filler Dispersion
Mechanical Properties
Fracture Surface
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Multifractal analyses were performed to elucidate the effect of incorporating maleic anhydride grafted polypropylene (MAPP) into a Polypropylene matrix: (i) on the dispersion of CaCO3 particles and (ii) on the fracture morphology of tensile samples. The box-counting method was applied considering the number of particles and the mean gray value distribution as measured properties of composites. The dispersion analysis exhibited, for the composite with MAPP, a reduction of larger agglomerates sizes without variation of the most frequent size. Similar results were achieved by a typical particle size distribution. Moreover, the morphology of fractured surfaces showed an irregular topography for composites without MAPP suggesting a complex fracture process. Composites with MAPP, on the contrary, displayed a regular surface morphology suggesting a more regular fracture process with an important reduction of ductile mechanisms. This fracture behavior was related to the variation of the singularity width Δα. The results obtained suggest that multifractal theory can be applied to elucidate the relationship between structure and mechanical behavior of PP–CaCO3 composite materials.
Fil: Perez, Ezequiel Martin. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Mecánica. Grupo de Materiales Avanzados; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Bernal, Celina Raquel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Mecánica. Grupo de Materiales Avanzados; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Piacquadio, Maria Natividad. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina
description Multifractal analyses were performed to elucidate the effect of incorporating maleic anhydride grafted polypropylene (MAPP) into a Polypropylene matrix: (i) on the dispersion of CaCO3 particles and (ii) on the fracture morphology of tensile samples. The box-counting method was applied considering the number of particles and the mean gray value distribution as measured properties of composites. The dispersion analysis exhibited, for the composite with MAPP, a reduction of larger agglomerates sizes without variation of the most frequent size. Similar results were achieved by a typical particle size distribution. Moreover, the morphology of fractured surfaces showed an irregular topography for composites without MAPP suggesting a complex fracture process. Composites with MAPP, on the contrary, displayed a regular surface morphology suggesting a more regular fracture process with an important reduction of ductile mechanisms. This fracture behavior was related to the variation of the singularity width Δα. The results obtained suggest that multifractal theory can be applied to elucidate the relationship between structure and mechanical behavior of PP–CaCO3 composite materials.
publishDate 2012
dc.date.none.fl_str_mv 2012-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/20024
Perez, Ezequiel Martin; Bernal, Celina Raquel; Piacquadio, Maria Natividad; Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites; Elsevier Science; Applied Surface Science; 258; 22; 9-2012; 8940-8945
0169-4332
CONICET Digital
CONICET
url http://hdl.handle.net/11336/20024
identifier_str_mv Perez, Ezequiel Martin; Bernal, Celina Raquel; Piacquadio, Maria Natividad; Multifractal analysis of tensile toughness and filler dispersion for polypropylene–CaCO3 composites; Elsevier Science; Applied Surface Science; 258; 22; 9-2012; 8940-8945
0169-4332
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2012.05.124
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S016943321200983X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
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