Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates

Autores
Veronica, Martino; Jimenez, Alfonso; Ruseckaite, Roxana Alejandra; Luc, Averous
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The use of nano-biocomposites based on plasticized poly(lactic acid) (PLA) has been proposed as a way to improve the polymer ductility and to expand PLA applications window. Novative nano-biocomposites were elaborated with PLA plasticized by polyadipates (15 wt%) with different molar masses (from 1500 to 2500 Da), with 2.1 wt% of an organo-modified montmorillonite (O-MMT). These materials showed enhanced ductility and barrier properties. The clay was swelled in liquid polyadipates prior to their blending with PLA to facilitate chains intercalation and nanofiller exfoliation during melt-blending. In certain processing conditions, quite homogenous and exfoliated structures were obtained, as shown by X-ray diffraction (XRD) and transmission electronic microscopy (TEM) results. Irrespective of the average molar mass of the polyadipate, the clay addition induced a reduction in around 25% in oxygen transmission rate (OTR) without an important detriment in tensile properties. Nano-biocomposites prepared with higher molar masses polyadipates showed the highest thermal stability as well as the lowest OTR, resulting in very promising and novative materials for different applications such as soft packaging.
Fil: Veronica, Martino. Universite de Strasbourg; Francia
Fil: Jimenez, Alfonso. Universidad de Alicante. Departamento de Quiâ­mica Orgánica; España
Fil: Ruseckaite, Roxana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Luc, Averous. Universite de Strasbourg; Francia
Materia
Poly(Lactic Acid)
Montmorillonite
Oxygen Transmission
Ductility
Polyadipates
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/9541
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipatesVeronica, MartinoJimenez, AlfonsoRuseckaite, Roxana AlejandraLuc, AverousPoly(Lactic Acid)MontmorilloniteOxygen TransmissionDuctilityPolyadipateshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The use of nano-biocomposites based on plasticized poly(lactic acid) (PLA) has been proposed as a way to improve the polymer ductility and to expand PLA applications window. Novative nano-biocomposites were elaborated with PLA plasticized by polyadipates (15 wt%) with different molar masses (from 1500 to 2500 Da), with 2.1 wt% of an organo-modified montmorillonite (O-MMT). These materials showed enhanced ductility and barrier properties. The clay was swelled in liquid polyadipates prior to their blending with PLA to facilitate chains intercalation and nanofiller exfoliation during melt-blending. In certain processing conditions, quite homogenous and exfoliated structures were obtained, as shown by X-ray diffraction (XRD) and transmission electronic microscopy (TEM) results. Irrespective of the average molar mass of the polyadipate, the clay addition induced a reduction in around 25% in oxygen transmission rate (OTR) without an important detriment in tensile properties. Nano-biocomposites prepared with higher molar masses polyadipates showed the highest thermal stability as well as the lowest OTR, resulting in very promising and novative materials for different applications such as soft packaging.Fil: Veronica, Martino. Universite de Strasbourg; FranciaFil: Jimenez, Alfonso. Universidad de Alicante. Departamento de Quiâ­mica Orgánica; EspañaFil: Ruseckaite, Roxana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Luc, Averous. Universite de Strasbourg; FranciaWiley2010-07-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/9541Veronica, Martino; Jimenez, Alfonso; Ruseckaite, Roxana Alejandra; Luc, Averous; Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates; Wiley; Polymers For Advanced Technologies; 22; 12; 15-7-2010; 2206-22131099-1581enginfo:eu-repo/semantics/altIdentifier/issn/1099-1581info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pat.1747/fullinfo:eu-repo/semantics/altIdentifier/doi/10.1002/pat.1747info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:14Zoai:ri.conicet.gov.ar:11336/9541instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:14.821CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
title Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
spellingShingle Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
Veronica, Martino
Poly(Lactic Acid)
Montmorillonite
Oxygen Transmission
Ductility
Polyadipates
title_short Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
title_full Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
title_fullStr Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
title_full_unstemmed Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
title_sort Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates
dc.creator.none.fl_str_mv Veronica, Martino
Jimenez, Alfonso
Ruseckaite, Roxana Alejandra
Luc, Averous
author Veronica, Martino
author_facet Veronica, Martino
Jimenez, Alfonso
Ruseckaite, Roxana Alejandra
Luc, Averous
author_role author
author2 Jimenez, Alfonso
Ruseckaite, Roxana Alejandra
Luc, Averous
author2_role author
author
author
dc.subject.none.fl_str_mv Poly(Lactic Acid)
Montmorillonite
Oxygen Transmission
Ductility
Polyadipates
topic Poly(Lactic Acid)
Montmorillonite
Oxygen Transmission
Ductility
Polyadipates
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The use of nano-biocomposites based on plasticized poly(lactic acid) (PLA) has been proposed as a way to improve the polymer ductility and to expand PLA applications window. Novative nano-biocomposites were elaborated with PLA plasticized by polyadipates (15 wt%) with different molar masses (from 1500 to 2500 Da), with 2.1 wt% of an organo-modified montmorillonite (O-MMT). These materials showed enhanced ductility and barrier properties. The clay was swelled in liquid polyadipates prior to their blending with PLA to facilitate chains intercalation and nanofiller exfoliation during melt-blending. In certain processing conditions, quite homogenous and exfoliated structures were obtained, as shown by X-ray diffraction (XRD) and transmission electronic microscopy (TEM) results. Irrespective of the average molar mass of the polyadipate, the clay addition induced a reduction in around 25% in oxygen transmission rate (OTR) without an important detriment in tensile properties. Nano-biocomposites prepared with higher molar masses polyadipates showed the highest thermal stability as well as the lowest OTR, resulting in very promising and novative materials for different applications such as soft packaging.
Fil: Veronica, Martino. Universite de Strasbourg; Francia
Fil: Jimenez, Alfonso. Universidad de Alicante. Departamento de Quiâ­mica Orgánica; España
Fil: Ruseckaite, Roxana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Luc, Averous. Universite de Strasbourg; Francia
description The use of nano-biocomposites based on plasticized poly(lactic acid) (PLA) has been proposed as a way to improve the polymer ductility and to expand PLA applications window. Novative nano-biocomposites were elaborated with PLA plasticized by polyadipates (15 wt%) with different molar masses (from 1500 to 2500 Da), with 2.1 wt% of an organo-modified montmorillonite (O-MMT). These materials showed enhanced ductility and barrier properties. The clay was swelled in liquid polyadipates prior to their blending with PLA to facilitate chains intercalation and nanofiller exfoliation during melt-blending. In certain processing conditions, quite homogenous and exfoliated structures were obtained, as shown by X-ray diffraction (XRD) and transmission electronic microscopy (TEM) results. Irrespective of the average molar mass of the polyadipate, the clay addition induced a reduction in around 25% in oxygen transmission rate (OTR) without an important detriment in tensile properties. Nano-biocomposites prepared with higher molar masses polyadipates showed the highest thermal stability as well as the lowest OTR, resulting in very promising and novative materials for different applications such as soft packaging.
publishDate 2010
dc.date.none.fl_str_mv 2010-07-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/9541
Veronica, Martino; Jimenez, Alfonso; Ruseckaite, Roxana Alejandra; Luc, Averous; Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates; Wiley; Polymers For Advanced Technologies; 22; 12; 15-7-2010; 2206-2213
1099-1581
url http://hdl.handle.net/11336/9541
identifier_str_mv Veronica, Martino; Jimenez, Alfonso; Ruseckaite, Roxana Alejandra; Luc, Averous; Structure and Properties of clay nano-biocomposites based on poly(lactic acid) plasticized with polyadipates; Wiley; Polymers For Advanced Technologies; 22; 12; 15-7-2010; 2206-2213
1099-1581
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1099-1581
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pat.1747/full
info:eu-repo/semantics/altIdentifier/doi/10.1002/pat.1747
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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