Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles

Autores
Stamplecoskie, Kevin G.; Pacioni, Natalia Lorena; Larson, Dayle; Scaiano, Juan C.
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Visible light exposure of films containing silver nanoparticles (AgNPs) shows that the enhanced field around AgNPs in a thin film containing an azo free radical initiator (AIBN) and a triacrylate selectively cross-links the triacrylate within the plasmonic region around the particles. The cross-linked polymer is less soluble than its precursor and behaves as a solubility switch. After the film is developed with ethanol, polymer-encapsulated nanoparticles are preserved on the surface. The 8-10 nm polymer structure that encapsulates the particles effectively maps and preserves the morphology of the plasmon field in AgNP-controlled nanostructures. © 2011 American Chemical Society.
Fil: Stamplecoskie, Kevin G.. University of Ottawa; Canadá
Fil: Pacioni, Natalia Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. University of Ottawa; Canadá
Fil: Larson, Dayle. University of Ottawa; Canadá
Fil: Scaiano, Juan C.. University of Ottawa; Canadá
Materia
Plasmonics
Nanomaterials
Photopolymerization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66922

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network_name_str CONICET Digital (CONICET)
spelling Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticlesStamplecoskie, Kevin G.Pacioni, Natalia LorenaLarson, DayleScaiano, Juan C.PlasmonicsNanomaterialsPhotopolymerizationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Visible light exposure of films containing silver nanoparticles (AgNPs) shows that the enhanced field around AgNPs in a thin film containing an azo free radical initiator (AIBN) and a triacrylate selectively cross-links the triacrylate within the plasmonic region around the particles. The cross-linked polymer is less soluble than its precursor and behaves as a solubility switch. After the film is developed with ethanol, polymer-encapsulated nanoparticles are preserved on the surface. The 8-10 nm polymer structure that encapsulates the particles effectively maps and preserves the morphology of the plasmon field in AgNP-controlled nanostructures. © 2011 American Chemical Society.Fil: Stamplecoskie, Kevin G.. University of Ottawa; CanadáFil: Pacioni, Natalia Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. University of Ottawa; CanadáFil: Larson, Dayle. University of Ottawa; CanadáFil: Scaiano, Juan C.. University of Ottawa; CanadáAmerican Chemical Society2011-06-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66922Stamplecoskie, Kevin G.; Pacioni, Natalia Lorena; Larson, Dayle; Scaiano, Juan C.; Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles; American Chemical Society; Journal of the American Chemical Society; 133; 24; 26-6-2011; 9160-91630002-7863CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ja201139zinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ja201139zinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:24Zoai:ri.conicet.gov.ar:11336/66922instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:24.316CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles
title Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles
spellingShingle Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles
Stamplecoskie, Kevin G.
Plasmonics
Nanomaterials
Photopolymerization
title_short Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles
title_full Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles
title_fullStr Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles
title_full_unstemmed Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles
title_sort Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles
dc.creator.none.fl_str_mv Stamplecoskie, Kevin G.
Pacioni, Natalia Lorena
Larson, Dayle
Scaiano, Juan C.
author Stamplecoskie, Kevin G.
author_facet Stamplecoskie, Kevin G.
Pacioni, Natalia Lorena
Larson, Dayle
Scaiano, Juan C.
author_role author
author2 Pacioni, Natalia Lorena
Larson, Dayle
Scaiano, Juan C.
author2_role author
author
author
dc.subject.none.fl_str_mv Plasmonics
Nanomaterials
Photopolymerization
topic Plasmonics
Nanomaterials
Photopolymerization
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Visible light exposure of films containing silver nanoparticles (AgNPs) shows that the enhanced field around AgNPs in a thin film containing an azo free radical initiator (AIBN) and a triacrylate selectively cross-links the triacrylate within the plasmonic region around the particles. The cross-linked polymer is less soluble than its precursor and behaves as a solubility switch. After the film is developed with ethanol, polymer-encapsulated nanoparticles are preserved on the surface. The 8-10 nm polymer structure that encapsulates the particles effectively maps and preserves the morphology of the plasmon field in AgNP-controlled nanostructures. © 2011 American Chemical Society.
Fil: Stamplecoskie, Kevin G.. University of Ottawa; Canadá
Fil: Pacioni, Natalia Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. University of Ottawa; Canadá
Fil: Larson, Dayle. University of Ottawa; Canadá
Fil: Scaiano, Juan C.. University of Ottawa; Canadá
description Visible light exposure of films containing silver nanoparticles (AgNPs) shows that the enhanced field around AgNPs in a thin film containing an azo free radical initiator (AIBN) and a triacrylate selectively cross-links the triacrylate within the plasmonic region around the particles. The cross-linked polymer is less soluble than its precursor and behaves as a solubility switch. After the film is developed with ethanol, polymer-encapsulated nanoparticles are preserved on the surface. The 8-10 nm polymer structure that encapsulates the particles effectively maps and preserves the morphology of the plasmon field in AgNP-controlled nanostructures. © 2011 American Chemical Society.
publishDate 2011
dc.date.none.fl_str_mv 2011-06-26
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66922
Stamplecoskie, Kevin G.; Pacioni, Natalia Lorena; Larson, Dayle; Scaiano, Juan C.; Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles; American Chemical Society; Journal of the American Chemical Society; 133; 24; 26-6-2011; 9160-9163
0002-7863
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66922
identifier_str_mv Stamplecoskie, Kevin G.; Pacioni, Natalia Lorena; Larson, Dayle; Scaiano, Juan C.; Plasmon-mediated photopolymerization maps plasmon fields for silver nanoparticles; American Chemical Society; Journal of the American Chemical Society; 133; 24; 26-6-2011; 9160-9163
0002-7863
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ja201139z
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ja201139z
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432