Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism

Autores
Alas, S. J.; Cordero, S.; Kornhauser, I.; Zgrablich, Jorge Andres
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Kinetic oscillations in the catalytic reduction of NO by CO on a reconstructing Pt(100) surface are simulated by using a dynamic Monte Carlo method. The simulation is based on the HS model and takes into account an alternative reaction mechanism arising from recent experimental findings for the catalytic reduction of No on Rh(111), which replaces the classical N+N recombination step by the formation of a (N–NO)∗ intermediary species for the production of molecular nitrogen. A synchronized mechanism and spatiotemporal patterns are observed during the oscillations. Oscillations are analyzed in terms of the controlling parameters involved in the reaction mechanism. Different values of these parameters lead to sustained, attenuated, and modulated oscillations.
Fil: Alas, S. J.. Universidad Autónoma Metropolitana; México
Fil: Cordero, S.. Universidad Autónoma Metropolitana; México
Fil: Kornhauser, I.. Universidad Autónoma Metropolitana; México
Fil: Zgrablich, Jorge Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina
Materia
KINETIC OSCILLATIONS
MONTE CARLO METHOD
HS MODEL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/158620
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanismAlas, S. J.Cordero, S.Kornhauser, I.Zgrablich, Jorge AndresKINETIC OSCILLATIONSMONTE CARLO METHODHS MODELhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Kinetic oscillations in the catalytic reduction of NO by CO on a reconstructing Pt(100) surface are simulated by using a dynamic Monte Carlo method. The simulation is based on the HS model and takes into account an alternative reaction mechanism arising from recent experimental findings for the catalytic reduction of No on Rh(111), which replaces the classical N+N recombination step by the formation of a (N–NO)∗ intermediary species for the production of molecular nitrogen. A synchronized mechanism and spatiotemporal patterns are observed during the oscillations. Oscillations are analyzed in terms of the controlling parameters involved in the reaction mechanism. Different values of these parameters lead to sustained, attenuated, and modulated oscillations.Fil: Alas, S. J.. Universidad Autónoma Metropolitana; MéxicoFil: Cordero, S.. Universidad Autónoma Metropolitana; MéxicoFil: Kornhauser, I.. Universidad Autónoma Metropolitana; MéxicoFil: Zgrablich, Jorge Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Laboratorio de Ciencias de Superficies y Medios Porosos; ArgentinaAmerican Institute of Physics2005-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/158620Alas, S. J.; Cordero, S.; Kornhauser, I.; Zgrablich, Jorge Andres; Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism; American Institute of Physics; Journal of Chemical Physics; 122; 14; 4-2005; 1-80021-9606CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.1878572info:eu-repo/semantics/altIdentifier/doi/10.1063/1.1878572info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:13:09Zoai:ri.conicet.gov.ar:11336/158620instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:13:09.917CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
title Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
spellingShingle Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
Alas, S. J.
KINETIC OSCILLATIONS
MONTE CARLO METHOD
HS MODEL
title_short Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
title_full Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
title_fullStr Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
title_full_unstemmed Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
title_sort Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
dc.creator.none.fl_str_mv Alas, S. J.
Cordero, S.
Kornhauser, I.
Zgrablich, Jorge Andres
author Alas, S. J.
author_facet Alas, S. J.
Cordero, S.
Kornhauser, I.
Zgrablich, Jorge Andres
author_role author
author2 Cordero, S.
Kornhauser, I.
Zgrablich, Jorge Andres
author2_role author
author
author
dc.subject.none.fl_str_mv KINETIC OSCILLATIONS
MONTE CARLO METHOD
HS MODEL
topic KINETIC OSCILLATIONS
MONTE CARLO METHOD
HS MODEL
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Kinetic oscillations in the catalytic reduction of NO by CO on a reconstructing Pt(100) surface are simulated by using a dynamic Monte Carlo method. The simulation is based on the HS model and takes into account an alternative reaction mechanism arising from recent experimental findings for the catalytic reduction of No on Rh(111), which replaces the classical N+N recombination step by the formation of a (N–NO)∗ intermediary species for the production of molecular nitrogen. A synchronized mechanism and spatiotemporal patterns are observed during the oscillations. Oscillations are analyzed in terms of the controlling parameters involved in the reaction mechanism. Different values of these parameters lead to sustained, attenuated, and modulated oscillations.
Fil: Alas, S. J.. Universidad Autónoma Metropolitana; México
Fil: Cordero, S.. Universidad Autónoma Metropolitana; México
Fil: Kornhauser, I.. Universidad Autónoma Metropolitana; México
Fil: Zgrablich, Jorge Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina
description Kinetic oscillations in the catalytic reduction of NO by CO on a reconstructing Pt(100) surface are simulated by using a dynamic Monte Carlo method. The simulation is based on the HS model and takes into account an alternative reaction mechanism arising from recent experimental findings for the catalytic reduction of No on Rh(111), which replaces the classical N+N recombination step by the formation of a (N–NO)∗ intermediary species for the production of molecular nitrogen. A synchronized mechanism and spatiotemporal patterns are observed during the oscillations. Oscillations are analyzed in terms of the controlling parameters involved in the reaction mechanism. Different values of these parameters lead to sustained, attenuated, and modulated oscillations.
publishDate 2005
dc.date.none.fl_str_mv 2005-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/158620
Alas, S. J.; Cordero, S.; Kornhauser, I.; Zgrablich, Jorge Andres; Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism; American Institute of Physics; Journal of Chemical Physics; 122; 14; 4-2005; 1-8
0021-9606
CONICET Digital
CONICET
url http://hdl.handle.net/11336/158620
identifier_str_mv Alas, S. J.; Cordero, S.; Kornhauser, I.; Zgrablich, Jorge Andres; Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism; American Institute of Physics; Journal of Chemical Physics; 122; 14; 4-2005; 1-8
0021-9606
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.1878572
info:eu-repo/semantics/altIdentifier/doi/10.1063/1.1878572
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Institute of Physics
publisher.none.fl_str_mv American Institute of Physics
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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