Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters

Autores
Reinoso, Deborath Mariana; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, zinc glycerolate (ZnGly) is studied as a new catalyst for an environmentally friendly production of biodiesel. The solid was prepared by a simple procedure, characterized and studied in the transesterification of soybean oil with methanol. ZnGly was able to convert soybean oil into fatty acid methyl esters with 66–76% yield and up to 95–97% triglyceride (TG) conversion in the 100–140 °C reaction temperature range studied. The catalyst showed a long life and could be reused for five catalytic cycles without deactivation or selectivity loss. The catalyst exhibited good tolerance toward 0.5 wt.% water, without important changes in the TG conversion, but with a 23% decrease in FAME yield. In the presence of 10 wt.% fatty acids, ZnGly showed an almost complete TG conversion with an increase in FAME yield of 51% (93% FAME selectivity at 50 min reaction time). At 140 °C and in acid oil, ZnGly can be easily transformed into Zn carboxylate and partially re-generated in the presence of glycerol.
Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
Materia
Zinc Glycerolate
Transesterifiation
Biodiesel
Soybean Oil
Heterogeneous Catalyst
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/13514
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/13514
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl estersReinoso, Deborath MarianaTonetto, Gabriela MartaDamiani, Daniel EduardoZinc GlycerolateTransesterifiationBiodieselSoybean OilHeterogeneous Catalysthttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this work, zinc glycerolate (ZnGly) is studied as a new catalyst for an environmentally friendly production of biodiesel. The solid was prepared by a simple procedure, characterized and studied in the transesterification of soybean oil with methanol. ZnGly was able to convert soybean oil into fatty acid methyl esters with 66–76% yield and up to 95–97% triglyceride (TG) conversion in the 100–140 °C reaction temperature range studied. The catalyst showed a long life and could be reused for five catalytic cycles without deactivation or selectivity loss. The catalyst exhibited good tolerance toward 0.5 wt.% water, without important changes in the TG conversion, but with a 23% decrease in FAME yield. In the presence of 10 wt.% fatty acids, ZnGly showed an almost complete TG conversion with an increase in FAME yield of 51% (93% FAME selectivity at 50 min reaction time). At 140 °C and in acid oil, ZnGly can be easily transformed into Zn carboxylate and partially re-generated in the presence of glycerol.Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; ArgentinaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; ArgentinaElsevier Science2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13514Reinoso, Deborath Mariana; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters; Elsevier Science; Applied Catalysis B: Environmental; 144; 1-2014; 308-3160926-3373enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926337313004451info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2013.07.026info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:58:42Zoai:ri.conicet.gov.ar:11336/13514instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:58:42.679CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters
title Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters
spellingShingle Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters
Reinoso, Deborath Mariana
Zinc Glycerolate
Transesterifiation
Biodiesel
Soybean Oil
Heterogeneous Catalyst
title_short Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters
title_full Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters
title_fullStr Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters
title_full_unstemmed Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters
title_sort Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters
dc.creator.none.fl_str_mv Reinoso, Deborath Mariana
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author Reinoso, Deborath Mariana
author_facet Reinoso, Deborath Mariana
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author_role author
author2 Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
author2_role author
author
dc.subject.none.fl_str_mv Zinc Glycerolate
Transesterifiation
Biodiesel
Soybean Oil
Heterogeneous Catalyst
topic Zinc Glycerolate
Transesterifiation
Biodiesel
Soybean Oil
Heterogeneous Catalyst
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, zinc glycerolate (ZnGly) is studied as a new catalyst for an environmentally friendly production of biodiesel. The solid was prepared by a simple procedure, characterized and studied in the transesterification of soybean oil with methanol. ZnGly was able to convert soybean oil into fatty acid methyl esters with 66–76% yield and up to 95–97% triglyceride (TG) conversion in the 100–140 °C reaction temperature range studied. The catalyst showed a long life and could be reused for five catalytic cycles without deactivation or selectivity loss. The catalyst exhibited good tolerance toward 0.5 wt.% water, without important changes in the TG conversion, but with a 23% decrease in FAME yield. In the presence of 10 wt.% fatty acids, ZnGly showed an almost complete TG conversion with an increase in FAME yield of 51% (93% FAME selectivity at 50 min reaction time). At 140 °C and in acid oil, ZnGly can be easily transformed into Zn carboxylate and partially re-generated in the presence of glycerol.
Fil: Reinoso, Deborath Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
description In this work, zinc glycerolate (ZnGly) is studied as a new catalyst for an environmentally friendly production of biodiesel. The solid was prepared by a simple procedure, characterized and studied in the transesterification of soybean oil with methanol. ZnGly was able to convert soybean oil into fatty acid methyl esters with 66–76% yield and up to 95–97% triglyceride (TG) conversion in the 100–140 °C reaction temperature range studied. The catalyst showed a long life and could be reused for five catalytic cycles without deactivation or selectivity loss. The catalyst exhibited good tolerance toward 0.5 wt.% water, without important changes in the TG conversion, but with a 23% decrease in FAME yield. In the presence of 10 wt.% fatty acids, ZnGly showed an almost complete TG conversion with an increase in FAME yield of 51% (93% FAME selectivity at 50 min reaction time). At 140 °C and in acid oil, ZnGly can be easily transformed into Zn carboxylate and partially re-generated in the presence of glycerol.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/13514
Reinoso, Deborath Mariana; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters; Elsevier Science; Applied Catalysis B: Environmental; 144; 1-2014; 308-316
0926-3373
url http://hdl.handle.net/11336/13514
identifier_str_mv Reinoso, Deborath Mariana; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Zinc glycerolate as a novel heterogeneous catalyst for the synthesis of fatty acid methyl esters; Elsevier Science; Applied Catalysis B: Environmental; 144; 1-2014; 308-316
0926-3373
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926337313004451
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2013.07.026
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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