A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen

Autores
Garcia Blanco, Andres Alberto; Alexandre de Oliveira, José Carlos; López, Raúl Horacio; Moreno Piraján, J. C.; Giraldo, L.; Zgrablich, Jorge Andres; Sapag, Manuel Karim
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
By adsorption of different gases and simulation methods it was studied the characterization of microporous monoliths in activated carbons from coconut shells in relation to the storage capacity of gases that present energetic interest. Adsorption isotherms of nitrogen, methane, carbon dioxide and hydrogen at different temperatures were measured at sub-atmospheric pressures. Additional adsorption isotherms of methane were performed at room temperature and high pressures (up to 4.5 MPa). A Grand Canonical Monte Carlo simulation of adsorption on slit pores was carried out for these gases. The simulated data were adjusted to experimental data to optimize the models. Different parameters such as micropore volume, pore size distribution and differential isosteric enthalpy of adsorption, were studied and related to the hydrogen and methane storage capacity for these materials.
Fil: Garcia Blanco, Andres Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Alexandre de Oliveira, José Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: López, Raúl Horacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Moreno Piraján, J. C.. Universidad de Los Andes; Venezuela
Fil: Giraldo, L.. Universidad Nacional de Colombia; Colombia
Fil: Zgrablich, Jorge Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Materia
Methane Storage
Pore Size Distribution
Simulation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/14148
Acceder
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network_name_str CONICET Digital (CONICET)
spelling A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogenGarcia Blanco, Andres AlbertoAlexandre de Oliveira, José CarlosLópez, Raúl HoracioMoreno Piraján, J. C.Giraldo, L.Zgrablich, Jorge AndresSapag, Manuel KarimMethane StoragePore Size DistributionSimulationhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1By adsorption of different gases and simulation methods it was studied the characterization of microporous monoliths in activated carbons from coconut shells in relation to the storage capacity of gases that present energetic interest. Adsorption isotherms of nitrogen, methane, carbon dioxide and hydrogen at different temperatures were measured at sub-atmospheric pressures. Additional adsorption isotherms of methane were performed at room temperature and high pressures (up to 4.5 MPa). A Grand Canonical Monte Carlo simulation of adsorption on slit pores was carried out for these gases. The simulated data were adjusted to experimental data to optimize the models. Different parameters such as micropore volume, pore size distribution and differential isosteric enthalpy of adsorption, were studied and related to the hydrogen and methane storage capacity for these materials.Fil: Garcia Blanco, Andres Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; ArgentinaFil: Alexandre de Oliveira, José Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; ArgentinaFil: López, Raúl Horacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; ArgentinaFil: Moreno Piraján, J. C.. Universidad de Los Andes; VenezuelaFil: Giraldo, L.. Universidad Nacional de Colombia; ColombiaFil: Zgrablich, Jorge Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; ArgentinaFil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; ArgentinaElsevier Science2010-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/14148Garcia Blanco, Andres Alberto; Alexandre de Oliveira, José Carlos; López, Raúl Horacio; Moreno Piraján, J. C.; Giraldo, L.; et al.; A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen; Elsevier Science; Colloids And Surfaces A: Physicochemical And Engineering Aspects; 357; 1-2010; 74-830927-7757enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0927775710000166info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1016/j.colsurfa.2010.01.006info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:11Zoai:ri.conicet.gov.ar:11336/14148instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:12.211CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen
title A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen
spellingShingle A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen
Garcia Blanco, Andres Alberto
Methane Storage
Pore Size Distribution
Simulation
title_short A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen
title_full A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen
title_fullStr A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen
title_full_unstemmed A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen
title_sort A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen
dc.creator.none.fl_str_mv Garcia Blanco, Andres Alberto
Alexandre de Oliveira, José Carlos
López, Raúl Horacio
Moreno Piraján, J. C.
Giraldo, L.
Zgrablich, Jorge Andres
Sapag, Manuel Karim
author Garcia Blanco, Andres Alberto
author_facet Garcia Blanco, Andres Alberto
Alexandre de Oliveira, José Carlos
López, Raúl Horacio
Moreno Piraján, J. C.
Giraldo, L.
Zgrablich, Jorge Andres
Sapag, Manuel Karim
author_role author
author2 Alexandre de Oliveira, José Carlos
López, Raúl Horacio
Moreno Piraján, J. C.
Giraldo, L.
Zgrablich, Jorge Andres
Sapag, Manuel Karim
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Methane Storage
Pore Size Distribution
Simulation
topic Methane Storage
Pore Size Distribution
Simulation
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv By adsorption of different gases and simulation methods it was studied the characterization of microporous monoliths in activated carbons from coconut shells in relation to the storage capacity of gases that present energetic interest. Adsorption isotherms of nitrogen, methane, carbon dioxide and hydrogen at different temperatures were measured at sub-atmospheric pressures. Additional adsorption isotherms of methane were performed at room temperature and high pressures (up to 4.5 MPa). A Grand Canonical Monte Carlo simulation of adsorption on slit pores was carried out for these gases. The simulated data were adjusted to experimental data to optimize the models. Different parameters such as micropore volume, pore size distribution and differential isosteric enthalpy of adsorption, were studied and related to the hydrogen and methane storage capacity for these materials.
Fil: Garcia Blanco, Andres Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Alexandre de Oliveira, José Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: López, Raúl Horacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Moreno Piraján, J. C.. Universidad de Los Andes; Venezuela
Fil: Giraldo, L.. Universidad Nacional de Colombia; Colombia
Fil: Zgrablich, Jorge Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
description By adsorption of different gases and simulation methods it was studied the characterization of microporous monoliths in activated carbons from coconut shells in relation to the storage capacity of gases that present energetic interest. Adsorption isotherms of nitrogen, methane, carbon dioxide and hydrogen at different temperatures were measured at sub-atmospheric pressures. Additional adsorption isotherms of methane were performed at room temperature and high pressures (up to 4.5 MPa). A Grand Canonical Monte Carlo simulation of adsorption on slit pores was carried out for these gases. The simulated data were adjusted to experimental data to optimize the models. Different parameters such as micropore volume, pore size distribution and differential isosteric enthalpy of adsorption, were studied and related to the hydrogen and methane storage capacity for these materials.
publishDate 2010
dc.date.none.fl_str_mv 2010-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/14148
Garcia Blanco, Andres Alberto; Alexandre de Oliveira, José Carlos; López, Raúl Horacio; Moreno Piraján, J. C.; Giraldo, L.; et al.; A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen; Elsevier Science; Colloids And Surfaces A: Physicochemical And Engineering Aspects; 357; 1-2010; 74-83
0927-7757
url http://hdl.handle.net/11336/14148
identifier_str_mv Garcia Blanco, Andres Alberto; Alexandre de Oliveira, José Carlos; López, Raúl Horacio; Moreno Piraján, J. C.; Giraldo, L.; et al.; A study of the pore size distribution for activated carbon monoliths and their relationship with the storage of methane and hydrogen; Elsevier Science; Colloids And Surfaces A: Physicochemical And Engineering Aspects; 357; 1-2010; 74-83
0927-7757
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0927775710000166
info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1016/j.colsurfa.2010.01.006
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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