Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation

Autores
Satti, Angel Jose; Andreucetti, N. A.; Quijada, R.; Valles, Enrique Marcelo
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Metallocenic polypropylene and copolymers with 3.7, 9.2 mol% of hexene and 3.0 mol% of octadecene comonomer content were synthesized and irradiated with 60Co gamma radiation under vacuum at room temperature. Size Exclusion Cromatography and gel extraction data showed that scission reactions predominate over crosslinking in the homopolymer and that there is a dose from where crosslinking started to increase considerably, in the irradiated copolymers. Rheology also showed evidence of chain-enlargements on the copolymers by means of an increase in the viscoelastic properties of the irradiated material.
Fil: Satti, Angel Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Andreucetti, N. A.. Universidad Nacional del Sur. Departamento de Química. Laboratorio de Radioisotopos; Argentina
Fil: Quijada, R.. Universidad de Chile; Chile
Fil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
rheology
polypropylene
copolymers
gamma irradiation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/270939
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiationSatti, Angel JoseAndreucetti, N. A.Quijada, R.Valles, Enrique Marcelorheologypolypropylenecopolymersgamma irradiationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Metallocenic polypropylene and copolymers with 3.7, 9.2 mol% of hexene and 3.0 mol% of octadecene comonomer content were synthesized and irradiated with 60Co gamma radiation under vacuum at room temperature. Size Exclusion Cromatography and gel extraction data showed that scission reactions predominate over crosslinking in the homopolymer and that there is a dose from where crosslinking started to increase considerably, in the irradiated copolymers. Rheology also showed evidence of chain-enlargements on the copolymers by means of an increase in the viscoelastic properties of the irradiated material.Fil: Satti, Angel Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Andreucetti, N. A.. Universidad Nacional del Sur. Departamento de Química. Laboratorio de Radioisotopos; ArgentinaFil: Quijada, R.. Universidad de Chile; ChileFil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaPergamon-Elsevier Science Ltd2012-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/270939Satti, Angel Jose; Andreucetti, N. A.; Quijada, R.; Valles, Enrique Marcelo; Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation; Pergamon-Elsevier Science Ltd; Radiation Physics and Chemistry (Oxford); 81; 7-2012; 1874-18800969-806XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0969806X12003520info:eu-repo/semantics/altIdentifier/doi/10.1016/j.radphyschem.2012.07.007info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:41:07Zoai:ri.conicet.gov.ar:11336/270939instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:41:07.36CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation
title Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation
spellingShingle Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation
Satti, Angel Jose
rheology
polypropylene
copolymers
gamma irradiation
title_short Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation
title_full Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation
title_fullStr Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation
title_full_unstemmed Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation
title_sort Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation
dc.creator.none.fl_str_mv Satti, Angel Jose
Andreucetti, N. A.
Quijada, R.
Valles, Enrique Marcelo
author Satti, Angel Jose
author_facet Satti, Angel Jose
Andreucetti, N. A.
Quijada, R.
Valles, Enrique Marcelo
author_role author
author2 Andreucetti, N. A.
Quijada, R.
Valles, Enrique Marcelo
author2_role author
author
author
dc.subject.none.fl_str_mv rheology
polypropylene
copolymers
gamma irradiation
topic rheology
polypropylene
copolymers
gamma irradiation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Metallocenic polypropylene and copolymers with 3.7, 9.2 mol% of hexene and 3.0 mol% of octadecene comonomer content were synthesized and irradiated with 60Co gamma radiation under vacuum at room temperature. Size Exclusion Cromatography and gel extraction data showed that scission reactions predominate over crosslinking in the homopolymer and that there is a dose from where crosslinking started to increase considerably, in the irradiated copolymers. Rheology also showed evidence of chain-enlargements on the copolymers by means of an increase in the viscoelastic properties of the irradiated material.
Fil: Satti, Angel Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Andreucetti, N. A.. Universidad Nacional del Sur. Departamento de Química. Laboratorio de Radioisotopos; Argentina
Fil: Quijada, R.. Universidad de Chile; Chile
Fil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Metallocenic polypropylene and copolymers with 3.7, 9.2 mol% of hexene and 3.0 mol% of octadecene comonomer content were synthesized and irradiated with 60Co gamma radiation under vacuum at room temperature. Size Exclusion Cromatography and gel extraction data showed that scission reactions predominate over crosslinking in the homopolymer and that there is a dose from where crosslinking started to increase considerably, in the irradiated copolymers. Rheology also showed evidence of chain-enlargements on the copolymers by means of an increase in the viscoelastic properties of the irradiated material.
publishDate 2012
dc.date.none.fl_str_mv 2012-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/270939
Satti, Angel Jose; Andreucetti, N. A.; Quijada, R.; Valles, Enrique Marcelo; Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation; Pergamon-Elsevier Science Ltd; Radiation Physics and Chemistry (Oxford); 81; 7-2012; 1874-1880
0969-806X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/270939
identifier_str_mv Satti, Angel Jose; Andreucetti, N. A.; Quijada, R.; Valles, Enrique Marcelo; Crosslinking of metallocenic α-olefin propylene copolymers by vacuum gamma irradiation; Pergamon-Elsevier Science Ltd; Radiation Physics and Chemistry (Oxford); 81; 7-2012; 1874-1880
0969-806X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0969806X12003520
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.radphyschem.2012.07.007
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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