Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
- Autores
- Moreno Betancourt, Angelica; Schwabedissen, Jan; Romano, Rosana Mariel; Della Védova, Carlos Omar; Beckers, Helmut; Willner, Helge; Stammler, Hans Georg; Mitzel, Norbert Werner
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized byvibrational spectroscopy in the gaseous and liquid phase as well asin the Ar-matrix. By varying the temperature, certain bands could beassigned to several conformers. Gas-phase electron diffractionrevealed a dominance of the anti-conformer at ambient temperature.The same conformation was found in the solid state. Via the in situtechnique for crystallization, not less than four different modificationswere identified. Among these different modifications, the structuralparameters of the molecules remain relatively constant, but theaggregation pattern changes. Although the molecules aggregate bychlorine···oxygen contacts in each modification, the geometricalparameters of these interaction show significant differences andwere evaluated and are in part inconsistent with the halogen bondingconcept.
Fil: Moreno Betancourt, Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Schwabedissen, Jan. Universitat Bielefeld; Alemania
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Beckers, Helmut. Bergische Universität Wuppertal; Alemania
Fil: Willner, Helge. Bergische Universität Wuppertal; Alemania
Fil: Stammler, Hans Georg. Universitat Bielefeld; Alemania
Fil: Mitzel, Norbert Werner. Universitat Bielefeld; Alemania - Materia
-
Matrix isolation
Gas Electron Diffraction
Crystal Structure
Polymorphism - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/87550
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network_name_str |
CONICET Digital (CONICET) |
spelling |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleonMoreno Betancourt, AngelicaSchwabedissen, JanRomano, Rosana MarielDella Védova, Carlos OmarBeckers, HelmutWillner, HelgeStammler, Hans GeorgMitzel, Norbert WernerMatrix isolationGas Electron DiffractionCrystal StructurePolymorphismhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized byvibrational spectroscopy in the gaseous and liquid phase as well asin the Ar-matrix. By varying the temperature, certain bands could beassigned to several conformers. Gas-phase electron diffractionrevealed a dominance of the anti-conformer at ambient temperature.The same conformation was found in the solid state. Via the in situtechnique for crystallization, not less than four different modificationswere identified. Among these different modifications, the structuralparameters of the molecules remain relatively constant, but theaggregation pattern changes. Although the molecules aggregate bychlorine···oxygen contacts in each modification, the geometricalparameters of these interaction show significant differences andwere evaluated and are in part inconsistent with the halogen bondingconcept.Fil: Moreno Betancourt, Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Schwabedissen, Jan. Universitat Bielefeld; AlemaniaFil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Beckers, Helmut. Bergische Universität Wuppertal; AlemaniaFil: Willner, Helge. Bergische Universität Wuppertal; AlemaniaFil: Stammler, Hans Georg. Universitat Bielefeld; AlemaniaFil: Mitzel, Norbert Werner. Universitat Bielefeld; AlemaniaWiley VCH Verlag2018-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/87550Moreno Betancourt, Angelica; Schwabedissen, Jan; Romano, Rosana Mariel; Della Védova, Carlos Omar; Beckers, Helmut; et al.; Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon; Wiley VCH Verlag; Chemistry- A European Journal; 24; 4-2018; 10409-104210947-6539CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201800817info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201800817info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)https://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:27:07Zoai:ri.conicet.gov.ar:11336/87550instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:27:08.221CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon |
title |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon |
spellingShingle |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon Moreno Betancourt, Angelica Matrix isolation Gas Electron Diffraction Crystal Structure Polymorphism |
title_short |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon |
title_full |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon |
title_fullStr |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon |
title_full_unstemmed |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon |
title_sort |
Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon |
dc.creator.none.fl_str_mv |
Moreno Betancourt, Angelica Schwabedissen, Jan Romano, Rosana Mariel Della Védova, Carlos Omar Beckers, Helmut Willner, Helge Stammler, Hans Georg Mitzel, Norbert Werner |
author |
Moreno Betancourt, Angelica |
author_facet |
Moreno Betancourt, Angelica Schwabedissen, Jan Romano, Rosana Mariel Della Védova, Carlos Omar Beckers, Helmut Willner, Helge Stammler, Hans Georg Mitzel, Norbert Werner |
author_role |
author |
author2 |
Schwabedissen, Jan Romano, Rosana Mariel Della Védova, Carlos Omar Beckers, Helmut Willner, Helge Stammler, Hans Georg Mitzel, Norbert Werner |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Matrix isolation Gas Electron Diffraction Crystal Structure Polymorphism |
topic |
Matrix isolation Gas Electron Diffraction Crystal Structure Polymorphism |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized byvibrational spectroscopy in the gaseous and liquid phase as well asin the Ar-matrix. By varying the temperature, certain bands could beassigned to several conformers. Gas-phase electron diffractionrevealed a dominance of the anti-conformer at ambient temperature.The same conformation was found in the solid state. Via the in situtechnique for crystallization, not less than four different modificationswere identified. Among these different modifications, the structuralparameters of the molecules remain relatively constant, but theaggregation pattern changes. Although the molecules aggregate bychlorine···oxygen contacts in each modification, the geometricalparameters of these interaction show significant differences andwere evaluated and are in part inconsistent with the halogen bondingconcept. Fil: Moreno Betancourt, Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Schwabedissen, Jan. Universitat Bielefeld; Alemania Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Beckers, Helmut. Bergische Universität Wuppertal; Alemania Fil: Willner, Helge. Bergische Universität Wuppertal; Alemania Fil: Stammler, Hans Georg. Universitat Bielefeld; Alemania Fil: Mitzel, Norbert Werner. Universitat Bielefeld; Alemania |
description |
Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized byvibrational spectroscopy in the gaseous and liquid phase as well asin the Ar-matrix. By varying the temperature, certain bands could beassigned to several conformers. Gas-phase electron diffractionrevealed a dominance of the anti-conformer at ambient temperature.The same conformation was found in the solid state. Via the in situtechnique for crystallization, not less than four different modificationswere identified. Among these different modifications, the structuralparameters of the molecules remain relatively constant, but theaggregation pattern changes. Although the molecules aggregate bychlorine···oxygen contacts in each modification, the geometricalparameters of these interaction show significant differences andwere evaluated and are in part inconsistent with the halogen bondingconcept. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/87550 Moreno Betancourt, Angelica; Schwabedissen, Jan; Romano, Rosana Mariel; Della Védova, Carlos Omar; Beckers, Helmut; et al.; Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon; Wiley VCH Verlag; Chemistry- A European Journal; 24; 4-2018; 10409-10421 0947-6539 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/87550 |
identifier_str_mv |
Moreno Betancourt, Angelica; Schwabedissen, Jan; Romano, Rosana Mariel; Della Védova, Carlos Omar; Beckers, Helmut; et al.; Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon; Wiley VCH Verlag; Chemistry- A European Journal; 24; 4-2018; 10409-10421 0947-6539 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201800817 info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201800817 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR) https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR) https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1846082724093231104 |
score |
13.22299 |