Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon

Autores
Moreno Betancourt, Angelica; Schwabedissen, Jan; Romano, Rosana Mariel; Della Védova, Carlos Omar; Beckers, Helmut; Willner, Helge; Stammler, Hans Georg; Mitzel, Norbert Werner
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized byvibrational spectroscopy in the gaseous and liquid phase as well asin the Ar-matrix. By varying the temperature, certain bands could beassigned to several conformers. Gas-phase electron diffractionrevealed a dominance of the anti-conformer at ambient temperature.The same conformation was found in the solid state. Via the in situtechnique for crystallization, not less than four different modificationswere identified. Among these different modifications, the structuralparameters of the molecules remain relatively constant, but theaggregation pattern changes. Although the molecules aggregate bychlorine···oxygen contacts in each modification, the geometricalparameters of these interaction show significant differences andwere evaluated and are in part inconsistent with the halogen bondingconcept.
Fil: Moreno Betancourt, Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Schwabedissen, Jan. Universitat Bielefeld; Alemania
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Beckers, Helmut. Bergische Universität Wuppertal; Alemania
Fil: Willner, Helge. Bergische Universität Wuppertal; Alemania
Fil: Stammler, Hans Georg. Universitat Bielefeld; Alemania
Fil: Mitzel, Norbert Werner. Universitat Bielefeld; Alemania
Materia
Matrix isolation
Gas Electron Diffraction
Crystal Structure
Polymorphism
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/87550

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network_name_str CONICET Digital (CONICET)
spelling Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleonMoreno Betancourt, AngelicaSchwabedissen, JanRomano, Rosana MarielDella Védova, Carlos OmarBeckers, HelmutWillner, HelgeStammler, Hans GeorgMitzel, Norbert WernerMatrix isolationGas Electron DiffractionCrystal StructurePolymorphismhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized byvibrational spectroscopy in the gaseous and liquid phase as well asin the Ar-matrix. By varying the temperature, certain bands could beassigned to several conformers. Gas-phase electron diffractionrevealed a dominance of the anti-conformer at ambient temperature.The same conformation was found in the solid state. Via the in situtechnique for crystallization, not less than four different modificationswere identified. Among these different modifications, the structuralparameters of the molecules remain relatively constant, but theaggregation pattern changes. Although the molecules aggregate bychlorine···oxygen contacts in each modification, the geometricalparameters of these interaction show significant differences andwere evaluated and are in part inconsistent with the halogen bondingconcept.Fil: Moreno Betancourt, Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Schwabedissen, Jan. Universitat Bielefeld; AlemaniaFil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Beckers, Helmut. Bergische Universität Wuppertal; AlemaniaFil: Willner, Helge. Bergische Universität Wuppertal; AlemaniaFil: Stammler, Hans Georg. Universitat Bielefeld; AlemaniaFil: Mitzel, Norbert Werner. Universitat Bielefeld; AlemaniaWiley VCH Verlag2018-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/87550Moreno Betancourt, Angelica; Schwabedissen, Jan; Romano, Rosana Mariel; Della Védova, Carlos Omar; Beckers, Helmut; et al.; Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon; Wiley VCH Verlag; Chemistry- A European Journal; 24; 4-2018; 10409-104210947-6539CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201800817info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201800817info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)https://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:27:07Zoai:ri.conicet.gov.ar:11336/87550instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:27:08.221CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
title Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
spellingShingle Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
Moreno Betancourt, Angelica
Matrix isolation
Gas Electron Diffraction
Crystal Structure
Polymorphism
title_short Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
title_full Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
title_fullStr Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
title_full_unstemmed Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
title_sort Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon
dc.creator.none.fl_str_mv Moreno Betancourt, Angelica
Schwabedissen, Jan
Romano, Rosana Mariel
Della Védova, Carlos Omar
Beckers, Helmut
Willner, Helge
Stammler, Hans Georg
Mitzel, Norbert Werner
author Moreno Betancourt, Angelica
author_facet Moreno Betancourt, Angelica
Schwabedissen, Jan
Romano, Rosana Mariel
Della Védova, Carlos Omar
Beckers, Helmut
Willner, Helge
Stammler, Hans Georg
Mitzel, Norbert Werner
author_role author
author2 Schwabedissen, Jan
Romano, Rosana Mariel
Della Védova, Carlos Omar
Beckers, Helmut
Willner, Helge
Stammler, Hans Georg
Mitzel, Norbert Werner
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Matrix isolation
Gas Electron Diffraction
Crystal Structure
Polymorphism
topic Matrix isolation
Gas Electron Diffraction
Crystal Structure
Polymorphism
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized byvibrational spectroscopy in the gaseous and liquid phase as well asin the Ar-matrix. By varying the temperature, certain bands could beassigned to several conformers. Gas-phase electron diffractionrevealed a dominance of the anti-conformer at ambient temperature.The same conformation was found in the solid state. Via the in situtechnique for crystallization, not less than four different modificationswere identified. Among these different modifications, the structuralparameters of the molecules remain relatively constant, but theaggregation pattern changes. Although the molecules aggregate bychlorine···oxygen contacts in each modification, the geometricalparameters of these interaction show significant differences andwere evaluated and are in part inconsistent with the halogen bondingconcept.
Fil: Moreno Betancourt, Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Schwabedissen, Jan. Universitat Bielefeld; Alemania
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Beckers, Helmut. Bergische Universität Wuppertal; Alemania
Fil: Willner, Helge. Bergische Universität Wuppertal; Alemania
Fil: Stammler, Hans Georg. Universitat Bielefeld; Alemania
Fil: Mitzel, Norbert Werner. Universitat Bielefeld; Alemania
description Disulfuryl dichloride ClSO 2 OSO 2 Cl was characterized byvibrational spectroscopy in the gaseous and liquid phase as well asin the Ar-matrix. By varying the temperature, certain bands could beassigned to several conformers. Gas-phase electron diffractionrevealed a dominance of the anti-conformer at ambient temperature.The same conformation was found in the solid state. Via the in situtechnique for crystallization, not less than four different modificationswere identified. Among these different modifications, the structuralparameters of the molecules remain relatively constant, but theaggregation pattern changes. Although the molecules aggregate bychlorine···oxygen contacts in each modification, the geometricalparameters of these interaction show significant differences andwere evaluated and are in part inconsistent with the halogen bondingconcept.
publishDate 2018
dc.date.none.fl_str_mv 2018-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/87550
Moreno Betancourt, Angelica; Schwabedissen, Jan; Romano, Rosana Mariel; Della Védova, Carlos Omar; Beckers, Helmut; et al.; Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon; Wiley VCH Verlag; Chemistry- A European Journal; 24; 4-2018; 10409-10421
0947-6539
CONICET Digital
CONICET
url http://hdl.handle.net/11336/87550
identifier_str_mv Moreno Betancourt, Angelica; Schwabedissen, Jan; Romano, Rosana Mariel; Della Védova, Carlos Omar; Beckers, Helmut; et al.; Disulfuryl dichloride ClSO2OSO2Cl: a conformation and polymorphism chameleon; Wiley VCH Verlag; Chemistry- A European Journal; 24; 4-2018; 10409-10421
0947-6539
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201800817
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201800817
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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