Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)

Autores
Traid, Hernán Darío; Vera, Maria Laura; Ares, Alicia Esther; Litter, Marta Irene
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Porous TiO2 coatings were obtained by anodic oxidation in spark discharge conditions, varying the range of current density (200-3000 A m−2) and the electrolyte concentration (H2SO4; 1 and 4 M). The samples were characterized by SEM, XRD and DRS. The photocatalytic activity was evaluated using the Cr(VI)/EDTA reductive system to find the optimal conditions for a high photocatalytic activity. A higher electrolyte concentration increased the pore diameter, the porous fraction and the coating thickness and, consequently, the photocatalytic activity; a higher current density improved the performance of coatings. A relationship between the anatase fraction and the photocatalytic activity of the samples was demonstrated, with a maximum activity close to 0.65 anatase fraction. The thermal treatment of the anodic coatings improved also the photocatalytic activity, without changes on neither the morphology nor the anatase fraction. The maximum Cr(VI) transformation achieved by the most active coating was 89.1% while a coating prepared with Evonik P25 achieved only 69.9%. The obtained TiO2 anodic coatings present great potential for application in heterogeneous photocatalysis processes in water and wastewater treatment as supported photocatalysts.
Fil: Traid, Hernán Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Vera, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Ares, Alicia Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Litter, Marta Irene. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; Argentina
Materia
Tio2 Coatings
Anodic Oxidation
Cr(Vi) Reduction
Heterogeneous Photocatalysis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44438
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/44438
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)Traid, Hernán DaríoVera, Maria LauraAres, Alicia EstherLitter, Marta IreneTio2 CoatingsAnodic OxidationCr(Vi) ReductionHeterogeneous Photocatalysishttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Porous TiO2 coatings were obtained by anodic oxidation in spark discharge conditions, varying the range of current density (200-3000 A m−2) and the electrolyte concentration (H2SO4; 1 and 4 M). The samples were characterized by SEM, XRD and DRS. The photocatalytic activity was evaluated using the Cr(VI)/EDTA reductive system to find the optimal conditions for a high photocatalytic activity. A higher electrolyte concentration increased the pore diameter, the porous fraction and the coating thickness and, consequently, the photocatalytic activity; a higher current density improved the performance of coatings. A relationship between the anatase fraction and the photocatalytic activity of the samples was demonstrated, with a maximum activity close to 0.65 anatase fraction. The thermal treatment of the anodic coatings improved also the photocatalytic activity, without changes on neither the morphology nor the anatase fraction. The maximum Cr(VI) transformation achieved by the most active coating was 89.1% while a coating prepared with Evonik P25 achieved only 69.9%. The obtained TiO2 anodic coatings present great potential for application in heterogeneous photocatalysis processes in water and wastewater treatment as supported photocatalysts.Fil: Traid, Hernán Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Vera, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Ares, Alicia Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Litter, Marta Irene. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; ArgentinaElsevier Science Sa2017-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44438Traid, Hernán Darío; Vera, Maria Laura; Ares, Alicia Esther; Litter, Marta Irene; Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI); Elsevier Science Sa; Materials Chemistry and Physics; 191; 4-2017; 106-1130254-05840254-0584CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058417300603info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2017.01.034info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:05Zoai:ri.conicet.gov.ar:11336/44438instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:05.473CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)
title Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)
spellingShingle Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)
Traid, Hernán Darío
Tio2 Coatings
Anodic Oxidation
Cr(Vi) Reduction
Heterogeneous Photocatalysis
title_short Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)
title_full Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)
title_fullStr Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)
title_full_unstemmed Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)
title_sort Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI)
dc.creator.none.fl_str_mv Traid, Hernán Darío
Vera, Maria Laura
Ares, Alicia Esther
Litter, Marta Irene
author Traid, Hernán Darío
author_facet Traid, Hernán Darío
Vera, Maria Laura
Ares, Alicia Esther
Litter, Marta Irene
author_role author
author2 Vera, Maria Laura
Ares, Alicia Esther
Litter, Marta Irene
author2_role author
author
author
dc.subject.none.fl_str_mv Tio2 Coatings
Anodic Oxidation
Cr(Vi) Reduction
Heterogeneous Photocatalysis
topic Tio2 Coatings
Anodic Oxidation
Cr(Vi) Reduction
Heterogeneous Photocatalysis
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Porous TiO2 coatings were obtained by anodic oxidation in spark discharge conditions, varying the range of current density (200-3000 A m−2) and the electrolyte concentration (H2SO4; 1 and 4 M). The samples were characterized by SEM, XRD and DRS. The photocatalytic activity was evaluated using the Cr(VI)/EDTA reductive system to find the optimal conditions for a high photocatalytic activity. A higher electrolyte concentration increased the pore diameter, the porous fraction and the coating thickness and, consequently, the photocatalytic activity; a higher current density improved the performance of coatings. A relationship between the anatase fraction and the photocatalytic activity of the samples was demonstrated, with a maximum activity close to 0.65 anatase fraction. The thermal treatment of the anodic coatings improved also the photocatalytic activity, without changes on neither the morphology nor the anatase fraction. The maximum Cr(VI) transformation achieved by the most active coating was 89.1% while a coating prepared with Evonik P25 achieved only 69.9%. The obtained TiO2 anodic coatings present great potential for application in heterogeneous photocatalysis processes in water and wastewater treatment as supported photocatalysts.
Fil: Traid, Hernán Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Vera, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Ares, Alicia Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Litter, Marta Irene. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín; Argentina
description Porous TiO2 coatings were obtained by anodic oxidation in spark discharge conditions, varying the range of current density (200-3000 A m−2) and the electrolyte concentration (H2SO4; 1 and 4 M). The samples were characterized by SEM, XRD and DRS. The photocatalytic activity was evaluated using the Cr(VI)/EDTA reductive system to find the optimal conditions for a high photocatalytic activity. A higher electrolyte concentration increased the pore diameter, the porous fraction and the coating thickness and, consequently, the photocatalytic activity; a higher current density improved the performance of coatings. A relationship between the anatase fraction and the photocatalytic activity of the samples was demonstrated, with a maximum activity close to 0.65 anatase fraction. The thermal treatment of the anodic coatings improved also the photocatalytic activity, without changes on neither the morphology nor the anatase fraction. The maximum Cr(VI) transformation achieved by the most active coating was 89.1% while a coating prepared with Evonik P25 achieved only 69.9%. The obtained TiO2 anodic coatings present great potential for application in heterogeneous photocatalysis processes in water and wastewater treatment as supported photocatalysts.
publishDate 2017
dc.date.none.fl_str_mv 2017-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44438
Traid, Hernán Darío; Vera, Maria Laura; Ares, Alicia Esther; Litter, Marta Irene; Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI); Elsevier Science Sa; Materials Chemistry and Physics; 191; 4-2017; 106-113
0254-0584
0254-0584
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44438
identifier_str_mv Traid, Hernán Darío; Vera, Maria Laura; Ares, Alicia Esther; Litter, Marta Irene; Advances on the synthesis of porous TiO2 coatings by anodic spark oxidation: photocatalytic reduction of Cr(VI); Elsevier Science Sa; Materials Chemistry and Physics; 191; 4-2017; 106-113
0254-0584
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058417300603
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2017.01.034
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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