Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control

Autores
Sánchez Arribas, Natalia; Guzmán, Eduardo; Lucia, Alejandro; Toloza, Ariel Ceferino; Velarde, Manuel G.; Ortega, Francisco; Rubio, Ramón G.
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Essential oils are highly volatile and non-water soluble natural products which have shown high efficiency against several insect pests. However, their low solubility in water is an important drawback for their practical applications. This work explores the design of new nanocarriers of eugenol based on silica nanoparticles capped with Pluronic F-127, a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide). Dynamic Light Scattering (DLS) and ζ-potential measurements have shown that particles capped with Pluronic F-127 are able to disperse eugenol between the polymer chains, probably due to the presence of poly(propylene oxide) blocks. Thus, nanocarriers with a structure similar to Pluronic F-127 emulsions supported on silica nanoparticles are formed. These nanocarriers are only stabilized in aqueous medium under conditions in which the ratio between the weight fractions of Pluronic F-127 and eugenol is above 1.5, otherwise phase separation appears within the first 48 h after their preparation. Furthermore, the weight fraction of silica nanoparticles is limited to low values. This work offers new possibilities for designing new aqueous based formulations with application in pests control. The use of aqueous formulations for this purpose is interesting because it makes easy the application process, handling and storage, reducing the hazards for environmental and human health associated with the use of toxic and volatile solvent.
Fil: Sánchez Arribas, Natalia. Universidad Complutense de Madrid; España
Fil: Guzmán, Eduardo. Universidad Complutense de Madrid; España
Fil: Lucia, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; Argentina
Fil: Toloza, Ariel Ceferino. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina
Fil: Velarde, Manuel G.. Universidad Complutense de Madrid; España
Fil: Ortega, Francisco. Universidad Complutense de Madrid; España
Fil: Rubio, Ramón G.. Universidad Complutense de Madrid; España
Materia
Biopesticides
Colloidal Dispersion
Essential Oils
Nanoparticles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/82809
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/82809
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests controlSánchez Arribas, NataliaGuzmán, EduardoLucia, AlejandroToloza, Ariel CeferinoVelarde, Manuel G.Ortega, FranciscoRubio, Ramón G.BiopesticidesColloidal DispersionEssential OilsNanoparticleshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Essential oils are highly volatile and non-water soluble natural products which have shown high efficiency against several insect pests. However, their low solubility in water is an important drawback for their practical applications. This work explores the design of new nanocarriers of eugenol based on silica nanoparticles capped with Pluronic F-127, a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide). Dynamic Light Scattering (DLS) and ζ-potential measurements have shown that particles capped with Pluronic F-127 are able to disperse eugenol between the polymer chains, probably due to the presence of poly(propylene oxide) blocks. Thus, nanocarriers with a structure similar to Pluronic F-127 emulsions supported on silica nanoparticles are formed. These nanocarriers are only stabilized in aqueous medium under conditions in which the ratio between the weight fractions of Pluronic F-127 and eugenol is above 1.5, otherwise phase separation appears within the first 48 h after their preparation. Furthermore, the weight fraction of silica nanoparticles is limited to low values. This work offers new possibilities for designing new aqueous based formulations with application in pests control. The use of aqueous formulations for this purpose is interesting because it makes easy the application process, handling and storage, reducing the hazards for environmental and human health associated with the use of toxic and volatile solvent.Fil: Sánchez Arribas, Natalia. Universidad Complutense de Madrid; EspañaFil: Guzmán, Eduardo. Universidad Complutense de Madrid; EspañaFil: Lucia, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; ArgentinaFil: Toloza, Ariel Ceferino. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; ArgentinaFil: Velarde, Manuel G.. Universidad Complutense de Madrid; EspañaFil: Ortega, Francisco. Universidad Complutense de Madrid; EspañaFil: Rubio, Ramón G.. Universidad Complutense de Madrid; EspañaElsevier Science2018-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/82809Sánchez Arribas, Natalia; Guzmán, Eduardo; Lucia, Alejandro; Toloza, Ariel Ceferino; Velarde, Manuel G.; et al.; Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 555; 10-2018; 473-4810927-7757CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0927775718306319info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2018.07.028info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:01:47Zoai:ri.conicet.gov.ar:11336/82809instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:01:47.796CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
title Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
spellingShingle Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
Sánchez Arribas, Natalia
Biopesticides
Colloidal Dispersion
Essential Oils
Nanoparticles
title_short Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
title_full Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
title_fullStr Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
title_full_unstemmed Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
title_sort Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
dc.creator.none.fl_str_mv Sánchez Arribas, Natalia
Guzmán, Eduardo
Lucia, Alejandro
Toloza, Ariel Ceferino
Velarde, Manuel G.
Ortega, Francisco
Rubio, Ramón G.
author Sánchez Arribas, Natalia
author_facet Sánchez Arribas, Natalia
Guzmán, Eduardo
Lucia, Alejandro
Toloza, Ariel Ceferino
Velarde, Manuel G.
Ortega, Francisco
Rubio, Ramón G.
author_role author
author2 Guzmán, Eduardo
Lucia, Alejandro
Toloza, Ariel Ceferino
Velarde, Manuel G.
Ortega, Francisco
Rubio, Ramón G.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Biopesticides
Colloidal Dispersion
Essential Oils
Nanoparticles
topic Biopesticides
Colloidal Dispersion
Essential Oils
Nanoparticles
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Essential oils are highly volatile and non-water soluble natural products which have shown high efficiency against several insect pests. However, their low solubility in water is an important drawback for their practical applications. This work explores the design of new nanocarriers of eugenol based on silica nanoparticles capped with Pluronic F-127, a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide). Dynamic Light Scattering (DLS) and ζ-potential measurements have shown that particles capped with Pluronic F-127 are able to disperse eugenol between the polymer chains, probably due to the presence of poly(propylene oxide) blocks. Thus, nanocarriers with a structure similar to Pluronic F-127 emulsions supported on silica nanoparticles are formed. These nanocarriers are only stabilized in aqueous medium under conditions in which the ratio between the weight fractions of Pluronic F-127 and eugenol is above 1.5, otherwise phase separation appears within the first 48 h after their preparation. Furthermore, the weight fraction of silica nanoparticles is limited to low values. This work offers new possibilities for designing new aqueous based formulations with application in pests control. The use of aqueous formulations for this purpose is interesting because it makes easy the application process, handling and storage, reducing the hazards for environmental and human health associated with the use of toxic and volatile solvent.
Fil: Sánchez Arribas, Natalia. Universidad Complutense de Madrid; España
Fil: Guzmán, Eduardo. Universidad Complutense de Madrid; España
Fil: Lucia, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; Argentina
Fil: Toloza, Ariel Ceferino. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina
Fil: Velarde, Manuel G.. Universidad Complutense de Madrid; España
Fil: Ortega, Francisco. Universidad Complutense de Madrid; España
Fil: Rubio, Ramón G.. Universidad Complutense de Madrid; España
description Essential oils are highly volatile and non-water soluble natural products which have shown high efficiency against several insect pests. However, their low solubility in water is an important drawback for their practical applications. This work explores the design of new nanocarriers of eugenol based on silica nanoparticles capped with Pluronic F-127, a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide). Dynamic Light Scattering (DLS) and ζ-potential measurements have shown that particles capped with Pluronic F-127 are able to disperse eugenol between the polymer chains, probably due to the presence of poly(propylene oxide) blocks. Thus, nanocarriers with a structure similar to Pluronic F-127 emulsions supported on silica nanoparticles are formed. These nanocarriers are only stabilized in aqueous medium under conditions in which the ratio between the weight fractions of Pluronic F-127 and eugenol is above 1.5, otherwise phase separation appears within the first 48 h after their preparation. Furthermore, the weight fraction of silica nanoparticles is limited to low values. This work offers new possibilities for designing new aqueous based formulations with application in pests control. The use of aqueous formulations for this purpose is interesting because it makes easy the application process, handling and storage, reducing the hazards for environmental and human health associated with the use of toxic and volatile solvent.
publishDate 2018
dc.date.none.fl_str_mv 2018-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/82809
Sánchez Arribas, Natalia; Guzmán, Eduardo; Lucia, Alejandro; Toloza, Ariel Ceferino; Velarde, Manuel G.; et al.; Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 555; 10-2018; 473-481
0927-7757
CONICET Digital
CONICET
url http://hdl.handle.net/11336/82809
identifier_str_mv Sánchez Arribas, Natalia; Guzmán, Eduardo; Lucia, Alejandro; Toloza, Ariel Ceferino; Velarde, Manuel G.; et al.; Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 555; 10-2018; 473-481
0927-7757
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0927775718306319
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2018.07.028
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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