Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control
- Autores
- Sánchez Arribas, Natalia; Guzmán, Eduardo; Lucia, Alejandro; Toloza, Ariel Ceferino; Velarde, Manuel G.; Ortega, Francisco; Rubio, Ramón G.
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Essential oils are highly volatile and non-water soluble natural products which have shown high efficiency against several insect pests. However, their low solubility in water is an important drawback for their practical applications. This work explores the design of new nanocarriers of eugenol based on silica nanoparticles capped with Pluronic F-127, a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide). Dynamic Light Scattering (DLS) and ζ-potential measurements have shown that particles capped with Pluronic F-127 are able to disperse eugenol between the polymer chains, probably due to the presence of poly(propylene oxide) blocks. Thus, nanocarriers with a structure similar to Pluronic F-127 emulsions supported on silica nanoparticles are formed. These nanocarriers are only stabilized in aqueous medium under conditions in which the ratio between the weight fractions of Pluronic F-127 and eugenol is above 1.5, otherwise phase separation appears within the first 48 h after their preparation. Furthermore, the weight fraction of silica nanoparticles is limited to low values. This work offers new possibilities for designing new aqueous based formulations with application in pests control. The use of aqueous formulations for this purpose is interesting because it makes easy the application process, handling and storage, reducing the hazards for environmental and human health associated with the use of toxic and volatile solvent.
Fil: Sánchez Arribas, Natalia. Universidad Complutense de Madrid; España
Fil: Guzmán, Eduardo. Universidad Complutense de Madrid; España
Fil: Lucia, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; Argentina
Fil: Toloza, Ariel Ceferino. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina
Fil: Velarde, Manuel G.. Universidad Complutense de Madrid; España
Fil: Ortega, Francisco. Universidad Complutense de Madrid; España
Fil: Rubio, Ramón G.. Universidad Complutense de Madrid; España - Materia
-
Biopesticides
Colloidal Dispersion
Essential Oils
Nanoparticles - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/82809
Ver los metadatos del registro completo
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Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests controlSánchez Arribas, NataliaGuzmán, EduardoLucia, AlejandroToloza, Ariel CeferinoVelarde, Manuel G.Ortega, FranciscoRubio, Ramón G.BiopesticidesColloidal DispersionEssential OilsNanoparticleshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Essential oils are highly volatile and non-water soluble natural products which have shown high efficiency against several insect pests. However, their low solubility in water is an important drawback for their practical applications. This work explores the design of new nanocarriers of eugenol based on silica nanoparticles capped with Pluronic F-127, a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide). Dynamic Light Scattering (DLS) and ζ-potential measurements have shown that particles capped with Pluronic F-127 are able to disperse eugenol between the polymer chains, probably due to the presence of poly(propylene oxide) blocks. Thus, nanocarriers with a structure similar to Pluronic F-127 emulsions supported on silica nanoparticles are formed. These nanocarriers are only stabilized in aqueous medium under conditions in which the ratio between the weight fractions of Pluronic F-127 and eugenol is above 1.5, otherwise phase separation appears within the first 48 h after their preparation. Furthermore, the weight fraction of silica nanoparticles is limited to low values. This work offers new possibilities for designing new aqueous based formulations with application in pests control. The use of aqueous formulations for this purpose is interesting because it makes easy the application process, handling and storage, reducing the hazards for environmental and human health associated with the use of toxic and volatile solvent.Fil: Sánchez Arribas, Natalia. Universidad Complutense de Madrid; EspañaFil: Guzmán, Eduardo. Universidad Complutense de Madrid; EspañaFil: Lucia, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; ArgentinaFil: Toloza, Ariel Ceferino. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; ArgentinaFil: Velarde, Manuel G.. Universidad Complutense de Madrid; EspañaFil: Ortega, Francisco. Universidad Complutense de Madrid; EspañaFil: Rubio, Ramón G.. Universidad Complutense de Madrid; EspañaElsevier Science2018-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/82809Sánchez Arribas, Natalia; Guzmán, Eduardo; Lucia, Alejandro; Toloza, Ariel Ceferino; Velarde, Manuel G.; et al.; Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 555; 10-2018; 473-4810927-7757CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0927775718306319info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2018.07.028info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:46Zoai:ri.conicet.gov.ar:11336/82809instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:46.599CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control |
title |
Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control |
spellingShingle |
Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control Sánchez Arribas, Natalia Biopesticides Colloidal Dispersion Essential Oils Nanoparticles |
title_short |
Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control |
title_full |
Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control |
title_fullStr |
Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control |
title_full_unstemmed |
Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control |
title_sort |
Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control |
dc.creator.none.fl_str_mv |
Sánchez Arribas, Natalia Guzmán, Eduardo Lucia, Alejandro Toloza, Ariel Ceferino Velarde, Manuel G. Ortega, Francisco Rubio, Ramón G. |
author |
Sánchez Arribas, Natalia |
author_facet |
Sánchez Arribas, Natalia Guzmán, Eduardo Lucia, Alejandro Toloza, Ariel Ceferino Velarde, Manuel G. Ortega, Francisco Rubio, Ramón G. |
author_role |
author |
author2 |
Guzmán, Eduardo Lucia, Alejandro Toloza, Ariel Ceferino Velarde, Manuel G. Ortega, Francisco Rubio, Ramón G. |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Biopesticides Colloidal Dispersion Essential Oils Nanoparticles |
topic |
Biopesticides Colloidal Dispersion Essential Oils Nanoparticles |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Essential oils are highly volatile and non-water soluble natural products which have shown high efficiency against several insect pests. However, their low solubility in water is an important drawback for their practical applications. This work explores the design of new nanocarriers of eugenol based on silica nanoparticles capped with Pluronic F-127, a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide). Dynamic Light Scattering (DLS) and ζ-potential measurements have shown that particles capped with Pluronic F-127 are able to disperse eugenol between the polymer chains, probably due to the presence of poly(propylene oxide) blocks. Thus, nanocarriers with a structure similar to Pluronic F-127 emulsions supported on silica nanoparticles are formed. These nanocarriers are only stabilized in aqueous medium under conditions in which the ratio between the weight fractions of Pluronic F-127 and eugenol is above 1.5, otherwise phase separation appears within the first 48 h after their preparation. Furthermore, the weight fraction of silica nanoparticles is limited to low values. This work offers new possibilities for designing new aqueous based formulations with application in pests control. The use of aqueous formulations for this purpose is interesting because it makes easy the application process, handling and storage, reducing the hazards for environmental and human health associated with the use of toxic and volatile solvent. Fil: Sánchez Arribas, Natalia. Universidad Complutense de Madrid; España Fil: Guzmán, Eduardo. Universidad Complutense de Madrid; España Fil: Lucia, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; Argentina Fil: Toloza, Ariel Ceferino. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas para la Defensa. Centro de Investigación de Plagas e Insecticidas; Argentina Fil: Velarde, Manuel G.. Universidad Complutense de Madrid; España Fil: Ortega, Francisco. Universidad Complutense de Madrid; España Fil: Rubio, Ramón G.. Universidad Complutense de Madrid; España |
description |
Essential oils are highly volatile and non-water soluble natural products which have shown high efficiency against several insect pests. However, their low solubility in water is an important drawback for their practical applications. This work explores the design of new nanocarriers of eugenol based on silica nanoparticles capped with Pluronic F-127, a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide). Dynamic Light Scattering (DLS) and ζ-potential measurements have shown that particles capped with Pluronic F-127 are able to disperse eugenol between the polymer chains, probably due to the presence of poly(propylene oxide) blocks. Thus, nanocarriers with a structure similar to Pluronic F-127 emulsions supported on silica nanoparticles are formed. These nanocarriers are only stabilized in aqueous medium under conditions in which the ratio between the weight fractions of Pluronic F-127 and eugenol is above 1.5, otherwise phase separation appears within the first 48 h after their preparation. Furthermore, the weight fraction of silica nanoparticles is limited to low values. This work offers new possibilities for designing new aqueous based formulations with application in pests control. The use of aqueous formulations for this purpose is interesting because it makes easy the application process, handling and storage, reducing the hazards for environmental and human health associated with the use of toxic and volatile solvent. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-10 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/82809 Sánchez Arribas, Natalia; Guzmán, Eduardo; Lucia, Alejandro; Toloza, Ariel Ceferino; Velarde, Manuel G.; et al.; Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 555; 10-2018; 473-481 0927-7757 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/82809 |
identifier_str_mv |
Sánchez Arribas, Natalia; Guzmán, Eduardo; Lucia, Alejandro; Toloza, Ariel Ceferino; Velarde, Manuel G.; et al.; Environmentally friendly platforms for encapsulation of an essential oil: Fabrication, characterization and application in pests control; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 555; 10-2018; 473-481 0927-7757 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0927775718306319 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2018.07.028 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613040398401536 |
score |
13.070432 |