One-step preparation of UV transparent highly ordered mesoporous zirconia thin films

Autores
Zelcer, Andrés; Soler Illia, Galo Juan de Avila Arturo
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Highly ordered mesoporous ZrO2 thin films were prepared by evaporation induced self-assembly. Complexing agents and low pH were simultaneously employed in order to control the hydrolysis-condensation kinetics, permitting to cast films in one step. Many commercially available PPO-based surfactants can be used as templates, yielding different pore sizes. The mesoporosity is well preserved at high temperatures (600 °C) and after exposing the films to extreme alkaline conditions (1 M NaOH, 18 h). The procedure has been used to cast multilayer films, paving the way to mesoporous thin films-based UV photonics. © The Royal Society of Chemistry 2013.
Fil: Zelcer, Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina
Materia
Mesoporous Thin Films
Zirconia
Multilayer Thin Films
Acetylacetonate
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/77856
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling One-step preparation of UV transparent highly ordered mesoporous zirconia thin filmsZelcer, AndrésSoler Illia, Galo Juan de Avila ArturoMesoporous Thin FilmsZirconiaMultilayer Thin FilmsAcetylacetonatehttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Highly ordered mesoporous ZrO2 thin films were prepared by evaporation induced self-assembly. Complexing agents and low pH were simultaneously employed in order to control the hydrolysis-condensation kinetics, permitting to cast films in one step. Many commercially available PPO-based surfactants can be used as templates, yielding different pore sizes. The mesoporosity is well preserved at high temperatures (600 °C) and after exposing the films to extreme alkaline conditions (1 M NaOH, 18 h). The procedure has been used to cast multilayer films, paving the way to mesoporous thin films-based UV photonics. © The Royal Society of Chemistry 2013.Fil: Zelcer, Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaRoyal Society of Chemistry2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/77856Zelcer, Andrés; Soler Illia, Galo Juan de Avila Arturo; One-step preparation of UV transparent highly ordered mesoporous zirconia thin films; Royal Society of Chemistry; Journal of Materials Chemistry C; 1; 7; 1-2013; 1359-13672050-7526CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2013/TC/c2tc00319hinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C2TC00319Hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:56:16Zoai:ri.conicet.gov.ar:11336/77856instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:56:16.682CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
spellingShingle One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
Zelcer, Andrés
Mesoporous Thin Films
Zirconia
Multilayer Thin Films
Acetylacetonate
title_short One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title_full One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title_fullStr One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title_full_unstemmed One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title_sort One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
dc.creator.none.fl_str_mv Zelcer, Andrés
Soler Illia, Galo Juan de Avila Arturo
author Zelcer, Andrés
author_facet Zelcer, Andrés
Soler Illia, Galo Juan de Avila Arturo
author_role author
author2 Soler Illia, Galo Juan de Avila Arturo
author2_role author
dc.subject.none.fl_str_mv Mesoporous Thin Films
Zirconia
Multilayer Thin Films
Acetylacetonate
topic Mesoporous Thin Films
Zirconia
Multilayer Thin Films
Acetylacetonate
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Highly ordered mesoporous ZrO2 thin films were prepared by evaporation induced self-assembly. Complexing agents and low pH were simultaneously employed in order to control the hydrolysis-condensation kinetics, permitting to cast films in one step. Many commercially available PPO-based surfactants can be used as templates, yielding different pore sizes. The mesoporosity is well preserved at high temperatures (600 °C) and after exposing the films to extreme alkaline conditions (1 M NaOH, 18 h). The procedure has been used to cast multilayer films, paving the way to mesoporous thin films-based UV photonics. © The Royal Society of Chemistry 2013.
Fil: Zelcer, Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina
description Highly ordered mesoporous ZrO2 thin films were prepared by evaporation induced self-assembly. Complexing agents and low pH were simultaneously employed in order to control the hydrolysis-condensation kinetics, permitting to cast films in one step. Many commercially available PPO-based surfactants can be used as templates, yielding different pore sizes. The mesoporosity is well preserved at high temperatures (600 °C) and after exposing the films to extreme alkaline conditions (1 M NaOH, 18 h). The procedure has been used to cast multilayer films, paving the way to mesoporous thin films-based UV photonics. © The Royal Society of Chemistry 2013.
publishDate 2013
dc.date.none.fl_str_mv 2013-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/77856
Zelcer, Andrés; Soler Illia, Galo Juan de Avila Arturo; One-step preparation of UV transparent highly ordered mesoporous zirconia thin films; Royal Society of Chemistry; Journal of Materials Chemistry C; 1; 7; 1-2013; 1359-1367
2050-7526
CONICET Digital
CONICET
url http://hdl.handle.net/11336/77856
identifier_str_mv Zelcer, Andrés; Soler Illia, Galo Juan de Avila Arturo; One-step preparation of UV transparent highly ordered mesoporous zirconia thin films; Royal Society of Chemistry; Journal of Materials Chemistry C; 1; 7; 1-2013; 1359-1367
2050-7526
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2013/TC/c2tc00319h
info:eu-repo/semantics/altIdentifier/doi/10.1039/C2TC00319H
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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