Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry

Autores
Ruiz Díaz, Juan Daniel; Savio, Marianela; Moyano, Mario Franco; Verni, Ernesto E.; Martinez, Luis Dante; Gil, Raul Andres
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A novel, simple, and rapid method is presented for vegetable oil sample analysis by inductively coupled plasma mass spectrometry (ICP-MS) after sample solubilization with tetrabutylammonium hydroxide (TBAH) in an ultrasonic bath. Sample introduction was accomplished after dilution in water with a high-performance microconcentric nebulizer and a cooled spray chamber. The sample was mixed with TBAH, kept in an ultrasonic bath with heat for half an hour, and then diluted with nitric acid to form an aqueous solution. External calibration against aqueous standard solutions, without TBAH, could be used for quantification of a reduced number of elements. However, external calibration with TBAH allowed the determination of all analytes with good accuracy. Comparison of obtained results with a microwave-assisted digestion was performed by linear regressions.
Fil: Ruiz Díaz, Juan Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Savio, Marianela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Moyano, Mario Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Verni, Ernesto E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Materia
Ultrasonic-Assisted Dissolution
Vegetable Oils
Tetrabuthylammonium Hydroxide
Icpms
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/7486
Acceder
id CONICETDig_7b8d4cccc4300d85e1aefcc8c1bfb4e1
oai_identifier_str oai:ri.conicet.gov.ar:11336/7486
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass SpectrometryRuiz Díaz, Juan DanielSavio, MarianelaMoyano, Mario FrancoVerni, Ernesto E.Martinez, Luis DanteGil, Raul AndresUltrasonic-Assisted DissolutionVegetable OilsTetrabuthylammonium HydroxideIcpmshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A novel, simple, and rapid method is presented for vegetable oil sample analysis by inductively coupled plasma mass spectrometry (ICP-MS) after sample solubilization with tetrabutylammonium hydroxide (TBAH) in an ultrasonic bath. Sample introduction was accomplished after dilution in water with a high-performance microconcentric nebulizer and a cooled spray chamber. The sample was mixed with TBAH, kept in an ultrasonic bath with heat for half an hour, and then diluted with nitric acid to form an aqueous solution. External calibration against aqueous standard solutions, without TBAH, could be used for quantification of a reduced number of elements. However, external calibration with TBAH allowed the determination of all analytes with good accuracy. Comparison of obtained results with a microwave-assisted digestion was performed by linear regressions.Fil: Ruiz Díaz, Juan Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Savio, Marianela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Moyano, Mario Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Verni, Ernesto E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaPerkinElmer Inc.2015-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/pdfhttp://hdl.handle.net/11336/7486Ruiz Díaz, Juan Daniel; Savio, Marianela; Moyano, Mario Franco; Verni, Ernesto E.; Martinez, Luis Dante; et al.; Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry; PerkinElmer Inc.; Atomic Spectroscopy; 36; 3-2015; 55-620195-5373enginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:04:03Zoai:ri.conicet.gov.ar:11336/7486instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:04:03.805CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry
title Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry
spellingShingle Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry
Ruiz Díaz, Juan Daniel
Ultrasonic-Assisted Dissolution
Vegetable Oils
Tetrabuthylammonium Hydroxide
Icpms
title_short Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry
title_full Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry
title_fullStr Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry
title_full_unstemmed Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry
title_sort Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry
dc.creator.none.fl_str_mv Ruiz Díaz, Juan Daniel
Savio, Marianela
Moyano, Mario Franco
Verni, Ernesto E.
Martinez, Luis Dante
Gil, Raul Andres
author Ruiz Díaz, Juan Daniel
author_facet Ruiz Díaz, Juan Daniel
Savio, Marianela
Moyano, Mario Franco
Verni, Ernesto E.
Martinez, Luis Dante
Gil, Raul Andres
author_role author
author2 Savio, Marianela
Moyano, Mario Franco
Verni, Ernesto E.
Martinez, Luis Dante
Gil, Raul Andres
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Ultrasonic-Assisted Dissolution
Vegetable Oils
Tetrabuthylammonium Hydroxide
Icpms
topic Ultrasonic-Assisted Dissolution
Vegetable Oils
Tetrabuthylammonium Hydroxide
Icpms
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A novel, simple, and rapid method is presented for vegetable oil sample analysis by inductively coupled plasma mass spectrometry (ICP-MS) after sample solubilization with tetrabutylammonium hydroxide (TBAH) in an ultrasonic bath. Sample introduction was accomplished after dilution in water with a high-performance microconcentric nebulizer and a cooled spray chamber. The sample was mixed with TBAH, kept in an ultrasonic bath with heat for half an hour, and then diluted with nitric acid to form an aqueous solution. External calibration against aqueous standard solutions, without TBAH, could be used for quantification of a reduced number of elements. However, external calibration with TBAH allowed the determination of all analytes with good accuracy. Comparison of obtained results with a microwave-assisted digestion was performed by linear regressions.
Fil: Ruiz Díaz, Juan Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Savio, Marianela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Moyano, Mario Franco. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Verni, Ernesto E.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
description A novel, simple, and rapid method is presented for vegetable oil sample analysis by inductively coupled plasma mass spectrometry (ICP-MS) after sample solubilization with tetrabutylammonium hydroxide (TBAH) in an ultrasonic bath. Sample introduction was accomplished after dilution in water with a high-performance microconcentric nebulizer and a cooled spray chamber. The sample was mixed with TBAH, kept in an ultrasonic bath with heat for half an hour, and then diluted with nitric acid to form an aqueous solution. External calibration against aqueous standard solutions, without TBAH, could be used for quantification of a reduced number of elements. However, external calibration with TBAH allowed the determination of all analytes with good accuracy. Comparison of obtained results with a microwave-assisted digestion was performed by linear regressions.
publishDate 2015
dc.date.none.fl_str_mv 2015-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/7486
Ruiz Díaz, Juan Daniel; Savio, Marianela; Moyano, Mario Franco; Verni, Ernesto E.; Martinez, Luis Dante; et al.; Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry; PerkinElmer Inc.; Atomic Spectroscopy; 36; 3-2015; 55-62
0195-5373
url http://hdl.handle.net/11336/7486
identifier_str_mv Ruiz Díaz, Juan Daniel; Savio, Marianela; Moyano, Mario Franco; Verni, Ernesto E.; Martinez, Luis Dante; et al.; Ultrasonic-assisted Dissolution of Vegetable Oils With Tetrabuthylammonium Hydroxide for Multielemental Analysis by Inductively Coupled Plasma Mass Spectrometry; PerkinElmer Inc.; Atomic Spectroscopy; 36; 3-2015; 55-62
0195-5373
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/vnd.openxmlformats-officedocument.wordprocessingml.document
application/vnd.openxmlformats-officedocument.wordprocessingml.document
application/pdf
dc.publisher.none.fl_str_mv PerkinElmer Inc.
publisher.none.fl_str_mv PerkinElmer Inc.
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269834568531968
score 13.13397

Publicaciones similares