The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spect...
- Autores
- Minaberry, Yanina Susana; Gordillo, Gabriel Jorge
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Natural water carrying a great amount of suspended particulate matter (SPM) was used as a model system for the study of the competition among organic ligands (dietilentetraamine pentaacetic acid, DTPA, nitrilotriacetic acid, NTA, and citrate, Cit) and natural complexants (SPM) for cadmium adsorption. Speciation diagrams at the pH of the natural sample were obtained by electroanalytical techniques, processing the experimental data with the complexation constants and the mass balance of the system. Results show that the adsorption equilibrium SPM-Cd is completely displaced by DTPA but not completely by NTA or Cit. Furthermore, larger Cit concentrations increase the amount of adsorbed Cd(II). The increment of the complexing capacity may be explained on the basis of SPM-Cit-Cd ternary complexes formation. This hypothesis was supported on the results obtained by applying for the first time the MALDI–TOF technique in a mixture of SPM, Cd(II), organic ligands and their complexes.
Fil: Minaberry, Yanina Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Gordillo, Gabriel Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina - Materia
-
Cadmium
Competitive adsorption
Suspended particulate matter
Organic ligands
Natural water - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/102604
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spelling |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methodsMinaberry, Yanina SusanaGordillo, Gabriel JorgeCadmiumCompetitive adsorptionSuspended particulate matterOrganic ligandsNatural waterhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Natural water carrying a great amount of suspended particulate matter (SPM) was used as a model system for the study of the competition among organic ligands (dietilentetraamine pentaacetic acid, DTPA, nitrilotriacetic acid, NTA, and citrate, Cit) and natural complexants (SPM) for cadmium adsorption. Speciation diagrams at the pH of the natural sample were obtained by electroanalytical techniques, processing the experimental data with the complexation constants and the mass balance of the system. Results show that the adsorption equilibrium SPM-Cd is completely displaced by DTPA but not completely by NTA or Cit. Furthermore, larger Cit concentrations increase the amount of adsorbed Cd(II). The increment of the complexing capacity may be explained on the basis of SPM-Cit-Cd ternary complexes formation. This hypothesis was supported on the results obtained by applying for the first time the MALDI–TOF technique in a mixture of SPM, Cd(II), organic ligands and their complexes.Fil: Minaberry, Yanina Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Gordillo, Gabriel Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaPergamon-Elsevier Science Ltd2010-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/102604Minaberry, Yanina Susana; Gordillo, Gabriel Jorge; The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods; Pergamon-Elsevier Science Ltd; Chemosphere; 78; 11; 3-2010; 1356-13610045-6535CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemosphere.2010.01.004info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0045653510000226info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:45:04Zoai:ri.conicet.gov.ar:11336/102604instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:45:05.263CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods |
title |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods |
spellingShingle |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods Minaberry, Yanina Susana Cadmium Competitive adsorption Suspended particulate matter Organic ligands Natural water |
title_short |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods |
title_full |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods |
title_fullStr |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods |
title_full_unstemmed |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods |
title_sort |
The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods |
dc.creator.none.fl_str_mv |
Minaberry, Yanina Susana Gordillo, Gabriel Jorge |
author |
Minaberry, Yanina Susana |
author_facet |
Minaberry, Yanina Susana Gordillo, Gabriel Jorge |
author_role |
author |
author2 |
Gordillo, Gabriel Jorge |
author2_role |
author |
dc.subject.none.fl_str_mv |
Cadmium Competitive adsorption Suspended particulate matter Organic ligands Natural water |
topic |
Cadmium Competitive adsorption Suspended particulate matter Organic ligands Natural water |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Natural water carrying a great amount of suspended particulate matter (SPM) was used as a model system for the study of the competition among organic ligands (dietilentetraamine pentaacetic acid, DTPA, nitrilotriacetic acid, NTA, and citrate, Cit) and natural complexants (SPM) for cadmium adsorption. Speciation diagrams at the pH of the natural sample were obtained by electroanalytical techniques, processing the experimental data with the complexation constants and the mass balance of the system. Results show that the adsorption equilibrium SPM-Cd is completely displaced by DTPA but not completely by NTA or Cit. Furthermore, larger Cit concentrations increase the amount of adsorbed Cd(II). The increment of the complexing capacity may be explained on the basis of SPM-Cit-Cd ternary complexes formation. This hypothesis was supported on the results obtained by applying for the first time the MALDI–TOF technique in a mixture of SPM, Cd(II), organic ligands and their complexes. Fil: Minaberry, Yanina Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina Fil: Gordillo, Gabriel Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina |
description |
Natural water carrying a great amount of suspended particulate matter (SPM) was used as a model system for the study of the competition among organic ligands (dietilentetraamine pentaacetic acid, DTPA, nitrilotriacetic acid, NTA, and citrate, Cit) and natural complexants (SPM) for cadmium adsorption. Speciation diagrams at the pH of the natural sample were obtained by electroanalytical techniques, processing the experimental data with the complexation constants and the mass balance of the system. Results show that the adsorption equilibrium SPM-Cd is completely displaced by DTPA but not completely by NTA or Cit. Furthermore, larger Cit concentrations increase the amount of adsorbed Cd(II). The increment of the complexing capacity may be explained on the basis of SPM-Cit-Cd ternary complexes formation. This hypothesis was supported on the results obtained by applying for the first time the MALDI–TOF technique in a mixture of SPM, Cd(II), organic ligands and their complexes. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/102604 Minaberry, Yanina Susana; Gordillo, Gabriel Jorge; The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods; Pergamon-Elsevier Science Ltd; Chemosphere; 78; 11; 3-2010; 1356-1361 0045-6535 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/102604 |
identifier_str_mv |
Minaberry, Yanina Susana; Gordillo, Gabriel Jorge; The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods; Pergamon-Elsevier Science Ltd; Chemosphere; 78; 11; 3-2010; 1356-1361 0045-6535 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemosphere.2010.01.004 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0045653510000226 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd |
publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614489770557440 |
score |
13.070432 |