The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spect...

Autores
Minaberry, Yanina Susana; Gordillo, Gabriel Jorge
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Natural water carrying a great amount of suspended particulate matter (SPM) was used as a model system for the study of the competition among organic ligands (dietilentetraamine pentaacetic acid, DTPA, nitrilotriacetic acid, NTA, and citrate, Cit) and natural complexants (SPM) for cadmium adsorption. Speciation diagrams at the pH of the natural sample were obtained by electroanalytical techniques, processing the experimental data with the complexation constants and the mass balance of the system. Results show that the adsorption equilibrium SPM-Cd is completely displaced by DTPA but not completely by NTA or Cit. Furthermore, larger Cit concentrations increase the amount of adsorbed Cd(II). The increment of the complexing capacity may be explained on the basis of SPM-Cit-Cd ternary complexes formation. This hypothesis was supported on the results obtained by applying for the first time the MALDI–TOF technique in a mixture of SPM, Cd(II), organic ligands and their complexes.
Fil: Minaberry, Yanina Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Gordillo, Gabriel Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
Cadmium
Competitive adsorption
Suspended particulate matter
Organic ligands
Natural water
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/102604
Acceder
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network_name_str CONICET Digital (CONICET)
spelling The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methodsMinaberry, Yanina SusanaGordillo, Gabriel JorgeCadmiumCompetitive adsorptionSuspended particulate matterOrganic ligandsNatural waterhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Natural water carrying a great amount of suspended particulate matter (SPM) was used as a model system for the study of the competition among organic ligands (dietilentetraamine pentaacetic acid, DTPA, nitrilotriacetic acid, NTA, and citrate, Cit) and natural complexants (SPM) for cadmium adsorption. Speciation diagrams at the pH of the natural sample were obtained by electroanalytical techniques, processing the experimental data with the complexation constants and the mass balance of the system. Results show that the adsorption equilibrium SPM-Cd is completely displaced by DTPA but not completely by NTA or Cit. Furthermore, larger Cit concentrations increase the amount of adsorbed Cd(II). The increment of the complexing capacity may be explained on the basis of SPM-Cit-Cd ternary complexes formation. This hypothesis was supported on the results obtained by applying for the first time the MALDI–TOF technique in a mixture of SPM, Cd(II), organic ligands and their complexes.Fil: Minaberry, Yanina Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Gordillo, Gabriel Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaPergamon-Elsevier Science Ltd2010-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/102604Minaberry, Yanina Susana; Gordillo, Gabriel Jorge; The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods; Pergamon-Elsevier Science Ltd; Chemosphere; 78; 11; 3-2010; 1356-13610045-6535CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemosphere.2010.01.004info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0045653510000226info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:43:33Zoai:ri.conicet.gov.ar:11336/102604instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:43:33.969CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods
title The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods
spellingShingle The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods
Minaberry, Yanina Susana
Cadmium
Competitive adsorption
Suspended particulate matter
Organic ligands
Natural water
title_short The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods
title_full The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods
title_fullStr The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods
title_full_unstemmed The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods
title_sort The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods
dc.creator.none.fl_str_mv Minaberry, Yanina Susana
Gordillo, Gabriel Jorge
author Minaberry, Yanina Susana
author_facet Minaberry, Yanina Susana
Gordillo, Gabriel Jorge
author_role author
author2 Gordillo, Gabriel Jorge
author2_role author
dc.subject.none.fl_str_mv Cadmium
Competitive adsorption
Suspended particulate matter
Organic ligands
Natural water
topic Cadmium
Competitive adsorption
Suspended particulate matter
Organic ligands
Natural water
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Natural water carrying a great amount of suspended particulate matter (SPM) was used as a model system for the study of the competition among organic ligands (dietilentetraamine pentaacetic acid, DTPA, nitrilotriacetic acid, NTA, and citrate, Cit) and natural complexants (SPM) for cadmium adsorption. Speciation diagrams at the pH of the natural sample were obtained by electroanalytical techniques, processing the experimental data with the complexation constants and the mass balance of the system. Results show that the adsorption equilibrium SPM-Cd is completely displaced by DTPA but not completely by NTA or Cit. Furthermore, larger Cit concentrations increase the amount of adsorbed Cd(II). The increment of the complexing capacity may be explained on the basis of SPM-Cit-Cd ternary complexes formation. This hypothesis was supported on the results obtained by applying for the first time the MALDI–TOF technique in a mixture of SPM, Cd(II), organic ligands and their complexes.
Fil: Minaberry, Yanina Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Gordillo, Gabriel Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description Natural water carrying a great amount of suspended particulate matter (SPM) was used as a model system for the study of the competition among organic ligands (dietilentetraamine pentaacetic acid, DTPA, nitrilotriacetic acid, NTA, and citrate, Cit) and natural complexants (SPM) for cadmium adsorption. Speciation diagrams at the pH of the natural sample were obtained by electroanalytical techniques, processing the experimental data with the complexation constants and the mass balance of the system. Results show that the adsorption equilibrium SPM-Cd is completely displaced by DTPA but not completely by NTA or Cit. Furthermore, larger Cit concentrations increase the amount of adsorbed Cd(II). The increment of the complexing capacity may be explained on the basis of SPM-Cit-Cd ternary complexes formation. This hypothesis was supported on the results obtained by applying for the first time the MALDI–TOF technique in a mixture of SPM, Cd(II), organic ligands and their complexes.
publishDate 2010
dc.date.none.fl_str_mv 2010-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/102604
Minaberry, Yanina Susana; Gordillo, Gabriel Jorge; The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods; Pergamon-Elsevier Science Ltd; Chemosphere; 78; 11; 3-2010; 1356-1361
0045-6535
CONICET Digital
CONICET
url http://hdl.handle.net/11336/102604
identifier_str_mv Minaberry, Yanina Susana; Gordillo, Gabriel Jorge; The influence of organic ligands on the adsorption of cadmium by suspended matter in natural waters studied by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and electrochemical methods; Pergamon-Elsevier Science Ltd; Chemosphere; 78; 11; 3-2010; 1356-1361
0045-6535
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemosphere.2010.01.004
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0045653510000226
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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