Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques
- Autores
- Ballarre, Josefina; Jimenez Pique, Emilio; Anglada, Marc; Pellice, Sergio Antonio; Cavalieri, Ana Lia
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- One way to enhance the surface properties of metals used as surgical implants such as wear or protective behaviour is to use hybrid organic-inorganic sol-gel coatings. The addition of SiO2 colloidal particles to some hybrid formulation is thought to give films with bigger thickness than the coatings without particles, acting as mechanical reinforcement and to make an adequate surface to resist the extreme surgical procedures taking place in orthopaedic replacements. Coatings made by sol-gel with tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) with the addition of silica nanoparticles were applied onto surgical grade stainless steel. One of the most recent techniques used to study the mechanical properties of thin films is the instrumented indentation, known as nanoindentation, was used to evaluate elastic modulus, hardness and friction coefficient. This is a superficial technique used to measure quasi-statically the penetration of an indenter at increasing loads applied to very little volumes of material. The mechanical properties values found for the TEOS-MTES-10%SiO2 coating are smaller than for the 30% filled coating, and higher that the coating without nanoparticles. In the scratch test of the TEOS-MTES-SiO2 30 wt.% coating it can be seen that in this case the failure takes place at higher applied load than for the less silica reinforced one, indicating a much better adhesion than the system with 10% of SiO2 nanoparticles. © 2009 Elsevier B.V. All rights reserved.
Fil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Jimenez Pique, Emilio. Universidad Politécnica de Catalunya; España
Fil: Anglada, Marc. Universidad Politécnica de Catalunya; España
Fil: Pellice, Sergio Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Cavalieri, Ana Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Mechanical Properties
Nanoindentation
Orthopaedic Stainless Steel
Silica Coatings - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/66115
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Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniquesBallarre, JosefinaJimenez Pique, EmilioAnglada, MarcPellice, Sergio AntonioCavalieri, Ana LiaMechanical PropertiesNanoindentationOrthopaedic Stainless SteelSilica Coatingshttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2One way to enhance the surface properties of metals used as surgical implants such as wear or protective behaviour is to use hybrid organic-inorganic sol-gel coatings. The addition of SiO2 colloidal particles to some hybrid formulation is thought to give films with bigger thickness than the coatings without particles, acting as mechanical reinforcement and to make an adequate surface to resist the extreme surgical procedures taking place in orthopaedic replacements. Coatings made by sol-gel with tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) with the addition of silica nanoparticles were applied onto surgical grade stainless steel. One of the most recent techniques used to study the mechanical properties of thin films is the instrumented indentation, known as nanoindentation, was used to evaluate elastic modulus, hardness and friction coefficient. This is a superficial technique used to measure quasi-statically the penetration of an indenter at increasing loads applied to very little volumes of material. The mechanical properties values found for the TEOS-MTES-10%SiO2 coating are smaller than for the 30% filled coating, and higher that the coating without nanoparticles. In the scratch test of the TEOS-MTES-SiO2 30 wt.% coating it can be seen that in this case the failure takes place at higher applied load than for the less silica reinforced one, indicating a much better adhesion than the system with 10% of SiO2 nanoparticles. © 2009 Elsevier B.V. All rights reserved.Fil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Jimenez Pique, Emilio. Universidad Politécnica de Catalunya; EspañaFil: Anglada, Marc. Universidad Politécnica de Catalunya; EspañaFil: Pellice, Sergio Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Cavalieri, Ana Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier Science Sa2009-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66115Ballarre, Josefina; Jimenez Pique, Emilio; Anglada, Marc; Pellice, Sergio Antonio; Cavalieri, Ana Lia; Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques; Elsevier Science Sa; Surface and Coatings Technology; 203; 20-21; 7-2009; 3325-33310257-8972CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2009.04.014info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0257897209003594info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:38Zoai:ri.conicet.gov.ar:11336/66115instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:38.469CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques |
title |
Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques |
spellingShingle |
Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques Ballarre, Josefina Mechanical Properties Nanoindentation Orthopaedic Stainless Steel Silica Coatings |
title_short |
Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques |
title_full |
Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques |
title_fullStr |
Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques |
title_full_unstemmed |
Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques |
title_sort |
Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques |
dc.creator.none.fl_str_mv |
Ballarre, Josefina Jimenez Pique, Emilio Anglada, Marc Pellice, Sergio Antonio Cavalieri, Ana Lia |
author |
Ballarre, Josefina |
author_facet |
Ballarre, Josefina Jimenez Pique, Emilio Anglada, Marc Pellice, Sergio Antonio Cavalieri, Ana Lia |
author_role |
author |
author2 |
Jimenez Pique, Emilio Anglada, Marc Pellice, Sergio Antonio Cavalieri, Ana Lia |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Mechanical Properties Nanoindentation Orthopaedic Stainless Steel Silica Coatings |
topic |
Mechanical Properties Nanoindentation Orthopaedic Stainless Steel Silica Coatings |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
One way to enhance the surface properties of metals used as surgical implants such as wear or protective behaviour is to use hybrid organic-inorganic sol-gel coatings. The addition of SiO2 colloidal particles to some hybrid formulation is thought to give films with bigger thickness than the coatings without particles, acting as mechanical reinforcement and to make an adequate surface to resist the extreme surgical procedures taking place in orthopaedic replacements. Coatings made by sol-gel with tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) with the addition of silica nanoparticles were applied onto surgical grade stainless steel. One of the most recent techniques used to study the mechanical properties of thin films is the instrumented indentation, known as nanoindentation, was used to evaluate elastic modulus, hardness and friction coefficient. This is a superficial technique used to measure quasi-statically the penetration of an indenter at increasing loads applied to very little volumes of material. The mechanical properties values found for the TEOS-MTES-10%SiO2 coating are smaller than for the 30% filled coating, and higher that the coating without nanoparticles. In the scratch test of the TEOS-MTES-SiO2 30 wt.% coating it can be seen that in this case the failure takes place at higher applied load than for the less silica reinforced one, indicating a much better adhesion than the system with 10% of SiO2 nanoparticles. © 2009 Elsevier B.V. All rights reserved. Fil: Ballarre, Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Jimenez Pique, Emilio. Universidad Politécnica de Catalunya; España Fil: Anglada, Marc. Universidad Politécnica de Catalunya; España Fil: Pellice, Sergio Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Cavalieri, Ana Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
One way to enhance the surface properties of metals used as surgical implants such as wear or protective behaviour is to use hybrid organic-inorganic sol-gel coatings. The addition of SiO2 colloidal particles to some hybrid formulation is thought to give films with bigger thickness than the coatings without particles, acting as mechanical reinforcement and to make an adequate surface to resist the extreme surgical procedures taking place in orthopaedic replacements. Coatings made by sol-gel with tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) with the addition of silica nanoparticles were applied onto surgical grade stainless steel. One of the most recent techniques used to study the mechanical properties of thin films is the instrumented indentation, known as nanoindentation, was used to evaluate elastic modulus, hardness and friction coefficient. This is a superficial technique used to measure quasi-statically the penetration of an indenter at increasing loads applied to very little volumes of material. The mechanical properties values found for the TEOS-MTES-10%SiO2 coating are smaller than for the 30% filled coating, and higher that the coating without nanoparticles. In the scratch test of the TEOS-MTES-SiO2 30 wt.% coating it can be seen that in this case the failure takes place at higher applied load than for the less silica reinforced one, indicating a much better adhesion than the system with 10% of SiO2 nanoparticles. © 2009 Elsevier B.V. All rights reserved. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-07 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/66115 Ballarre, Josefina; Jimenez Pique, Emilio; Anglada, Marc; Pellice, Sergio Antonio; Cavalieri, Ana Lia; Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques; Elsevier Science Sa; Surface and Coatings Technology; 203; 20-21; 7-2009; 3325-3331 0257-8972 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/66115 |
identifier_str_mv |
Ballarre, Josefina; Jimenez Pique, Emilio; Anglada, Marc; Pellice, Sergio Antonio; Cavalieri, Ana Lia; Mechanical characterization of nano-reinforced silica based sol-gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques; Elsevier Science Sa; Surface and Coatings Technology; 203; 20-21; 7-2009; 3325-3331 0257-8972 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2009.04.014 info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0257897209003594 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science Sa |
publisher.none.fl_str_mv |
Elsevier Science Sa |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268872608055296 |
score |
13.13397 |